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Interfacial Charge Transfer Reactions in Colloidal Dispersions and Their Application to Water Cleavage by Visible Light

  • Chapter
Modern Aspects of Electrochemistry

Abstract

There is ample evidence from present day analysis1 that conventional energy supplies are insufficient to cover future energy needs and, in fact, need to be supplemented by alternative resources, such as solar radiation. Therefore, during the coming decades mankind is faced with the challenging task of conceiving devices that accomplish the conversion and storage of solar energy. Endeavors have to be undertaken now to provide a broad scientific basis for such a future development. Devices that harness visible light and convert it into a storable fuel have to be designed and thoroughly investigated. One process that deserves particular attention is the cleavage of water into hydrogen and oxygen by visible light.

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References

  1. J. Bolton, Solar Power and Fuels, AcademicPress, London, 1977.

    Google Scholar 

  2. S. Claesson, Photochemical Conversion and Storage of Solar Energy, Swedish National Energy Board Report, Stockholm, 1977.

    Google Scholar 

  3. J. Bolton and D. O. Hall, Ann. Rev. Energy 4(1979) 353.

    CAS  Google Scholar 

  4. E. Schuhmacher, Chimia 32(1978) 194.

    Google Scholar 

  5. J. Bolton, Science 202(1978) 705.

    CAS  Google Scholar 

  6. D. O. Hall, Fuel 57(1978) 322.

    CAS  Google Scholar 

  7. M. Calvin, Photochem. Photobiol. 23(1976) 425.

    CAS  Google Scholar 

  8. J. O’M. Bockris, Energy, The Solar Hydrogen Alternative, Australia and New Zealand Book Co. Pty. Ltd., Sidney, 1978.

    Google Scholar 

  9. G. Porter and M. D. Archer, Interdisc. Sci. Rev. 1(1976) 119.

    CAS  Google Scholar 

  10. K. I. Zamaraev and V. N. Parmon, Catal. Rev. Sci. Eng. 22(1980) 261.

    CAS  Google Scholar 

  11. R. Memming, Electrochim. Acta 25(1980) 77.

    CAS  Google Scholar 

  12. K. Rajeshwar, P. Singh, and J. DuBow, J. Electrochimica Acta 23(1978) 1117.

    CAS  Google Scholar 

  13. A. Harris and R. H. Wilson, Ann. Rev. Mater. Sci. 8(1978) 99.

    CAS  Google Scholar 

  14. V. Guruswamy and J. O’M. Bockris, Solar Energy Mater. 1(1979) 141.

    Google Scholar 

  15. A. J. Nozik, Phil. Trans. R. Soc. London A295(1980) 453.

    Google Scholar 

  16. A. Heller and B. Miller, Electrochim. Acta 29(1980) 29.

    Google Scholar 

  17. M. S. Wrighton, Acc. Chem. Res. 12(1979) 303.

    Google Scholar 

  18. H. Gerischer, Proc. 2nd E.C. Photovoltaic Solar Energy Conf., Ed. by R. van Overstraefen and W. Palz, D. Reidel, Dordrecht-Boston-London, 1979, pp. 408–431.

    Google Scholar 

  19. A. Fujishima and K. Honda, Nature 238(1972) 37.

    CAS  Google Scholar 

  20. Y. Nakato, S. Tonomura, and H. Tsubomura, Ber. Bunsenges. Phys. Chem. 80(1976) 1289.

    CAS  Google Scholar 

  21. W. Kautek, J. Cobrecht, and H. Gerischer, Ber. Bunsenges. Phys. Chem. 84(1980) 1034.

    CAS  Google Scholar 

  22. A. Heller, Acc. Chem. Res. 14(1981) 154.

    CAS  Google Scholar 

  23. M. Grätzel, Acc. Chem. Res. 14(1981) 376.

    Google Scholar 

  24. W. L. Reynolds and R. W. Lumry, Mechanism of Electron Transfer, Ronald Press, New York, 1966.

    Google Scholar 

  25. A. W. Addison, W. R. Cullen, D. Dolphin, and B. R. James, Biological Aspects of Inorganic Chemistry, Wiley-Interscience, New York, 1977.

