Advertisement

The potential of fluorescence for pesticide residue analysis

  • D. MacDougall
Conference paper
Part of the Residue Reviews/Rückstands-Berichte book series (RECT, volume 5)

Abstract

As a technique for the determination of pesticide residues, fluorescence is not as generally applicable as some modern methods such as vapor phase chromatography. However, it does have certain advantages over the classical methods of analysis in cases where it can be used. The possible uses of this technique for residue purposes have not been thoroughly explored. It is important that the residue chemist consider all possible techniques available and use whichever is most readily applicable to a given problem. Therefore, in this paper the author will attempt to explore the areas of residue analysis in which fluorescence should be applicable. No attempt is made to make an exhaustive review of fluorescence methods in general.

Keywords

Pesticide Residue Phthalic Acid Methyl Amine Aliphatic Acid Fluorescent Material 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Adams, J. M., and D. Mac Dougall: Report No. 7075 Chemagro Corp., Kansas City, Missouri, 1961.Google Scholar
  2. Anderson, C. A., J. M. Adams, and D. Mac Dougall: Photofluorometric method for determination of Co-Ral (O-β-chloro-4-methylumbelliferone O,O-diethyl phosphorothioate) residues in animal tissues. J. Agr. Food Chem. 7, 256 (1959).CrossRefGoogle Scholar
  3. Arison, B. H., G. V. Downing, R. A. Gray, M. A. Manzelli, J. D. Neuss, O. Speth, N. R. Tzenner, and F. J. Wolf: Abstracts of Papers, 132nd National Meeting Amer. Chem. Soc., New York City, p. 35 C (1957).Google Scholar
  4. Baker, W., J. B. Harborne, and W. D. Ollis: Characterization of primary aliphatic amines by reaction with o-acetoacetylphenol and by paper chromatography. J. Chem. Soc. 1952, 3215.Google Scholar
  5. Barr, C. G.: Investigations on the fluorometric determination of malic and succinic acids in apple tissue. Plant Physiol. 23, 443 (1948).PubMedCrossRefGoogle Scholar
  6. Brandt, R., and N. D. Cheronis: Fluorometric detection and determination of organic compounds. I. A rapid microsemiquantitative test for acetone and some spectrophotofluorometric data on this detection. Microchem. J. 5, 110 (1961).CrossRefGoogle Scholar
  7. Braunsberg, H., and V. H. T. James: Some observations on fluorometric determinations. Anal. Biochem. 1, 443 (1961).CrossRefGoogle Scholar
  8. Cheng, E. W., and W. Burroughs: Determination of small amounts of diethylstilbestrol in feeds. J. Assoc. Official Agr. Chemists 38, 146 (1955).Google Scholar
  9. Chomse, H., and I. Arend: Microchemical detection of phthalic acid. Chem. Tech. (Berlin) 11, 377 (1959).Google Scholar
  10. Cohn, V. J. Jr., and P. A. Shore: A microfluorometric method for the determination of agmatine. Anal. Biochem. 2, 237 (1961).PubMedCrossRefGoogle Scholar
  11. Conn, R. B. Jr., and R. B. Davis: Green fluorescence of guanidinium compounds with ninhydrin. Nature 183, 1053 (1959).CrossRefGoogle Scholar
  12. Druckrey, H., D. Schmohl, and R. Preussmann: Fluorescent impurities in liquid paraffin and organic solvents. Arzneimittel-Forsdi. 9, 600 (1959).Google Scholar
  13. Fiegl, F.: Spot tests in organic analysis. 5th English ed. Princeton: Van Nostrand 1956.Google Scholar
  14. Gehauf, B., and J. Goldenson: Detection and estimation of nerve gases by fluorescence reaction. Anal. Chem. 29, 276 (1957).CrossRefGoogle Scholar
  15. Goodyear, J. M., and N. R. Jenkinson: Irradiation fluorimetric method for estimation of diethylstilbesterol in beef liver tissue. Anal. Chem. 33, 853 (1961).CrossRefGoogle Scholar
  16. Hanker, J. S., A. Gelberg, and B. Witten: Fluorometric and colorimetric estimation of cyanide and sulfide by demasking reactions of palladium chelates. Anal. Chem. 30, 93 (1958).CrossRefGoogle Scholar
  17. Hercules, D. M., and L. B. Rogers: Fluorometric determination of 1- and 2- naphthol in mixtures. Anal. Chem. 30, 96 (1958).CrossRefGoogle Scholar
  18. Hornstein, I.: Spectrophotofluorometry for pesticide determination. T. Agr. Food Chem. 6, 32 (1958).CrossRefGoogle Scholar
  19. Hosoi, M.: A fluorometric method for the determination of estrogens in urine and plasma. Kanazawa Daigaku Kekkakm Kenkyusho Nempo 16, 145 (1958).Google Scholar
  20. Ichimura, Y.: Fluorescence of coumarin derivatives. I. Fluorometric analysis of warfarin. Yakugaku Zasshi 79, 1079 (1959).Google Scholar
  21. Inai, T.: Fluorometric method for the determination of human urinary estrogens Shikoku Igaku Zasshi 16, 735 (1960).Google Scholar
  22. Loeffler, W. W., and D. Mac Dougall: Report No. 5119 Chemagro Corp., Kansas City, Missouri, 1960.Google Scholar
  23. Mac Dougall, D.: The use of fluorometric measurements for determination of pesticide residues. Residue reviews 1, 24 (1962).Google Scholar
  24. Munsey, V. E.: Diethylstilbesterol in cattle feed. J. Assoc. Official Agr. Chemists 41, 316 (1958).Google Scholar
  25. Pesez, M., and J. Ferrero: A fluorescence test in the paper chromatography of aliphatic acids. Bull. Soc. Chim. Biol. 39, 221 (1957).PubMedGoogle Scholar
  26. Sawicki, E., and T. W. Stanley: Fluorescence spot tests for glyoxal pyruvaldehyde, salicylaldehyde and some other aromatic aldehydes. Chemist Analyst 49, 107Google Scholar
  27. Shore, P. A., A. Burkhalter, and V. H. Cohn, Jr.: A method for the fluorometric assay of histamine in tissues. J. Pharmacol. Expt. Therap. 127, 182 (1959).Google Scholar
  28. Sorensen, L. M., and J. R. Matzke: Stable 2-naphthol solution for fluorometric determination of malic acid. Chemist Analyst 47, 20 (1958).Google Scholar
  29. Theriault, R. J., W. C. Friedland, M. H. Peterson, and J. C. Sylvester: Fluorometric assay for gibberellic acid. J. Agr. Food Chem. 9, 21 (1961).CrossRefGoogle Scholar
  30. Thommes, G. A., and E. Leininger: Fluorometric determination of o- and m- hydroxybenzoic acids in mixtures. Anal. Chem. 30, 1361 (1958).CrossRefGoogle Scholar
  31. Thommes, G. A., and E. Leininger: Fluorometric determination of o-phthalic acid. Talanta 5, 260 (1960).CrossRefGoogle Scholar
  32. Weil-Malherbe, H., and A. D. Bone: Chemical estimation of adrenaline-like substances in blood. Biochem. J. 51, 311 (1952).PubMedGoogle Scholar

Copyright information

© Springer-Verlag OHG Berlin · Göttingen · Heidelberg 1964

Authors and Affiliations

  • D. MacDougall
    • 1
  1. 1.Chemagro CorporationKansas CityUSA

Personalised recommendations