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Equilibria in Condensed Phases

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Abstract

BY EQUATION (5.102) THE CHEMICAL potential μiis the contribution per mole of the ith constituent to the Gibbs energy in a homogeneous region. For equilibrium to exist between this region and a different homogeneous region, the chemical potentials must be equal following condition (6.102). In an ideal gas phase, μiis related to the pressure of the ith constituent by formula (7.40)

$$ {\mu _i} = \mu _i^0 + RT\ln {P_i} $$
(8.1)

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Authors and Affiliations

  1. South Dakota State University, Brookings, South Dakota

    George H. Duffey

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  1. George H. Duffey
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© 2000 Kluwer Academic/Plenum Publishers, New York

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Duffey, G.H. (2000). Equilibria in Condensed Phases. In: Modern Physical Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-4297-1_8

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  • DOI: https://doi.org/10.1007/978-1-4615-4297-1_8

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-0-306-46395-2

  • Online ISBN: 978-1-4615-4297-1

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