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Mechanism and Phenomenology of Organic Inhibitors

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Advances in Corrosion Science and Technology

Abstract

In general, any phase constituent whose presence is not essential to the occurrence of an electrochemical process, but leads to a retardation of this process by modifying the surface state of the metallic material, will be called an inhibitor (this applies to electrolytic phases). Such modification of the surface state implies adsorption, the formation of “surface compounds,” or a reaction between the metallic material and the inhibitor with separation of the corrosion products at the contact surface of the metallic material with the electrolytic conductor.1 If we consider that corrosion is the degradation of a metallic material through the passage of its constitutive elements to a state of combination with surrounding materials, making particular reference to corrosion phenomena in electrolytic conductors, we can define corrosion inhibitors as substances that inhibit one or more of the partial processes of the corrosion process as a whole.

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Trabanelli, G., Carassiti, V. (1970). Mechanism and Phenomenology of Organic Inhibitors. In: Fontana, M.G., Staehle, R.W. (eds) Advances in Corrosion Science and Technology. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-8252-6_3

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