Skip to main content
SpringerLink
Log in

Modification of Polyvinyl Butyral Properties Via the Incorporation of Ionomer Groups

  • Chapter
Frontiers of Polymer Research

Abstract

Polyvinyl butyral ionomers (IPVB) were synthesized in order to modify some of the performance properties of polyvinyl butyral (PVB) used in safety glazings. The ionomers were synthesized via a condensation polymerization process in which ionic groups were permanently incorporated into the polyvinyl butyral backbone by using an ion-containing aldehyde in addition to butyraldehyde during the acetalization of polyvinyl alcohol. Several techniques including 1-H and 13-C NMR spectroscopy, dilute solution viscometry, dynamic mechanical analysis and differential scanning calorimetry were used to characterize the IPVB’s. Property modifications such as increased ambient temperature stiffness and high temperature flow comparable to PVB were observed in the IPVB’s.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
eBook
USD 16.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 99.00
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Similar content being viewed by others

References

  1. R.W. Rees and D.J. Vaughan, Polym. Prepr. Am. Chem. Soc., Div. Polym. Chem., 6, 287 (1965 a).

    CAS  Google Scholar 

  2. R.W. Rees and D.J. Vaughan, Polym. Prepr. Am. Chem. Soc., Div. Polym. Chem., 6, 296 (1965 b).

    Google Scholar 

  3. A. Eisenberg, Macromolecules, 3, 147 (1970).

    Article  CAS  Google Scholar 

  4. A. Eisenberg and M. Navratil, J. Polym. Sci., B, 10, 537 (1972).

    Article  CAS  Google Scholar 

  5. A. Eisenberg and M. Navratil, Macromolecules, 6, 604 (1973)

    Article  CAS  Google Scholar 

  6. A. Eisenberg and M. Navratil, Macromolecules 7, 90 (1974).

    Article  CAS  Google Scholar 

  7. W.J. Macknight, W.P. Taggert and R.S. Stein, J. Polym. Sci., Polym. Sym., 45, 113 (1974).

    Article  CAS  Google Scholar 

  8. W.J. Macknight, L.W. McKenna and B.E. Read, J. Appl. Phys., 38, 4208 (1967).

    Article  CAS  Google Scholar 

  9. P.J. Phillips and W.J. Macknight, J. Polym. Sci., A-2, 8, 727 (1970).

    Article  CAS  Google Scholar 

  10. A. Eisenberg, Adv. Polym. Sci., 5, 59 (1967).

    Article  CAS  Google Scholar 

  11. A. Eisenberg and M. King, “Ion-Containing Polymers”, Academic Press, New York, 1977.

    Google Scholar 

  12. W.J. Macknight and T.R. Earnest, Jr., J. Polym. Sci., Macromol. Rev., 16, 41 (1981).

    Article  CAS  Google Scholar 

  13. L. Holliday, Ed. “Ionic Polymers”, Halstead Press, Wiley, New York, 1975.

    Google Scholar 

  14. A. Eisenberg, Ed. “Ions in Polymers”, Adv. Chem. Ser., 187, Amer. Chem. Soc., Washington DC, 1980.

    Google Scholar 

  15. C.G. Bauzin and A. Eisenberg, Ind. Eng. Chem. Prod. Res. Dev., 20, 2, 271 (1981).

    Article  Google Scholar 

  16. E.P. Otocka, J. Macromol. Sci., C5, 275 (1971).

    Google Scholar 

  17. H.P. Brown, Rubber Chem. Technol., 30, 1347 (1957).

    Article  CAS  Google Scholar 

  18. K.F. Wissburn, Makromol. Chem., 118, 211, (1968).

    Article  Google Scholar 

  19. K. Sanui, R.W. Lenz and W.J. Macknight, J. Polym. Sci., Polym. Chem. Ed., 12, 1965 (1974).

    Article  CAS  Google Scholar 

  20. A. Noshay and L.M. Robeson, J. Appl. Polym. Sci., 20, 1885 (1976).

    Article  CAS  Google Scholar 

  21. G.O. Morrison, F.W. Skirrow and K.G. Blaikie (to Canadian Electro Products), U.S. Pat. 2,036,092 (Mar. 31, 1936), reissue 20,430 (June 29, 1937 ).