    Google Scholar 

  26. F. Scandola, V. Balzani, and G. B. Schuster, J. Am. Chem. Soc. 103 (1981) 2519.

    CAS  Google Scholar 

  27. W. F. Libby, J. Phys. Chem. 56(1953) 863.

    Google Scholar 

  28. R. A. Marcus, Discuss. Faraday Soc. 29(1960) 21.

    Google Scholar 

  29. R. A. Marcus, Ann. Rev. Phys. Chem. 15(1964) 155.

    CAS  Google Scholar 

  30. R. A. Marcus, J. Chem. Phys. 43(1965) 679.

    Google Scholar 

  31. R. A. Marcus, Electrochim. Acta 13(1968) 995.

    Google Scholar 

  32. N. S. Hush, Trans. Faraday Soc. 57(1961) 155.

    Google Scholar 

  33. T. Holstein, Philos. Mag. 37(1978) 49.

    CAS  Google Scholar 

  34. T. Holstein, Ann. Phys. (Leipzig) 8(1959) 343.

    CAS  Google Scholar 

  35. V. G. Levich, Adv. Electrochem. Electrochem. Eng. 4(1966) 249.

    Google Scholar 

  36. N. R. Kestner, J. Logan, and J. Jortner, J. Phys. Chem. 78(1974) 2148.

    CAS  Google Scholar 

  37. J. Ulstrup and J. J. Jortner, Chem. Phys. 63(1975) 4358.

    CAS  Google Scholar 

  38. S. Efrima and M. Bixon, Chem. Phys. 13(1976) 447.

    CAS  Google Scholar 

  39. R. P. Van Duyne and S. F. Fischer, Chem. Phys. 5(1974) 183.

    Google Scholar 

  40. J. J. Hopfield, Proc. Natl. Acad. Sci. U.S.A. 71(1974) 3640.

    CAS  Google Scholar 

  41. M. A. Vorotyntsev, R. R. Dogonadze, and A. M. Kuznetsov, Dokl. Akad. Nauk SSR 195(1970) 1135.

    CAS  Google Scholar 

  42. E. D. German, V. G. Dvali, R. R. Dogonadze, and A. M. Kuznetsov, Elektrokimiya 12(1976) 639.

    Google Scholar 

  43. R. R. Dogonadze and A. M. Kuznetsov, Prog. Surf. Sci. 6(1975) 1.

    CAS  Google Scholar 

  44. R. R. Dogonadze and A. M. Kuznetsov, Elektrokimiya 2(1967) 1324.

    Google Scholar 

  45. R. R. Dogonadze, A. M. Kuznetsov, and V. G. Levich, Electrochim. Acta 13(1968) 1025.

    CAS  Google Scholar 

  46. L. Landau, Phys. Z. Sowjetunion 2(1932) 46.

    CAS  Google Scholar 

  47. C. Zener, Proc. R. Soc. London, Ser. A 137(1932) 696.

    Google Scholar 

  48. C. Zener, Proc. R. Soc. London 140(1033) 660.

    Google Scholar 

  49. B. S. Brunschwig, J. Logan, M. D. Newton, and N. Sutin, J. Am. Chem. Soc. 102(1980) 5798.

    CAS  Google Scholar 

  50. R. A. Marcus, Ann. Rev. Phys. Chem. 15(1964) 155.

    CAS  Google Scholar 

  51. D. Rehm and A. Weller, Ber. Bunsenges. Phys. Chem. 73(1969) 834.

    CAS  Google Scholar 

  52. C. R. Bock, T. J. Meyer, and D. G. Whitten, J. Am. Chem. Soc. 97(1975) 2909.

    CAS  Google Scholar 

  53. P. A. Carapelluci and D. Mauzerall, Ann. N.Y. Acad. Sci. 244(1975) 214.

    Google Scholar 

  54. R. Scheerer and M. Grätzel, J. Am. Chem. Soc. 99(1977) 865.

    CAS  Google Scholar 

  55. H. Leonhardt and A. Weller, Ber. Bunsenges. Phys. Chem. 67(1963) 791.

    CAS  Google Scholar 

  56. A. Weller, Fast React. Primary Processes Chem. Kinet., Proc. NobelSymp. 5th, 1967, p. 413.

    Google Scholar 

  57. E. H. Cordes and C. Gitler, Progr. Bioorg. Chem. 2(1973) 1.

    CAS  Google Scholar 

  58. C. Tanford, The Hydrophobic Effect; Formation of Micelles and Biological Membranes, Wiley-Interscience, New York, 1973.

