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Formation of FeIII or FeII Complexes with Acetylaceto-Nate and 5,6,7,8-Tetrahydropterin as Ligands and Their Activation of Oxygen

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Chemistry and Biology of Pteridines and Folates

Part of the book series: Advances in Experimental Medicine and Biology ((AEMB,volume 338))

Abstract

The formation of a FeIII ⇋FeII complex 3a ⇋ 3b with acetylacetonate [acac] and N(5)-methyl-5,6,7,8-tetrahydropterin [N(5)MTHP] (1) as ligands was demonstrated by electrospray ionization mass spectrometry (ESI-MS)1,2.

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References

  1. B. Fischer, A. Schäfer, R. Bosshard, M. Hesse, and M. Viscontini,“6th International Conference on Pteridines and Related Biogenic Amines and Folates”, N. Blau, H. Ch. Curtius, R. Levine, J. Yim, eds., Hanrim Publishing Comp., 56–1 Soopydong, Chung-ku, Seoul 100–230, South Korea (1992), 35.

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  2. A. Schäfer, B. Fischer, H. Paul, R. Bosshard, M. Hesse, and M. Viscontini, Helv. Chim.Acta 75:1955, (1992).

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Author information

Authors and Affiliations

  1. Organisch-chemisches Institut der Universität, Winterthurerstrasse 190, CH-8057, Zürich, Switzerland

    Andrea Schäfer, Manfred Hesse & Max Viscontini

  2. Anorganisch-chemisches Institut der Universität, Winterthurerstrasse 190, CH-8057, Zürich, Switzerland

    Berthold Fischer

  3. Abteilung Klinische Chemie, Kinderspital der Universität, Stein-wiesstrasse 75, CH-8032, Zürich, Switzerland

    René Bosshard

Authors
  1. Andrea Schäfer
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  2. Berthold Fischer
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  3. René Bosshard
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  4. Manfred Hesse
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  5. Max Viscontini
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Editor information

Editors and Affiliations

  1. Dept of Pharmacology College of Medicine, Universily of South Alabama, Mobile, AL, 36688, USA

    June E. Ayling

  2. Dept. of Biochemistry College of Medicine, University of South Alabama, Mobile, AL, 36688, USA

    M. Gopal Nair

  3. College of Medicine, Universily of South Alabama, Mobile, AL, 36688, USA

    Charles M. Baugh

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© 1993 Springer Science+Business Media New York

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Schäfer, A., Fischer, B., Bosshard, R., Hesse, M., Viscontini, M. (1993). Formation of FeIII or FeII Complexes with Acetylaceto-Nate and 5,6,7,8-Tetrahydropterin as Ligands and Their Activation of Oxygen. In: Ayling, J.E., Nair, M.G., Baugh, C.M. (eds) Chemistry and Biology of Pteridines and Folates. Advances in Experimental Medicine and Biology, vol 338. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-2960-6_5

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  • DOI: https://doi.org/10.1007/978-1-4615-2960-6_5

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-6287-6

  • Online ISBN: 978-1-4615-2960-6

  • eBook Packages: Springer Book Archive

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