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Theory

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Membrane Handbook

Abstract

Pervaporation through a nonporous membrane can be described by the widely accepted solution-diffusion mechanism (Binning and James 1958a, 1958b; Binning et al. 1961). The underlying assumptions of pervaporative transport are:

  1. 1

    Sorption of the liquid mixture on the feed (upstream) side of the membrane

  2. 2

    Diffusion through the membrane

  3. 3

    Desorption on the permeate (downstream) side of the membrane in the vapor phase.

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References

  • Binning, R. C., and F. E. James. 1958a. Now separate by membrane permeation. Petrol. Refiner. 37:214.

    CAS  Google Scholar 

  • Binning, R. C., and F. E. James. 1958b. Permeation: a new way to separate mixtures. Oil Gas J. 56(21):104–105.

    Google Scholar 

  • Binning, R. C., R. J. Lee, J. F. Jennings, and E. C. Martin. 1961. Separation of liquid mixture by permeation. Ind. Eng. Chem. 53:45–50.

    Article  Google Scholar 

  • Brun, J-P., C. Larchet, R. Melet, and G. Bulvestre. 1985. Modelling of the pervaporation of binary mixtures through moderately swelling, non-reacting membranes. J. Membr. Sci. 23:257–283.

    Article  CAS  Google Scholar 

  • Duggal, A., and E. V. Thompson. 1986. Dependence of diffusive permeation rates on upstream and downstream pressures: VI. experimental results for the water/ethanol system. J. Membr. Sci. 27:13–30.

    Article  CAS  Google Scholar 

  • Fels, M., and R. Y. M. Huang. 1971. Theoretical interpretation of the effect of mixture composition on separation of liquids in polymers. J. Macro-mol. Sci. 5:89–110.

    Article  CAS  Google Scholar 

  • Flory, P. 1953. Principles of Polymer Chemistry. Ithaca NY: Cornell University Press.

    Google Scholar 

  • Fujita, H. 1961. Diffusion in polymer diluent sys-tems. Forschr. Hochpolym. Forsch. 3:1–47.

    Article  CAS  Google Scholar 

  • Greenlaw, F. W., W. D. Prince, R. A. Shelden, and E. V. Thompson. 1977. Dependence of diffusive permeation rates on upstream and downstream pressures: 1. single component permeant. J. Membr. Sci. 2:141–151.

    Article  CAS  Google Scholar 

  • Greenlaw, F. W., R. A. Shelden, and E. V. Thompson. 1977. Dependence of diffusive permeation rates on upstream and downstream pressures: II. two component permeant. J. Membr. Sci. 2:333–348.

    Article  CAS  Google Scholar 

  • Knight, K. F., A. Duggal, R. A. Shelden, and E. V. Thompson. 1986. Dependence of diffusive permeation rates on upstream and downstream pressures: V. experimental results for the hexane/ heptane (ideal) and toluene/ethanol (non-ideal) systems. J. Membr. Sci. 26:31–50.

    Article  CAS  Google Scholar 

  • Long, R. B. 1965. Liquid permeation through plastic films. Ind. Eng. Chem. Fundam. 4:445–451.

    Article  CAS  Google Scholar 

  • Mulder, M. H. V., T. Franken, and C. A. Smolders. 1985. Preferential sorption versus preferential permeability in pervaporation. J. Membr. Sci. 22:155–173.

    Article  CAS  Google Scholar 

  • Mulder, M. H. V., and C. A. Smolders. 1984. On the mechanism of separation of ethanol/water mixtures by pervaporation: 1. calculation of concentration profiles. J. Membr. Sci. 17:289–307.

    Article  CAS  Google Scholar 

  • Mulder, M. H. V., and C. A. Smolders. 1986. Pervaporation solubility aspects of the solution-diffusion model. Sep. Purif. Methods 15:1–19.

    Article  CAS  Google Scholar 

  • Nguyen, T. Q. 1987. Modelling of the influence of downstream pressure for highly selective pervaporation. J. Membr. Sci. 34:165–183.

    Article  Google Scholar 

  • Rautenbach, R., and R. Albrecht. 1985a. The separation potential of pervaporation: part 1. discussion of transport equations and comparison with reverse osmosis. J. Membr. Sci. 25:1–23.

    Article  CAS  Google Scholar 

  • Rautenbach, R., and R. Albrecht. 1985b. The separation potential of pervaporation: part 2. process design and economics. J. Membr. Sci. 25:25–54.

    Article  CAS  Google Scholar 

  • Rautenbach, R., and R. Albrecht. 1989. Membrane Processes. New York: John Wiley & Sons.

    Google Scholar 

  • Rogers, C. E., V. Stannett, and M. Szwarc. 1960. The sorption, diffusion, and permeation of organic vapors in polyethylene. J. Polymer Sci. 45:6182.

    Google Scholar 

  • Sferrazza, R. A., R. Escobosa, and C. H. Gooding. 1988. Estimation of parameters in a sorption-diffusion model of pervaporation. J. Membr. Sci. 35:125–136.

    Article  CAS  Google Scholar 

  • Sferrazza, R. A., and C. H. Gooding. 1987. Determination of sorption selectivity by liquid chromatography. In Proceedings of the Second International Conference on Pervaporation Processes in the Chemical Industry ed. R. A. Bakish, pp. 186–199. Englewood, NJ: Bakish Materials Corporation.

    Google Scholar 

  • Shelden, R. A., and E. V. Thompson. 1978. Dependence of diffusive permeation rates on upstream and downstream pressures: III. membrane selectivity and implications for separations processes. J. Membr. Sci. 4:115–127.

    Article  CAS  Google Scholar 

  • Shelden, R. A., and E. V. Thompson. 1984. Dependence of diffusive permeation rates on upstream and downstream pressures: IV. computer simulation of non-ideal systems. J. Membr. Sci. 19:39–49.

    Article  Google Scholar 

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© 1992 Springer Science+Business Media New York

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Fleming, H.L., Slater, C.S. (1992). Theory. In: Ho, W.S.W., Sirkar, K.K. (eds) Membrane Handbook. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-3548-5_8

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  • DOI: https://doi.org/10.1007/978-1-4615-3548-5_8

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-6575-4

  • Online ISBN: 978-1-4615-3548-5

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