    Google Scholar 

  59. J. H. Fendler and E. J. Fendler, Catalysis in Micellar and Macromolecular Systems, Academic Press, New York, 1975.

    Google Scholar 

  60. B. Lindman and H. Wennerstrüm, Topics in Current Chemistry, Springer-Verlag, Berlin, 1980, Vol. 87, p. 1 ff.

    Google Scholar 

  61. M. S. Fernandez and P. Fromherz, J. Phys. Chem. 81(1977) 1755.

    CAS  Google Scholar 

  62. S. McLaughlin, Current Topics in Membranes and Transport, Academic Press, New York, 1977, Vol. 9, p. 71 ff.

    Google Scholar 

  63. M. Czerniawski and R. Mikulski, Polish J. Chem. 54(1980) 1205.

    CAS  Google Scholar 

  64. M. Grützel, Micellization and Microemulsion, Ed. by K. L. Mittal, Plenum Press, 1977, Vol. 2, p. 831.

    Google Scholar 

  65. P. P. Infelta and M. Grätzel, J. Chem. Phys. 70(1979) 179.

    CAS  Google Scholar 

  66. R. C. Dorrance and T. F. Hunter, J. Chem. Soc. Faraday Trans. 168(1972) 1312.

    Google Scholar 

  67. N. Khuanga, B. K. Selinger, and R. McDonald, Aust. J. Chem. 29(1976) 1.

    CAS  Google Scholar 

  68. M. Maestri, P. P. Infelta, and M. Grätzel, J. Chem. Phys. 69(1978) 1522.

    CAS  Google Scholar 

  69. P. P. Infelta, M. Grätzel, and J. K. Thomas, J. Phys. Chem. 78(1974) 190.

    CAS  Google Scholar 

  70. M. P. Pileni and M. Grätzel, J. Phys. Chem. 84(1980) 1822.

    CAS  Google Scholar 

  71. N. J. Turro, M. Grätzel, and A. M. Braun, Angew. Chem. Int. Ed. 19(1980) 675.

    Google Scholar 

  72. S. S. Atik and J. K. Thomas, J. Am. Chem. Soc. 103(1981) 3203.

    Google Scholar 

  73. Y. Moroi, P. P. Infelta, and M. Grätzel, J. Am. Chem. Soc. 101(1979) 573.

    CAS  Google Scholar 

  74. M. D. Hatley, J. J. Kozak, G. Rothenberger, P. P. Infelta, and M. Grätzel, J. Phys. Chem. 84(1980) 1508.

    Google Scholar 

  75. M. Grätzel and J. K. Thomas, J. Am. Chem. Soc. 95(1973) 6885.

    Google Scholar 

  76. M. Grätzel, in Dahlem Conference 1978 on Light Induced Charge Separation, Ed. by H. Gerischer and J. J. Kutz, Verlag Chemie, Weinheim, Germany, pp. 287–302.

