Abstract
Upgrading the value of raw materials by the selective conversion of organic molecules to oxygenated derivatives using air as an oxidant represents a worthy goal and challenge. Industrially, oxygenates are prepared at a rate of 109 to 1010 lbs/year, mostly using high temperature (above 100°C) processes.1 Since, in general, the oxygenated products are more reactive then the starting hydrocarbons, secondary reactions which lower the selectivity occur.
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Bond, J.E., Gorun, S.M., Stibrany, R.T., Schriver, G.W., Vanderspurt, T.H. (1993). Bioinspired Catalysis: Hydroperoxidation of Alkylaromatics. In: Barton, D.H.R., Martell, A.E., Sawyer, D.T. (eds) The Activation of Dioxygen and Homogeneous Catalytic Oxidation. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-3000-8_15
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DOI: https://doi.org/10.1007/978-1-4615-3000-8_15
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