Oxidation of Amines and Imines by Mo(VI) and W(VI) Peroxopolyoxo Complexes

  • Francesco Paolo Ballistreri
  • Gaetano Andrea Tomaselli
  • Rosa Maria Toscano

Abstract

Mo(VI) and W(VI) peroxopolyoxo complexes have been shown to be versatile oxidant agents toward a large variety of organic compounds. They can be employed as stoichiometric reagents or catalitically in the presence of dilute hydrogen peroxide as oxygen source. The application of suitable phase transfer techniques has played a relevant role in the development of such oxidation catalytic processes.

Keywords

Hydrogen Peroxide Sulfide Alkene Alkyne Sulfoxide 

References

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    Ballistreri, F.P.; Failla, S.; Tomaselli, G.A. J. Org. Chem. 1988, 53, 830CrossRefGoogle Scholar
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    Ballistreri, F.P.; Failla, S.; Spina, E.; Tomaselli, G.A. J. Org. Chem. 1989, 54, 947.CrossRefGoogle Scholar
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    Ballistreri, F.P.; Tomaselli, G.A.; Toscano, R.M. J. Mol. Cat. 1991, 68, 269CrossRefGoogle Scholar
  4. (2b).
    Ballistreri, F.P.; Tomaselli, G.A.; Toscano, R.M.; Conte, V.; Di Furia, F. J.Am.Chem.Soc. 1991, 113, 6209CrossRefGoogle Scholar
  5. (2c).
    Ballistreri, F.P.; Bazzo, A.; Tomaselli, G.A.; Toscano, R.M. J.Org.Chem. in press.Google Scholar

Copyright information

© Springer Science+Business Media New York 1993

Authors and Affiliations

  • Francesco Paolo Ballistreri
    • 1
  • Gaetano Andrea Tomaselli
    • 1
  • Rosa Maria Toscano
    • 1
  1. 1.Dipartimento Scienze ChimicheUniversity of CataniaCataniaItaly

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