Abstract
At low temperatures and high pressures, icelike crystalline inclusion compounds, gas hydrates, may form when high concentrations of methane and water cooccur in subsurface strata. Sediments in large areas of the permafrost and on the outer continental margins of the oceans occur within the appropriate temperature and pressure regime for hydrates to be stable. Since Makogon (1965) first reported the occurrence of hydrates in permafrost regions, it has been determined that an even larger reservoir of hydrate gas is probably present in marine sediments (Fig. 1). Estimates of the amount of hydrate gas in permafrost and oceanic sediments vary from 1.4 × 1013 to 3.4 × 1016 and from 3.1 × 1015 to 7.6 × 1018 m3, respectively (Kvenvolden, 1988). The reservoir of hydrates in oceanic sediments is believed to be at least two orders of magnitude greater than that in permafrost regions. Given these two repositories of hydrates, even the most conservative estimates indicate the enormity of the carbon reservoir. On a global scale, it has been estimated that the only pool of organic carbon larger than methane hydrates is disseminated carbon in sediments and rocks (Kvenvolden, 1988). It has been estimated that the natural gas reservoired in hydrates surpasses total fossil fuel reserves by as much as a factor of 2 (Kvenvolden, 1988). Hydrates represent a substantial energy resource of the future if the appropriate technologies can be developed for their recovery.
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References
Bell, P. R., 1983, Methane hydrate and the carbon dioxide question, in: Carbon Dioxide Review, 1982 (W. C. Clark, ed.), Oxford University Press, New York, pp. 401–406.
Bernard, B. B., Brooks, J. M., and Sackett, W. M., 1977, A geochemi-cal model for characterizing hydrocarbon gas sources in marine sediments, in: Proceedings of Offshore TechnoJogy Conference OTC 2934, OTC, Houston, pp. 435–438.
Brooks, J. M., Barnard, L. A., Weisenberg, D. A., Kennicutt, M. C., II, and Kvenvolden, K. A., 1983, Molecular and isotopic compositions of hydrocarbons at Site 533, DSDP Leg 76, in Initial Reports of Deep Sea Drilling Project, Vol. 76 (R. E. Sheridan, F. M., Gradstein, et al., eds.), U.S. Government Printing Office, Washington, D.C., pp. 337–390.
Brooks, J. M., Kennicutt, M. C., II, Fay, R. R., McDonald, T. J., and Sassen, R., 1984, Thermogenic gas hydrates in the Gulf of Mexico, Science 225:409–411.
Brooks, J. M., Jeffrey, A. W. A., McDonald, T. J., Pflaum, R. C., and Kvenvolden, K. A., 1985, Analysis of hydrate gas and water from Site 570 DSDP Leg 84, in: Initial Reports of Deep Sea Drilling Project, Vol. 84 (R. von Huene, J. Aubouin et al., eds), U.S. Government Printing Office, Washington, D.C., pp. 699–704.
Brooks, J. M., Cox, H. B., Bryan, W. R., Kennicutt, M. C., II, Mann, R. G., and McDonald, T. J., 1986, Association of gas hydrates and oil seepage in the Gulf of Mexico, Org. Geochem. 10:221–234.
Brooks, J. M., Field, M. E., and Kennicutt, M. C., II, 1991, Observations of gas hydrates offshore northern California, Mar. Geol. 96:103–109.
Carpenter, G., 1981, Coincident sediment slum/clathrate complexes on the U.S. Atlantic continental slope, Geo-Mar. Lett. 1:29–32.
Chamberlain, J. W., Foley, H. M., MacDonald, G. J., and Ruderman, M. A., 1983, Climate effects of minor atmospheric constituents, in: Carbon Dioxide Review, 1982 (W. C. Clark, ed.), Oxford University Press, New York, pp. 255–277.
Claypool, G. E., and Kvenvolden, K. A., 1983, Methane and other hydrocarbon gases in marine sediment, Annu. Rev. Earth Planet. Sci. 11:294–297.
Dillon, W. P., Grow, J. A., and Pauli, C. K., 1980, Unconventional gas hydrate seals may trap gas off the southeastern U.S., Oil Gas J. 1980 (January 7):124–130.
Field, M. E., and Kvenvolden, K. A., 1985, Gas hydrates on the northern California continental margin, Geology 13:517–520.
Hand, J. H., Katz, D. L., and Verma, V. K., 1974, Review of gas hydrates with implication for ocean sediments, in: Natural Gases in Marine Sediments (I. R. Kaplan, ed.), Plenum Press, New York, pp. 179–194.
