Abstract
Chemically modified silica surfaces have been synthesized and characterized as model olefin polymerization catalysts. By variation of silica gel pretreatments, TiC14 can be reacted with various surface bonding geometries. Most surface characterization was done acing diffuse reflectance FTIR spectroscopy. The TiC14 reacted silica gels, after reaction with Al(Et)3, give catalysts which polymerize ethylene and 1-butene with different activities and comonomer incorporation.
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© 1993 Springer Science+Business Media New York
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Blitz, J.P. (1993). Model Silica Supported Olefin Polymerization Catalysts. In: Chung, T.C. (eds) New Advances in Polyolefins. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-2992-7_1
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DOI: https://doi.org/10.1007/978-1-4615-2992-7_1
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