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Charge States In Polymers: Application to Triboelectricity

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Physicochemical Aspects of Polymer Surfaces

Abstract

A mathematical model of localized molecular-ion, and molecular-exciton states in a dielectric medium is described. This model is shown to provide a quantitative description of the lineshapes and temperature dependence of photoemission and UV absorption from molecular glasses and pendant-group polymers. Its extension to describe electron transfer in these systems is indicated. Attention is focussed on polystyrene, poly(2-vinyl pyridine), and molecular glasses of 2-ethyl benzene, isopropylbenzene and 2-ethyl pyridine as model systems. Application of the model to describe contact charge exchange in copolymers of polystyrene, poly(methyl methacrylate) and poly(2-vinyl pyridine) correctly predicts the steady-state charge exchange among these materials.

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Authors and Affiliations

  1. Xerox Webster Research Laboratory, Xerox Square-114, Rochester, N.Y., 14644, USA

    C. B. Duke

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  1. C. B. Duke
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Editor information

Editors and Affiliations

  1. East Fishkill Facility, IBM Corporation, 12533, Hopewell Junction, New York, USA

    K. L. Mittal

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© 1983 Plenum Press, New York

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Duke, C.B. (1983). Charge States In Polymers: Application to Triboelectricity. In: Mittal, K.L. (eds) Physicochemical Aspects of Polymer Surfaces. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-7584-9_27

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  • DOI: https://doi.org/10.1007/978-1-4615-7584-9_27

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4615-7586-3

  • Online ISBN: 978-1-4615-7584-9

  • eBook Packages: Springer Book Archive

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