Harrison, W. E., and Curiale, J. A., 1982, Gas hydrates in sediments of holes 497 and 498A DSDP Leg 67, in: Initial Reports of Deep Sea Drilling Project, Vol. 67 (J. Aubouin, R. von Huene, et al., eds.), U.S. Government Printing Office, Washington, D.C., pp. 591–594.
Hedberg, H. D., 1980, Methane generation and petroleum migration, in Problems of Petroleum Migration (W. H. Robers, III and R. J. Cordell, eds.), AAPG Studies in Geology No. 10, American Association of Petroleum Geologists, Tulsa, Oklahoma, pp. 179–206.
Hein, J. R., Scholl, D. W., Barron, J. A., Jones, M. G., and Miller, J., 1978, Diagenesis of later Cenozoic diatomaceous deposits and formation of the bottom simulating reflector in the southern Bering Sea, Sedimentology 25:155–181.
Hesse, R., 1990, Pore-water anomalies in gas hydrate-bearing sediments of the deeper continental margins: Facts and problems, J. Inclusion Phenom. Mol. Recognit. Chem. 8:117–138.
Hesse, R., and Harrison, W. E., 1981, Gas hydrates (clathrates) causing pore-water freshening and oxygen isotope fractionation in deep-water sedimentary sections of terrigenous continental margins, Earth Planet. Sci. Lett. 55:453–462.
Hitchon, B., 1974, Occurrence of natural gas hydrates in sedimentary basins, in: Natural Gases in Marine Sediments (I. R. Kaplan, ed.), Plenum Press, New York, pp. 195–225.
Hollister, C. D., Ewing, J. I., Habib, D., Hathaway, J. C., Lancelot, Y., Luterbacher, H., Paulus, F. J., Poag, C. W., Wilcoxon, J. A., and Worstell, P., 1972, Sites 102-103-104 Blake-Bahama Outer Ridge (Northern End), in: Initial Reports of Deep Sea Drilling Project, Vol. 11 (C. D. Hollister, J. I. Ewing et al., eds.), U.S. Government Printing Office, Washington, D.C., pp. 135–143.
Hunt, J. M., 1979, Methane hydrates, in: Petroleum Geochemistry and Geology (J. M. Hunt, ed.), W. H. Freeman and Co., San Francisco, pp. 156–162.
Jeffrey, A. W A., Pflaum, R. C., McDonald, T. J., Brooks, J. M., and Kvenvolden, K. A., 1985, Isotopic analysis of core gases at site 565–570, in: Initial Reports of Deep Sea Drilling Project, Vol. 84 (R. von Huene, J. Aubouin et al., eds.), U.S. Government Printing Office, Washington, D.C., pp. 719–726.
John, V T., and Holder, G. D., 1982, Hydrates of methane + n-bu-tane below the ice point, J. Chem. Eng. 27:18–21.
Katz, D. L., Cornell, D., Kobayashi, R., Poettmann, F. H., Vary, J. A., Elenbaas, J. R., and Winaug, C. F., 1959, Handhook of Natural Gas Engineering, McGraw-Hill, New York.
Kvenvolden, K. A., 1988, Methane hydrate—a major reservoir of carbon in the shallow geosphere? Chem. Geol. 71:41–51.
Kvenvolden, K. A., and Barnard, L.A., 1983, Gas hydrates of the Blake Outer Ridge, Site 533, DSDP Leg 76, in: Initial Reports of Deep Sea Drilling Project, Vol. 76 (R. E. Sheridan, F. M. Gradstein, et al., eds.), U.S. Government Printing Office, Washington, D.C., pp. 353–365.
Kvenvolden, K. A., and Kastner, M., in press, Gas hydrates of the Peruvian continental margin, in: Initial Reports ODP, Vol. 112, U.S. Government Printing Office, Washington, D.C.
Kvenvolden, K. A., and McDonald, T. J., 1985, Gas hydrates of the Middle America Trench-DSDP/IPOD Leg 84, in: Initial Reports of Deep Sea Drilling Project, Vol. 84 (R. von Huene, J. Aubouin, et al., eds.), U.S. Government Printing Office, Washington, D.C., pp. 667–682.
Kvenvolden, K. A., Claypool, G. E., Threlkeld, C. N., and Dendy, E., 1984, Geochemistry of a naturally occurring massive marine gas hydrate, Org. Geochem. 6:703–713.
Kvenvolden, K. A., and McMenamin, M. A., 1980, Hydrates of natural gas: A review of their geologic occurrence, U.S. Geol. Surv. Circ. 825.
MacDonald, G. J., 1982, The Long-Term impacts of increasing Atmospheric Carbon Dioxide Levels, Ballinger, Cambridge, Massachusetts.
MacLeod, M. K., 1982, Gas hydrates in ocean bottom sediments, Am. Assoc. Petrol. Geol. Bull. 66:2649–2662.
Makogon, Y. F., 1965, Hydrate formation in gas bearing strata in permafrost regions, Gazov. Promst. Izd. Nedra 5.
Makogon, Y. F., 1981, Hydrates of Natural Gas, Pennwell Publishing Co., Tulsa, Oklahoma [translation by W. J. Cieslewicz].
Markl, R. G., Bryan, G. M., and Ewing, J. I., 1970, Structure of the Blake-Bahama Outer Ridge, J. Geophys. Res. 75:4539–4555.
Miller, S. L., 1974, The nature and occurrence of clathrate hydrates, in: Natural Gases in Marine Sediments (I. R. Kaplan, ed.), Plenum Press, New York, pp. 151–178.
Ng, H. J., and Robinson, D. B., 1976, The role of n-butane in hydrate formation, AIChE J. 22:656–661.
Pflaum, R. C., Brooks, J. M., Cox, H. B., Kennicutt, M. C., II, and Sheu, D. D., 1986, Molecular and isotopic analysis of core gases and gas hydrates from sites 618 and 619, DSDP Leg 96, in: Initial Reports of Deep Sea Drilling Project, Vol. 96 (A. H. Bouma, J. M. Coleman, et al., eds.), U.S. Government Printing Office, Washington, D.C., pp. 781–784.
Prior, D. B., Doyle, E. H., and Kaluza, M. J., 1989, Evidence for sediment eruption on deep sea floor, Gulf of Mexico, Science 243:517–519.
Revelle, R. R., 1983, Methane hydrates in continental slope sediments and increasing atmospheric carbon dioxide, in: Changing Climates, National Academy Press, Washington, D.C., pp. 252–261.
Scholl, D. W., and Creager, J. S., 1973, Geologic synthesis of Leg 19 (DSDP) results for North Pacific and Aleutian Ridge, and Bering Sea, in: Initial Reports of Deep Sea Drilling Project, Vol. 19 (J. S. Creager, D. W. Scholl, et al., eds.), U.S. Government Printing Office, Washington, D.C., pp. 897–913.
Shipley, T. H., and Didyk, B. M., 1982, Occurrence of methane hydrates offshore southern Mexico, in: Initial Reports of Deep Sea Drilling Project, Vol. 66 (J. S. Watkins, J. C. Moore, et al., eds.), U.S. Government Printing Office, Washington, D.C., pp. 547–555.
Shipley, T. H., Houston, M. H., Buffler, R. T., Shaub, F. J., McMillen, K. J., Ladd, J. W., and Worzel, J. L., 1979, Seismic evidence for widespread possible gas hydrate horizons on continental slopes and rises, Am. Assoc. Petrol. Geol. Bull. 63:2204–2213.
Sloan, E. D., 1989, Clathrate Hydrates of Natural Gases, Marcel Dekker, New York.
Stoll, R. D., Ewing, J., and Bryan, G. M., 1971, Anomalous wave velocities in sediments containing gas hydrates, J. Geophys. Res. 76:2090–2094.
von Huene, R., Ladd, J., and Norton, I., 1982, Geophysical observations of slope deposits, Middle America Trench off Guatemala, in: Initial Reports of Deep Sea Drilling Project, Vol. 67 (J. Aubouin, R. von Huene, et al., eds.), U.S. Government Printing Office, Washington, D.C., pp. 719–732.
Yefremova, A. G., and Zhizhchencko, B. P., 1974, Occurrence of crystal hydrates of gases in the sediments of modern marine basins, Dokl. Akad. Nauk SSSR, Earth Science Section [Engl. translation 1975], 214:219–220.
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Kennicutt, M.C., Brooks, J.M., Cox, H.B. (1993). The Origin and Distribution of Gas Hydrates in Marine Sediments. In: Engel, M.H., Macko, S.A. (eds) Organic Geochemistry. Topics in Geobiology, vol 11. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-2890-6_24
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DOI: https://doi.org/10.1007/978-1-4615-2890-6_24
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