    Google Scholar 

  22. R.W. Hall (to General Electric Co.), U.S. Pat. 2,114,877 (Apr. 19, 1938 ).

    Google Scholar 

  23. H.F. Robertson (to Carbide and Carbon Chemical Corp.), U.S. Pat. 2,167,678 (June 13, 1939 ).

    Google Scholar 

  24. G.O. Morrison and A.F. Price (to Shawinigan Chemicals Ltd.), U.S. Pat, 2,168,827 (Aug. 8, 1939 ).

    Google Scholar 

  25. J. Dahle (to Monsanto Chemical Co.), U.S. Pat. 2,258,410 (Oct. 7, 1941 ).

    Google Scholar 

  26. W.H. Sharkey (to E.I. du Pont de Nemours & Co., Inc.), U.S. Pat. 2,396,209 (Mar. 5, 1946 ).

    Google Scholar 

  27. W.O. Kenyon and W.F. Fowler, Jr. (to Eastman Kodak Co.), U.S. Pat. 2,397,548 (Apr. 2, 1946 ).

    Google Scholar 

  28. E. Lavin, A.T. Marinaro and W.R. Richard (to Shawinigan Resins Corp.), U.S. Pat. 2,496,480 (Feb. 7, 1950 ).

    Google Scholar 

  29. E.H. Jackson and R.W. Hall (to General Electric Co.), U.S. Pat. 2,307,063 (Jan. 5, 1943 ).

    Google Scholar 

  30. W. Haehnel and W.O. Herrmann (to Consortium fur Elektrochemische Industrie), Ger. Pat. 507, 962 (1927).

    Google Scholar 

  31. H. Hopf (to I.G. Farben Industrie AG), U.S. Pat. 1,955, 068 (1934).

    Google Scholar 

  32. S. Nomura et. al. (to Sekesui Chemical Co.), U.S. Pat. 4,452,935 (Jun. 5, 1984 ).

    Google Scholar 

  33. H.D. Hermann et. al. (to Hoechst Aktiengesellschaft), U.S. Pat. 4,205,146 (May 27, 1980 ).

    Google Scholar 

  34. I. Tadoki et. al. (to Sekesui Chemical Co.), Jap. Pat. 30706 (Feb. 19, 1982 ).

    Google Scholar 

  35. P. Dauvergne (to Saint-Gobain Industries), U.K. Pat. 2,007,677 (Mar. 10, 1982 ).

    Google Scholar 

  36. G. E. Cartier and P.H. Farmer (to Monsanto Company), U.S. Pat. 4,874,814 (Oct. 17, 1989 ).

    Google Scholar 

  37. P.A. Berger, E.E. Remsen, G.C. Leo and D.J. David, accepted for publication in Macromolecules (May, 1991 ).

    Google Scholar 

  38. R.D. Lundberg, Polym. Prepr. Amer. Chem. Soc., Div. Polym. Chem., 19, 1, 455 (1978).

    CAS  Google Scholar 

  39. R.D. Lundberg and H.S. Makowski, Adv. Chem. Ser., no. 187, 21 (1980).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Monsanto Chemical Company, 730 Worcester Street, Springfield, MA, 01151, USA

    Arijit M. DasGupta & Donald J. David

  2. Indian Institute of Technology, Hauz Khas, New Delhi, 110016, India

    Ashok Misra

Authors
  1. Arijit M. DasGupta
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Donald J. David
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ashok Misra
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. State University of New York at Buffalo, Buffalo, New York, USA

    Paras N. Prasad

  2. Shriram Institute for Industrial Research, Delhi, India

    Jai K. Nigam

Rights and permissions

Reprints and permissions

Copyright information

© 1991 Springer Science+Business Media New York

About this chapter

Cite this chapter

DasGupta, A.M., David, D.J., Misra, A. (1991). Modification of Polyvinyl Butyral Properties Via the Incorporation of Ionomer Groups. In: Prasad, P.N., Nigam, J.K. (eds) Frontiers of Polymer Research. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-3856-1_64

Download citation

  • DOI: https://doi.org/10.1007/978-1-4615-3856-1_64

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-6721-5

  • Online ISBN: 978-1-4615-3856-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation