Abstract
It is commonly accepted that in a hydrogen volume source the negative hydrogen ions H- are formed by dissociative attachment of slow plasma electrons e to vibrationally excited molecules H2 *(v″), where v″ is the vibrational quantum number.1,2 The vibrational excitation is attributed to electron impact excitation of hydrogen molecules H2 by the fast primary electrons ef in the discharge.3 To clarify the mechanism of H- production and to show the dependence of H- ions on plasma parameters concretely, we have proposed a set of particle balapce equations for a steady-state hydrogen plasma in a single chamber system.4,5 According to our recent simulation results,6–8 most H- ions are produced by the two-step process mentioned above, i.e. H2+ef→H2 *(v″)+ef; H2 *(v″)+e→H-+H. Besides, the presence of ef with energies Efe in excess of 40 eV is reasonable for H2 *(v″) production while plasma electrons e with electron temperature \( {{T}_{e}} \cong 1eV \) are optimum for H- formation.
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Fukumasa, O., Ohashi, S. (1990). Numerical Simulation on Tandem Negative Ion Source. In: Capitelli, M., Bardsley, J.N. (eds) Nonequilibrium Processes in Partially Ionized Gases. NATO ASI Series, vol 220. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-3780-9_40
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