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Electron Spectrometry of Atoms and Molecules

  • Chapter
Synchrotron Radiation Research

Abstract

Electron spectrometry using synchrotron radiation (essr) is a new endeavor, having had its first trials in 1972(1, 2) and its real beginning shortly thereafter.(3) Of course, neither electron spectrometry nor synchrotron radiation are very old. Electron spectrometry matured in the late sixties relying on conventional excitation sources,(4–9) and synchrotron radiation was widely applied to photoabsorption studies in the gas phase during the sixties.(10–12) The combination of electron spectrometry and synchrotron radiation has already led to results of great specificity that would be difficult or impossible to obtain by either continuous absorption measurements or by electron spectrometry that uses discrete photon sources. The essr technique allows the x-ray physicist to decompose a photoabsorption spectrum into its constituent components, and it allows the electron spectroscopist to study the features of a photoelectron spectrum as they vary with the photon energy. Thus, structure and dynamics of atomic and molecular systems can be delineated at a highly differentiated level. Specifically, essr has the potential of probing many-electron effects in bound and in continuum states, interactions between continuum and bound states, de-excitation pathways, and relativistic effects.

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Krause, M.O. (1980). Electron Spectrometry of Atoms and Molecules. In: Winick, H., Doniach, S. (eds) Synchrotron Radiation Research. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-7998-4_5

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