Abstract
The finding of new efficient and selective oxidation catalysts is an important challenge in fine chemistry and in bulk chemicals manufacture. In fact, the synthesis of many of the main chemicals of industrial chemistry, like ethylene and propylene oxides, phenol or terephthalic acid, involve oxidation catalysts. There is an always increasing demand of more efficient and selective catalysts for the transfer of oxygen atoms from readily available and cheap oxygen atom donors like O2, H2O2 or alkylhydroperoxides (eq.1). In that respect, the hydroxylation of inert C-H bonds of alkanes under mild conditions, the enantioselective epoxidation of alkenes and the regioselective hydroxylation of aromatic rings by those oxygen atom donors remain very interesting challenges in organic chemistry.
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Mansuy, D. (1993). New Model Systems for Oxygenases. In: Barton, D.H.R., Martell, A.E., Sawyer, D.T. (eds) The Activation of Dioxygen and Homogeneous Catalytic Oxidation. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-3000-8_25
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DOI: https://doi.org/10.1007/978-1-4615-3000-8_25
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