    Google Scholar 

  77. G. Rothenberger, P. P. Infelta, and M. Grützel, J. Phys. Chem. 83 (1979)1871.

    Google Scholar 

  78. G. Rothenberger, P. P. Infelta, and M. Grützel, J. Phys. Chem. 85 (1981)1950.

    Google Scholar 

  79. B. Razem, M. Wong, and J. K. Thomas, J. Am. Chem. Soc. 100(1978) 1679.

    Google Scholar 

  80. Y. Waka, K. Hamamoto, and N. Mataga, Chem. Phys. Lett. 53(1978) 242.

    CAS  Google Scholar 

  81. C. Wolff and M. Grätzel, Chem. Phys. Lett. 52(1977) 542.

    CAS  Google Scholar 

  82. Y. Moroi, A. M. Braun, and M. Grätzel, J. Am. Chem. Soc. 101(1979) 567.

    CAS  Google Scholar 

  83. R. Humphry-Baker, Y. Moroi, M. Grätzel, P. Tundo, and E. Pelizzetti, Angew. Chem. Int. Ed. 18(1979) 630.

    Google Scholar 

  84. R. Humphry-Baker, Y. Moroi, M. Grätzel, P. Tundo, and E. Pelizzetti, J. Am. Chem. Soc. 102(1980) 3689.

    CAS  Google Scholar 

  85. K. Monserrat, M. Grätzel, and P. Tundo, J. Am. Chem. Soc. 102 (1980) 3689.

    Google Scholar 

  86. Y. Moroi, E. Pramauro, M. Grätzel, E. Pelizzetti, and P. Tundo, J. Coll. Int. Sci. 69(1979) 341.

    CAS  Google Scholar 

  87. J. Le Moigne, P. Gramein, and J. Simon, J. Coll. Int. Sci. 60(1977) 565.

    Google Scholar 

  88. M. P. Pileni, A. M. Braun, and M. Grätzel, Photochem. Photobiol. 31(1980) 423.

    CAS  Google Scholar 

  89. P.-A. Brugger and M. Grätzel, J. Am. Chem. Soc. 102(1980) 2461.

    Google Scholar 

  90. P.-A. Brugger, P. P. Infelta, A. M. Braun, and M. Grätzel, J. Am. Chem. Soc. 103(1981) 320.

    CAS  Google Scholar 

  91. M. Krieg, M. P. Pileni, A. M. Braun, and M. Grätzel, J. Coll. Int. Sci. 83(1981) 209.

    CAS  Google Scholar 

  92. K. Monserrat and M. Grätzel, J. Chem. Soc. Chem. Commun.1981, 183.

    Google Scholar 

  93. T. Matsuo, K. Takuma, Y. Tsutsui, and T. Nishijima, J. Coord. Chem. 10(1980) 187.

    CAS  Google Scholar 

  94. S. A. Alkaitis, G. Beck, and M. Grätzel, J. Am. Chem. Soc. 97(1975) 5723.

    CAS  Google Scholar 

  95. S. A. Alkaitis, M. Grätzel, and A. Henglein, Ber. Bunsenges. Phys. Chem. 79(1975) 541.

    CAS  Google Scholar 

  96. S. A. Alkaitis and M. Grätzel, J. Am. Chem. Soc. 98(1976) 3549.

    CAS  Google Scholar 

  97. J. K. Thomas, Acc. Chem. Res. 133(1977) 10.

    Google Scholar 

  98. R. Humphry-Baker, A. M. Braun, and M. Grützel, Hely. Chim. Acta.

    Google Scholar 

  99. D. Duonghong, J. Ramsden, and M. Grützel, J. Am. Chem. Soc.

    Google Scholar 

  100. E. C. Dutoit, F. Cardon, and W. P. Gomes, Ber. Bunsenges. Phys. Chem. 8(1976) 1285.

    Google Scholar 

  101. H. Gerischer, Pure and Appl. Chem. 52(1980) 2649.

    CAS  Google Scholar 

  102. B. Chance, D. C. DeVault, H. Frauenfelder, R. A. Marcus, J. B. Schrieffer, and N. Sutin, Tunneling in Biological Systems, AcademicPress, New York, 1979.

