Abstract
On the basis of previously published data and the author’s experimental data, a self-consistent set of equilibrium constants for various oleate species was determined and compared with those already existing in the literature. A domain diagram is presented which shows the oleate-pH-sodium ion activity regions for such oleate forms as HOlaq, HOloil, NaOlin HOl, NaHOl2, and NaβOlβ-1 associates (where β is the so-called degree of counterion [sodium] binding to an oleate ion), and also such forms as the liquid crystalline, hydrated and anhydrous phases. Also, a diagram is presented showing the activity of various oleate species vs pH of aqueous solutions for the oleic acid-water-sodium chloride system at 25°C having a total oleate species concentration of 10−3 M and total sodium ion concentration of 2· 10−3 M.
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References
J. Drzymala, Colloid Interface Sci., 108, 257 (1985).
R. F. Jung, Oleic Acid Adsorption at the Geothite-Water Interface. M. S. Thesis, University of Melbourne, Australia, 1976.
P. Somasundaran, K. P. Ananthapadmanabhan, and I. B. Ivanov, J. Colloid Interface Sci., 99, 128 (1984).
J. R. White, J. Am. Chem. Soc., 72, 1859 (1950).
C. du Rietz, in “Proc. XIth Inter. Mineral Proc. Congress,” Inst. di Arte Mineraria, Cagliari, p. 357 (1975).
P. Somasundaran and P. Ananthapadmanabhan, in “Solution Chemistry of Surfactants,” K. L. Mittal, Editor, Vol. 2, p. 777, Plenum Press, New York, 1979.
G. Nemethy and H. A. Scheraga, J. Phys. Chem., 66, 1777 (1962).
K. P. Ananthapadmanabhan and P. Somasundaran, in “Interfacial Phenomena in Mineral Processing,” B. Yarar and D. J. Spottiswood, Editors, p. 207, Engineering Foundation, New York, 1982.
P. Mukerjee, Adv. Colloid Interface Sci., 1, 241 (1967).
P. Ekwall, Colloid Polymer Sci., 266, 723 (1988).
A. Pomianowski, private communication, 1986.
H. W. Brouwer and H. L. Spier, in “Proc. 3rd International Conference on Thermal Analysis,” Vol. 3, p. 130, Birkhauser/Verlag, Baselu, Stuttgart, 1972.
R. D. Kulkarni and P. Somasundaran, Colloids Surfaces, 1, 387 (1980).
S. N. Yap, S. Mishra, S. Raghavan, and D-W. Fuerstenau, in “Adsorption From Aqueous Solutions,” P. H. Tewari, Editor, p. 119, Plenum Press, New York, 1981.
C. du Rietz, in “Proc. 2nd Scand. Symp. on Surface Activity,” p. 21, Stockholm, 1964.
V. Zimmels and I. J. Lin, Colloid Polymer Sci., 252, 594 (1974).
P. Mukerjee and K. J. Mysels, “Critical Micelle Concentration of Aqueous Surfactant Systems,” National Standard References Data System, NSRDS-NBV-36 USA, 1971.
Z. N. Markina, O. P. Bovkun, and P. A. Rehbinder, Kolloid. Zhur., 35, 833 (1973).
V. C. L’vov and A. I. Serdiuk, Kolloid. Zhur., 45, 1090 (1983).
R. V. Kucher, A. I. Serdiuk, and V. G. L’vov, Zhurnal Prikladnej Khimii, 53, 1502 (1980).
H. Sonntag, “Lehrbuch der Kolloid Wissenschaft,” p. 276, VED Deutscher Verlag der Wissenschaften, Berlin, 1977.
I. N. Plaskin and V. I. Solnyshkin, “Infrared Spectroscopy of Surface Layers of Agents on Minerals,” p. 200, Nauka, Moscow, 1966, Russian text.
S. S. Voyutskii, “Course in Colloidal Chemistry,” p. 215, Khimya, Moscow, 1964.
H. Palonen and P. Stenius, in “Proc. Int. Symp. Wood Pulping Chem.,” Vol. V, p. 100 Ekman Days Stockholm, Sweden, 1981.
P. Stenius, H. Palonen, G. Strom, and L. Odberg, in “Surfactant in Solution,” K. L. Mittal and B. Lindman, Editors, Vol. 1, p. 153, Plenum Press, New York, 1984.
J. L. Curat and R. Perron, in “13th Actes Congr. Mond.-Soc. Int. Etude Corps Gras,” M. Naudet, E. Uccioni, and A. Uzzan, Eds., Iterg, Paris Sec. F. 51, 1976.
R. D. Vold and M. J. Vold, “Colloid and Interface Chemistry,” p. 595, Addison-Wesley Publishing Company, 1983.
J. Drzymala, Wlasciwosci wodnych roztworow i emulsji oleinianowych, Monograph, Wroclaw Technical University, submitted for publication, 1988.
J. Drzymala, J. Colloid Interface Sci., 107, 442 (1985).
R. D. Kulkarni, P. Somasundaran, and K. P. Anathapadmanabhan, in “Proc. XIIth Int. Min. Proc. Congress,” Special Volume-Iron, Vol. 2, p. 80, Sao Paulo, 1977.
K. P. Ananthapadmanabhan, P. Somasundaran, and T. W. Healy, Trans. AIME, 266, 2003 (1979).
J. Mager and J. Lekki, in “Fizykochemiczne Problemy Mineralurgii,” Technical University of Wroclaw, Wroclaw, 1985.
S. Backlund, K. Rundt, K. S. Birdi, and S. Dalsager, Colloid Polymer Sci., 259, 1105 (1981).
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Drzymala, J. (1989). Chemistry of the Oleic Acid-H2O-NaCl System VS pH at 25°C. In: Mittal, K.L. (eds) Surfactants in Solution. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-7984-7_33
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DOI: https://doi.org/10.1007/978-1-4615-7984-7_33
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