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Biomimetic Oxidation of Cyclohexane Using the Gif-Krict System

  • Kyu-Wan Lee
  • Seong-Bo Kim
  • Ki-Won Jun

Abstract

Gif systems were originally designed to mimic non-heme enzymatic oxidation of alkanes. All of them involve a pyridine-acetic acid (or other carboxylic acid) solution of the hydrocarbon being oxidized, an iron-based catalyst, and an electron source. However, Gif systems have a ploblem in the separation of catalyst because the homogeneous catalytic systems are employed. Thus, we have modified the GifIV system by using heterogeneous catalysts, iron oxide supported on silica, and then the results are reported in this paper.

Keywords

Heterogeneous Catalyst Catalytic Oxidation Metallic Iron Electron Source Iron Catalyst 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Copyright information

© Springer Science+Business Media New York 1993

Authors and Affiliations

  • Kyu-Wan Lee
    • 1
  • Seong-Bo Kim
    • 1
  • Ki-Won Jun
    • 1
  1. 1.Catalysis Research DivisionKorea Research Institute of Chemical TechnologyDaedeog-Danji, TaejonKorea

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