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Dielectric Properties and Materials

  • Robert M. Hill

Abstract

Elsewhere it has been noted(1) that what might well be the first area of experimental physics has benefited least by the quantum revolution. The area in question, of course, was that opened up by Thales of Milerus around 500 BC, when he is reported to have rubbed some amber with fur and noticed that the amber then attracted particles over small, but finite, distances and that this attractive property decayed in time. Frictional electricity, as it came to be called, was investigated by Faraday, who deduced that the effect was due to the induction of charges on the surface of the amber by the action of rubbing and the retention of these surface charges over a period of time. Both these properties are still required of a di-electric, or dielectric—viz., the storage of surface charge and a low rate of dissipation of this charge within the bulk of the material. In more conventional terms we say that a good dielectric has to have a high capacitance and a low leakage current.

Keywords

Dielectric Property Spectral Response Schottky Barrier Vinyl Chloride Dielectric Response 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    R. M. Hill and A. K. Jonscher, The dielectric behavior of condensed matter and its many-body interpretation, Contemp. Phys. 24, 75 - 110 (1983).CrossRefGoogle Scholar
  2. 2.
    P. Debye, Polar Molecules, Dover, New York (1945).Google Scholar
  3. 3.
    G. E. Johnson, E. W. Anderson, and T. Furukawa, Fourier transform dielectric spectroscopy utilizing a real time executive (RTE) system, IEEE Trans. Conf. Elec. Insul. Diel. Phenom.258–263 (1981).Google Scholar
  4. 4.
    R. M. Hill, Thin film dielectrics—The future, Thin Solid Films 100, 319 - 323 (1983).CrossRefGoogle Scholar
  5. 5.
    Y. Ishida, Studies in dielectric behavior of high polymers, Kolloid-Z. 168, 29–36 (1960).CrossRefGoogle Scholar
  6. 6.
    G. P. Johari, Glass transitions and secondary relaxations in molecular crystals, Ann. N.Y. Acad. Sci. 279, 117 - 140 (1976).CrossRefGoogle Scholar
  7. 7.
    R. M. Hill and L. A. Dissado, The temperature dependence of relaxation processes, J. Phys. C: Solid State Phys. 15, 5171 - 5193 (1982).CrossRefGoogle Scholar
  8. 8.
    K. Deguchi, E. Okaue, and E. Nakamura, Effect of deuterization on the dielectric properties of the ferroelectric CsH2PO4, J. Phys. Soc. Jpn. 51, 3569 - 3582 (1982).CrossRefGoogle Scholar
  9. 9.
    D. K. Davies, Charge generation on dielectric surfaces, Brit. J. Appl. Phys. (J. Phys. D.) 2, 1533–1537 (1969).Google Scholar
  10. 10.
    V. F. Mott, in Electronic and Structural Properties of Amorphous Semiconductors(P. G. Le Comber and J. Mort, eds.), pp. 1–54, Academic, London (1973).Google Scholar
  11. 11.
    N. F. Mott and E. A. Davis, Electronic Processes in Noncrystalline Materials, Oxford U.P., Oxford (1979).Google Scholar
  12. 12.
    I. Barsony and A. K. Jonscher, Dielectric properties of silicon p-n junctions, Solid State Electron. 21, 471–473 (1978).CrossRefGoogle Scholar
  13. 13.
    R. M. Hill and C. Pickup, Barrier effects in dispersive media, J. Mater. Sci. 20, 4431 - 4444 (1985).CrossRefGoogle Scholar
  14. 14.
    L. A. Dissado, R. C. Rowe, A. Haidar, and R. M. Hill, The characterization of heterogeneous gels by means of a dielectric technique. I. Theory and preliminary evaluation, J. Colloid Interface Sci. 117, 310 - 324 (1987).CrossRefGoogle Scholar
  15. 15.
    R. C. Rowe, L. A. Dissado, S. H. Zaidi, and R. M. Hill, The characterization of heterogeneous gels by means of a dielectric technique. II. Formulation and structural considerations, J. Colloid Interface Sci. 112, 354 - 366 (1988).CrossRefGoogle Scholar
  16. 16.
    D. P. Almond, G. K. Duncan, and A. R. West, The determination of hopping rates and carrier concentrations in ionic conduction by a new analysis of ac conductivity, Solid State Ionics 8, 159 - 164 (1983).CrossRefGoogle Scholar
  17. 17.
    A. K. Jonscher, Low frequency dispersion in carrier-dominated dielectrics, Phil. Mag. B38, 587 - 601 (1978).CrossRefGoogle Scholar
  18. 18.
    L. A. Dissado and R. M. Hill, Anomalous low frequency dispersion—A quasi-dc response, J. Chem. Soc. Trans. Faraday Soc. 2 80, 291 - 317 (1984).CrossRefGoogle Scholar
  19. 19.
    L. A. Dissado and R. M. Hill, A cluster approach to the structure of imperfect materials and their relaxation spectroscopy, Proc. R. Soc. London Ser. A 390, 131 - 180 (1983).CrossRefGoogle Scholar
  20. 20.
    J. J. Hopfield, Infrared divergence, X-ray edges, and all that, Commun. Solid State Phys. 11, 40–49 (1969).Google Scholar
  21. 21.
    M. Abramowitz and I. A. Stegun, Handbook of Mathematical Functions, Dover, New York (1970), Chap. 15.Google Scholar
  22. 22.
    R. M. Hill, L. A. Dissado, and R. Jackson, The examination of correlated noise, J. Phys. C: Solid State Phys. 14, 3915 - 3925 (1981).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 1991

Authors and Affiliations

  • Robert M. Hill
    • 1
  1. 1.Department of PhysicsKing’s College LondonLondonUK

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