    Google Scholar 

  103. W. W. Dunn, Y. Aikawa, and A. J. Bard, J. Electrochem. Soc. 128(1981) 222.

    CAS  Google Scholar 

  104. W. W. Dunn, Y. Aikawa, and A. J. Bard, J. Am. Chem. Soc. 103(1981) 3456.

    CAS  Google Scholar 

  105. D. Duonghong, E. Borgarello, and M. Grätzel, J. Am. Chem. Soc. 103(1981) 4685.

    CAS  Google Scholar 

  106. G. Hodes, D. Cahen, J. Manassen, and M. David, J. Electrochem. Soc. 127(1980) 2252.

    CAS  Google Scholar 

  107. F. D. Saeva, G. R. Olin, and J. R. Harbour, J. Chem. Soc. Chem. Commun.1980, 401.

    Google Scholar 

  108. J. R. Harbour and M. L. Hair, J. Phys. Chem. 81(1977) 1741.

    Google Scholar 

  109. S. N. Frank and A. J. Bard, J. Phys. Chem. 81(1977) 1484.

    CAS  Google Scholar 

  110. J. R. Darwent and G. Porter, J. Chem. Soc. Chem. Commun.1981, 145.

    Google Scholar 

  111. K. Kalyanasundaram, E. Borgarello, and M. Grätzel, Heiv. Chim. Acta 64(1981) 362.

    CAS  Google Scholar 

  112. K. Kalyanasundaram, E. Borgarello, D. Duonghong, and M. Grützel, Angew. Chem. Int. Ed.

    Google Scholar 

  113. B. A. Parkinson, A. Heller, and B. Miller, J. Electrochem. Soc. 126(1979) 954.

    CAS  Google Scholar 

  114. C. Wagner and W. Traud, Z. Elektrochem. 44(1938) 391.

    CAS  Google Scholar 

  115. M. Spiro and A. B. Ravno, J. Chem. Soc. Faraday Trans. 175(1979) 1507.

    Google Scholar 

  116. M. Spiro and A. B. Ravno, J. Chem. Soc.1965, 78.

    Google Scholar 

  117. D. S. Miller, A. J. Bard, G. Mc. Lendon, and J. Ferguson, J. Am. Chem. Soc. 103(1981) 5337.

    Google Scholar 

  118. G. Sprintschnik, H. W. Sprintschnik, P. P. Kirsch, and D. G. Whitten, J. Am. Chem. Soc. 98(1976) 2337.

    CAS  Google Scholar 

  119. G. Sprintschnik, H. W. Sprintschnik, P. P. Kirsch, and D. G. Whitten, J. Am. Chem. Soc. 99(1977) 4947.

    CAS  Google Scholar 

  120. S. J. Valenty and G. L. Gaines, J. Am. Chem. Soc. 99(1977) 1285.

    CAS  Google Scholar 

  121. K. P. Seefeld, D. Möbius, and H. Kuhn, Heiv. Chim. Acta 60(1977) 2608.

    CAS  Google Scholar 

  122. K. Kalyanasundaram and M. Grätzel, in NATO Summer School on Photoelec -trochemistry, Gent (Belgium), NATO Advanced Studies Treatise, 1980.

    Google Scholar 

  123. J. Kiwi, K. Kalyanasundaram, and M. Grätzel, Structure and Bonding, Springer-Verlag, Heidelberg, 1981, Vol. 49, p. 37.

