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Oxygenation of Olefins with Molecular Oxygen Catalyzed by Low Valent Metal Complexes

  • Chapter
The Activation of Dioxygen and Homogeneous Catalytic Oxidation

Abstract

Molecular oxygen is often expected to be the easily available oxidant, but its utilization in organic synthesis has been restricted to several reactions because of the difficulties in carrying a desired reaction out exclusively. Molecular oxygen is caputured and activated by transition-metal complexes coordinated by organic ligands whose stereochmical and electrochemical properties could be tuned by modofication of its ligand systems. Several new and efficient synthetic oxidation reactions of olefins using molecular oxygen were recently developed based on the above concept.

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Author information

Authors and Affiliations

  1. Department of Applied Chemistry, Faculty of Science, Science University of Tokyo, Kagurazaka, Shinjuku-ku, Tokyo 162, Japan

    Teruaki Mukaiyama

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  1. Teruaki Mukaiyama
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Editor information

Editors and Affiliations

  1. Texas A&M University, College Station, Texas, USA

    Derek H. R. Barton , Arthur E. Martell  & Donald T. Sawyer ,  & 

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Mukaiyama, T. (1993). Oxygenation of Olefins with Molecular Oxygen Catalyzed by Low Valent Metal Complexes. In: Barton, D.H.R., Martell, A.E., Sawyer, D.T. (eds) The Activation of Dioxygen and Homogeneous Catalytic Oxidation. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-3000-8_11

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  • DOI: https://doi.org/10.1007/978-1-4615-3000-8_11

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-6307-1

  • Online ISBN: 978-1-4615-3000-8

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