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Oligomeric Hydrolyzable Tannins From Liquidambar Formosana and Spectral Analysis of the Orientation of Valoneoyl Groups in Their Molecules

  • Tsutomu Hatano
  • Akira Okonogi
  • Takuo Okuda
Part of the Basic Life Sciences book series (BLSC, volume 59)

Abstract

The leaves of Liquidambar formosana (Hamamelidaceae), used as herbal medicines, contain a complex array of hydrolyzable tannins including dimers and trimers. The structures of the dimer isorugosin E (11) and the trimer isorugosin G (12) were defined for the first time. In addition, application of NMR and CD spectroscopic data permitted assignment of the orientation of the valoneoyl groups in the isomeric pairs of dimers (11) and rugosin E (14) as well as the trimers (12) and rugosin G (20). The rules defined for these compounds are applicable to assignment of the structure of other isomeric pairs.

Keywords

Upfield Shift Hydrolyzable Tannin Anomeric Carbon Isomeric Pair Anomeric Center 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 1992

Authors and Affiliations

  • Tsutomu Hatano
    • 1
  • Akira Okonogi
    • 1
  • Takuo Okuda
    • 1
  1. 1.Faculty of Pharmaceutical SciencesOkayama UniversityTsushima, Okayama 700Japan

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