    CAS  Google Scholar 

  124. H. Kallmann and M. Pope, Nature 188(1960) 935.

    CAS  Google Scholar 

  125. M. Calvin, Acc. Chem. Res. 11(1978) 369.

    CAS  Google Scholar 

  126. H. T. Tien, in Topics in Photosynthesis, Ed. by J. Barber, Elsevier, Amsterdam, 1979, Vol. 3, pp. 116–173.

    Google Scholar 

  127. V. Balzani, F. Boletta, M. T. Gandolfi, and M. Maestri, Top. Current Chem. 75(1978) 1.

    CAS  Google Scholar 

  128. G. Porter, Proc. R. Soc. London A362(1978) 281.

    Google Scholar 

  129. M. Calvin, Photochem. Photobiol. 23(1976) 425.

    CAS  Google Scholar 

  130. N. Sutin, J. Photochem. 10(1979) 19.

    CAS  Google Scholar 

  131. D. Whitten, Acc. Chem. Res. 13(1980) 83.

    CAS  Google Scholar 

  132. H. D. Gafney and A. W. Adamson, J. Am. Chem. Soc. 94(1972) 8238.

    CAS  Google Scholar 

  133. R. Bock, T. J. Meyer, and D. G. Whitten, J. Am. Chem. Soc. 96(1974) 4710.

    CAS  Google Scholar 

  134. D. Manzerall, in The Porphyrins, Ed. by D. Dolphin, Academic Press, New York, 1978, Vol. 5, Part C, pp. 53–68.

    Google Scholar 

  135. K. Kalyanasundaram and M. Grätzel, Helv. Chim. Acta 64(1981) 362.

    CAS  Google Scholar 

  136. G. Mc. Lendon and D. S. Miller, J. Chem. Soc. Chem. Commun.1980, 533.

    Google Scholar 

  137. A. Harriman, G. Porter, and M. C. Richoux, J. Chem. Soc. Faraday Trans. 277(1981)833.

    Google Scholar 

  138. B. V. Koriakin, T. S. Dzhabiev, and A. E. Shilov, Dokl. Akad. Nauk SSSR 233(1977) 620.

    Google Scholar 

  139. A. I. Krasna, Photochem. Photobiol. 29(1979) 1345.

    Google Scholar 

  140. K. Kalyanasundaram and M. Grätzel, J. Chem. Soc. Chem. Commun.1979, 1137.

    Google Scholar 

  141. K. Kalyanasundaram, J. Kiwi, and M. Grätzel, Heiv. Chim. Acta 61(1978) 2720.

    CAS  Google Scholar 

  142. A. Moradpour, E. Amoyal, P. Keller, and H. Kagan, Nouveau J. Chim. 2(1978) 547.

    CAS  Google Scholar 

  143. B. V. Koryakin, T. S. Dzabiev, and A. E. Shilov, Dokl. Akad. Nauk SSSR 229(1976) 128.

    CAS  Google Scholar 

  144. J. M. Lehn and J. P. Sauvage, Nouveau J. Chim. 1(1977) 449.

    CAS  Google Scholar 

  145. G. M. Brown, S. F. Chan, C. Creutz, H. A. Schwarz, and N. Sutin, J. Am. Chem. Soc. 101(1979) 7638.

    CAS  Google Scholar 

  146. S. F. Chan, M. Chou, C. Creutz, T. Matsubara, and N. Sutin, J. Am. Chem. Soc. 103(1981) 369.

    CAS  Google Scholar 

  147. G. M. Brown, B. S. Brunschwig, C. Creutz, J. Endicott, and N. Sutin, J. Am. Chem. Soc. 101(1979) 1248.

    Google Scholar 

  148. P.-A. Brugger, M. Grätzel, T. Guarr, and G. Mc. Lendon, J. Phys. Chem. 86(1982) 944.

    Google Scholar 

  149. I. Willner, J. W. Otrös, and M. Calvin, J. Am. Chem. Soc. 103(1981) 3203.

    Google Scholar 

  150. P. Cuendet and M. Grützel, Photochem. Photobiol.

    Google Scholar 

  151. G. Bredig and R. Müller von Berneck, Ber. 31(1899) 258.

    Google Scholar 

  152. D. E. Green and L. H. Stickland, Biochem. J. 28(1934) 898.

    CAS  Google Scholar 

  153. A. Henglein, B. Lindig, and J. Westerhausen, J. Phys. Chem. 85 (1981)1637.

    Google Scholar 

  154. L. M. Peter, Disc. Faraday Soc. 70(1980) 414.

    Google Scholar 

  155. W J. Albery and P. N. Bartlett, Disc. Faraday Soc. 70(1980) 421.

    Google Scholar 

  156. J. Kiwi and M. Grätzel, Nature 281(1979) 657.

    CAS  Google Scholar 

  157. J. Kiwi and M. Grätzel, J. Am. Chem. Soc. 101(1979) 7214.

    CAS  Google Scholar 

  158. D. Whitten, Acc. Chem. Res. 13(1980) 83.

    CAS  Google Scholar 

  159. S. Markiewicz, M. S. Chan, R. H. Sparks, C. A. Evans, and J. R. Bolton, Abstract A9, in International Conference on the Photochemical Conversion and Storage of Solar Energy, London, Ontario, Aug. 24–28, 1976.

