Oxidation of Amines and Imines by Mo(VI) and W(VI) Peroxopolyoxo Complexes
Mo(VI) and W(VI) peroxopolyoxo complexes have been shown to be versatile oxidant agents toward a large variety of organic compounds. They can be employed as stoichiometric reagents or catalitically in the presence of dilute hydrogen peroxide as oxygen source. The application of suitable phase transfer techniques has played a relevant role in the development of such oxidation catalytic processes.
KeywordsHydrogen Peroxide Sulfide Alkene Alkyne Sulfoxide
- (2c).Ballistreri, F.P.; Bazzo, A.; Tomaselli, G.A.; Toscano, R.M. J.Org.Chem. in press.Google Scholar