    Google Scholar 

  160. J. Turkevich, K. Aika, L. L. Ban, I. Okura, and S. Namba, J. Res. Inst. Catal., Hokkaido Univ. 24(1976) 54.

    Google Scholar 

  161. P.-A. Brugger, P. Cuendet, and M. Grätzel, J. Am. Chem. Soc. 103(1981) 2923.

    CAS  Google Scholar 

  162. M. Grätzel, Ber. Bunsenges. Phys. Chem. 84(1980) 981.

    Google Scholar 

  163. M. Grätzel, Disc. Fraday Soc. 70(1980) 359.

    Google Scholar 

  164. M. Grätzel, Disc. Fraday Soc. 70(1980) 359.

    Google Scholar 

  165. M. Calvin, Disc. Faraday Soc. 70(1980) 383.

    Google Scholar 

  166. M. Kirch, J. M. Lehn, and J. P. Sauvage, Hely. Chim. Acta 62(1979) 1345.

    CAS  Google Scholar 

  167. T. Sakata and T. Kawai, Hyomen 17(1981) 624.

    Google Scholar 

  168. E. Borgarello, K. Kalyanasundaram, Y. Okuno, and M. Grätzel, Hely. Chim. Acta 64(1981) 1937.

    CAS  Google Scholar 

  169. J. M. Lehn, J. P. Sauvage, and R. Ziessel, Nouveau J. Chim. 5(1981) 291.

    CAS  Google Scholar 

  170. P. Keller and A. Moradpour, J. Am. Chem. Soc. 102(1980) 7193.

    CAS  Google Scholar 

  171. N. Toshima, M. Kuriyama, Y. Yamada, and H. Hirai, Chem. Lett.1981, 793.

    Google Scholar 

  172. A. J. Frank and K. L. Stevenson, J. Chem. Soc. Chem. Commun.1981, 593.

    Google Scholar 

  173. J. R. Darwent, J. Chem. Soc. Faraday Trans. 2, 77 (1981) 1703.

    Google Scholar 

  174. C. K. Grätzel and M. Grätzel, J. Am. Chem. Soc. 101(1979) 7741.

    Google Scholar 

  175. T. Kawai and T. Sakata, Nature 282(1979) 283.

    CAS  Google Scholar 

  176. T. Kawai and T. Sakata, J. Chem. Soc. Chem. Commun.1979, 1047.

    Google Scholar 

  177. T. Kawai and T. Sakata, Nature 286(1980) 474.

    CAS  Google Scholar 

  178. M. Fujishira, Y. Satok, and T. Osa, Nature 293(1981) 206.

    Google Scholar 

  179. M. Fujishira, Y. Satok, and T. Osa, Chem. Lett.1981, 1053.

    Google Scholar 

  180. B. Kraeutler and A. Bard, J. Am. Chem. Soc. 100(1978) 5985.

    CAS  Google Scholar 

  181. B. Kraeutler and A. Bard, J. Am. Chem. Soc. 99(1977) 7724.

    Google Scholar 

  182. S. Sato and J. M. White, Chem. Phys. Lett. 70(1980) 131.

    CAS  Google Scholar 

  183. C. V. Krishan and N. Sutin, J. Am. Chem. Soc. 103(1981) 2141.

    Google Scholar 

  184. J. Kiwi and M. Grätzel, Angew. Chem. Int. Ed. 17(1978) 880.

    Google Scholar 

  185. J. Kiwi and M. Grätzel, Angew. Chem. Int. Ed. 18(1979) 624.

    Google Scholar 

  186. J. Kiwi and M. Grätzel, Chimia 33(1979) 289.

    CAS  Google Scholar 

  187. K. Kalyanasundaram, O. Micic, E. Promauro, and M. Grätzel, Hely. Chim. Acta 62(1979) 2432.

    CAS  Google Scholar 

  188. J. M. Lehn, J. P. Sauvage, and R. Ziessel, Nouveau J. Chim. 3(1979) 423.

    CAS  Google Scholar 

  189. J. M. Lehn, J. P. Sauvage, and R. Ziessel, Nouveau J. Chim. 4(1980) 355.

    CAS  Google Scholar 

  190. A. Mills and M. L. Zeeman, J. Chem. Soc. Chem. Commun.1981, 948.

    Google Scholar 

  191. S. Trassati and G. Lodi, in Electrodes of Conductive Metallic Oxides PtB, Ed. by S. Trassati, Elsevier, Amsterdam, 1981, pp. 521–627.

    Google Scholar 

  192. F. Bolletta, A. Juris, M. Maestri, and D. Sardini, Inorg. Chem. 1980, L-175.

    Google Scholar 

  193. M. Neumann-Spallart, K. Kalyanasundaram, C. K. Grätzel, and M. Grätzel, Helv. Chim. Acta 63(1980) 1111.

    CAS  Google Scholar 

  194. R. Humphry-Baker, J. Lilie, and M. Grätzel, J. Am. Chem. Soc. 104(1982) 422.

    CAS  Google Scholar 

  195. A. Henglein and J. Lilie, J. Am. Chem. Soc. 103(1981) 1059.

    CAS  Google Scholar 

  196. V. Ya. Shafirovich, N. K. Khannov, and V. V. Strelets, Nouveau J. Chim. 4(1980) 81.

    CAS  Google Scholar 

  197. E. R. Buyanova, L. G. Matvienko, A. I. Kokorin, G. L. Elizarova, V. N. Parmon, and K. I. Zamaraev, React. Kinet. Catal. Lett. 16(1981) 309.

    CAS  Google Scholar 

  198. G. L. Elizarova, L. G. Matvienko, N. V. Lozhkina, V. N. Parmon, and K. I. Zamaraev, React. Kinet. Catal. Lett. 16(1981) 191.

    CAS  Google Scholar 

  199. G. L. Elizarova, L. G. Matvienko, N. V. Lozhkina, V. E. Maizlish, and V. N. Parmon, React. Kinet. Catal. Lett. 16(1981) 285.

    CAS  Google Scholar 

  200. D. S. Miller and G. Mc. Lendon, submitted for publication.

    Google Scholar 

  201. M. Neumann-Spallart, Hely. Chim. Acta.

    Google Scholar 

  202. R. S. Nicholson and I. Shain, Anal. Chem. 36(1964) 706.

    CAS  Google Scholar 

  203. K. Kalyanasundaram and M. Grätzel, Angew. Chem. Int. Ed. 18(1979) 701.

    Google Scholar 

  204. P P. Infelta, J. Phys. Chem., submitted for publication.

    Google Scholar 

  205. J. Kiwi, E. Borgarello, E. Pelizzetti, M. Visca, and M. Grätzel, Angew. Chem. Int. Ed. 19(1980) 646.

    Google Scholar 

  206. G. Munuera, V. Rives-Arnau, and A. Saucedo, J. Chem. Soc. Faraday Trans. 1(1979) 736.

    Google Scholar 

  207. E. Borgarello, J. Kiwi, E. Pelizzetti, M. Visca, and M. Grätzel, J. Am. Chem. Soc. 103(1981) 6423.

    Google Scholar 

  208. A. Hamnet, M. P. Dare-Edwards, R. O. Wright, K. R. Seddon, and J. B. Goodenough, J. Phys. Chem. 83(1979) 3280.

    Google Scholar 

  209. W. D. K. Clark and N. Sutin, J. Am. Chem. Soc. 99(1977) 4676.

    CAS  Google Scholar 

  210. A. Mackor and J. Schoonman, Rec. J. Neth. Chem. Soc. 99(1980) 71.

    CAS  Google Scholar 

  211. E. Borgarello, J. Kiwi, E. Pelizzetti, M. Visca, and M. Grätzel, Nature 289(1981) 158.

    Google Scholar 

  212. T. Kawai and T. Sakata, Chem. Phys. Lett. 72(1980) 87.

    CAS  Google Scholar 

  213. S. Sato and J. M. White, Chem. Phys. 72(1980) 83.

    CAS  Google Scholar 

  214. G. N. Schrauzer and T. D. Guth, J. Am. Chem. Soc. 99(1977) 7189.

    CAS  Google Scholar 

  215. H. Van Damme and W. K. Hall, J. Am. Chem. Soc. 101(1979) 4373.

    Google Scholar 

  216. K. Domen, S. Naito, M. Soma, T. Onishi, and K. Tamaru, J. Chem. Soc. Chem. Commun.1980, 543.

    Google Scholar 

  217. F. T. Wagner and G. A. Somorjai, Nature 285(1980) 559.

    CAS  Google Scholar 

  218. J. M. Lehn, J. P. Sauvage, and R. Ziessel, Nouveau J. Chim. 4(1980) 623.

    CAS  Google Scholar 

  219. S. Sato and J. M. White, J. Catal. 69(1981) 128.

    CAS  Google Scholar 

  220. A. V. Bulatov and M. L. Khidekel, Izv. Akad. Nauk SSSR, Ser. Khim.1976, 1902.

    Google Scholar 

  221. E. Borgarello, J. Kiwi, E. Pelizzetti, M. Visca, and M. Grützel, J. Am. Chem. Soc.

    Google Scholar 

  222. F. Vanden Kerchove, J. Vandermolen, W. P. Gomes, and F. Cardon, Ber. Bunsenges. Phys. Chem. 83(1979) 230.

    Google Scholar 

  223. C. D. Jaeger and A. J. Bard, J. Phys. Chem. 24(1979) 3146.

    Google Scholar 

  224. E. Borgarello, K. Kalyanasundaram, M. Grützel, and E. Pelizzetti, Heiv. Chim. Acta.

    Google Scholar 

  225. A. J. Nozik, Appl. Phys. Lett. 30(1977) 567.

    Google Scholar 

  226. A. B. Ellis, S. W. Kaiser, and M. S. Wrighton, J. Am. Chem. Soc. 98(1976) 1635

    CAS  Google Scholar 

  227. A. B. Ellis, S. W. Kaiser, and M. S. Wrighton, J. Am. Chem. Soc. 94(1976) 6418

    Google Scholar 

  228. A. B. Ellis, S. W. Kaiser, and M. S. Wrighton, J. Am. Chem. Soc. 94(1976) 6855.

    Google Scholar 

  229. G. Hodes, J. Manassen, and D. Cohen, Nature 261(1976) 403.

    CAS  Google Scholar 

  230. B. Miller and A. Heller, Nature 262(1976) 680.

    CAS  Google Scholar 

  231. M. Halmann, Nature 275(1978) 115.

    CAS  Google Scholar 

  232. T. Inoue, A. Fujishima, S. Konishi, and K. Honda, Nature 277(1979) 637.

    Google Scholar 

  233. A. Aurian-Blajeni, M. Halmann, and J. Manassen, Solar Energy 25(1980) 165.

    Google Scholar 

  234. S. Tazuke and H. Ozawa, J. Chem. Soc. Chem. Commun.1975, 238.

    Google Scholar 

  235. B. Akermark, N. Eklund-Westlin, P. Baeckström, and R. Löt, Acta Chem. Scand. Ser. B 34(1980) 27.

    Google Scholar 

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Grätzel, M. (1983). Interfacial Charge Transfer Reactions in Colloidal Dispersions and Their Application to Water Cleavage by Visible Light. In: White, R.E., Bockris, J.O., Conway, B.E. (eds) Modern Aspects of Electrochemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-7461-3_2

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