Skip to main content

The nuclear microprobe — PIXE, PIGE, RBS, NRA and ERDA

  • Chapter
Microprobe Techniques in the Earth Sciences

Part of the book series: The Mineralogical Society Series ((MIBS,volume 6))

Abstract

Like the electron microprobe (Chapter 2), the scanning nuclear microprobe uses a focused beam of charged particles to excite samples. The focused beam usually consists of protons, but can include heavier particles such as alpha particles, oxygen ions or sulphur ions. In modern instruments, the beam can be scanned and rastered to produce line scans and two-dimensional elemental maps in addition to performing spot analyses. This instrumentation is often referred to as the scanning proton microprobe (or SPM). The incident proton beam is most commonly used to generate characteristic secondary X-rays from a sample in an analogous way to the electrons in the electron microprobe. In the nuclear microprobe literature this phenomenon is known as particle-induced X-ray emission or PIXE.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Anderson, H.H. and Ziegler, J.F. (1977) The Stopping and Ranges of Ions in Matter, Vol. 2. Pergamon Press, New York.

    Google Scholar 

  • CarJsson, L.-E. and Akselsson, R.K. (1981) Adv. X-Ray Anal. 24, 313.

    Google Scholar 

  • Chu, W.-K., Mayer, J.W. and Nicolet, M.-A. (1978) Back-scattering Spectrometry, Academic Press, New York.

    Google Scholar 

  • Cookson, J.A. (1987a) Historical background, in Principles and Applications of High-Energy Ion Microbeams (eds F. Watt and G.W. Grime), Adam Hilger, Bristol, pp. 1–20.

    Google Scholar 

  • Cookson, J.A. (1987b) Analytical techniques, in Principles and Applications of High-Energy Ion Microbeams (eds F. Watt and G.W. Grime), Adam Hilger, Bristol, pp. 21–78.

    Google Scholar 

  • Cookson, J.A. (1987c) Microbeam applications in metallurgy and industry, in Principles and Applications of High-Energy Ion Microbeams (eds F. Watt and G.W. Grime), Adam Hilger, Bristol, pp. 273–98.

    Google Scholar 

  • Cookson, J.A. and Pilling, F.D. (1973) Use of focused ion beams for analysis Thin Solid Films, 19, 381–5.

    Google Scholar 

  • Cookson, J.A., Ferguson, A.T.G. and Pilling, F.D. (1972) Proton beams, their production and use. J. Radioanal. Chem. 12. 39–52.

    Google Scholar 

  • Della Mea, G., Dran, J.-C., Petit, J.-C. et al. (1983) Use of ion beam techniques for studying the leaching properties of lead-implanted silicates. Nucl. Instr. Meth. Phys. Res., 218, 493–9.

    Article  Google Scholar 

  • Folkmann, F., Gaarde, C., Huus, T. and Kemp, K. (1974) Proton induced X-ray emission as a tool for trace element analysis. Nucl. Instr. Methods, 116, 487.

    Article  Google Scholar 

  • Frantz, J.D., Wu, Y., Thompson, A.C. et al. (1988) Analysis of fluid inclusions by X-ray fluorescence with synchrotron radiation. Ann. Rep. Geophys. Lab, 62–9.

    Google Scholar 

  • Fraser, D.G. (1990) Applications of the high resolution scanning proton microprobe in the Earth sciences: an overview. Chem. Geol., 83, 27–37.

    Article  Google Scholar 

  • Fraser, D.G., Feltham, D. and Whiteman, M. (1989) High resolution scanning proton microprobe studies of micron-scale zoning in a secondary dolomite: implications for studies of redox behaviour in dolomites. Sediment. Geol., 65, 223–32.

    Article  Google Scholar 

  • Fraser, D.G., Watt, F., Grime, G.W. and Takacs, J. (1984) Direct determination of strontium enrichment on grain boundaries in a garnet lherzolite xenolith by proton microprobe analysis. Nature, 312, 352–4.

    Article  Google Scholar 

  • Griffin, W.L., Jaques, A.L., Sie, S.H. et al. (1988) Conditions of diamond growth: a proton microprobe study of inclusions in West Australian diamonds. Contrib. Mineral. Petrol., 99, 143–58.

    Article  Google Scholar 

  • Griffin, W.L., Smith, D., Boyd, F.R. et al. (1989) Trace element zoning in garnets from sheared mantle xenoliths. Geochim. Cosmochim. Acta, 53, 561–7.

    Article  Google Scholar 

  • Horn, E.E. and Traxel, K. (1987) Investigations of individual fluid inclusions with the Heidelberg proton microprobe. A non-destructive analytical method. Chem. Geol., 61. 29–35.

    Article  Google Scholar 

  • Johansson S.A.E. and Capbell J.L. (1988) P.I.X.E.: A Novel Technique for Elemental Analysis John Wiley 347 pp

    Google Scholar 

  • Johansson, T.B., Akselsson. K.R. and Johansson, S.A.E. (1970) X-ray analysis: elemental trace analysis at the 10-12 g level. Nucl. Instr. Meth., 84, 141–3.

    Article  Google Scholar 

  • Khan, J.M., Potter, D.L. and Worley, R.D. (1966) Proposed method for microgram sufacedensity measurements by observation of proton-produced X-rays. J. Appl. Phvs., 37. 564–7.

    Article  Google Scholar 

  • Petit, J.-C., Dran, J.-C. and Della Mea, G. (1990) Energetic ion beam analysis in the Earth Sciences. Nature. 344, 621–6.

    Article  Google Scholar 

  • Pierce, T.B. (1972) Charged particle activation analysis. J. Radioanal. Chem., 12, 23–38.

    Article  Google Scholar 

  • Ryan, C.G., Clayton, E.J., Griffin, W.L. et al. (1988) SNIP, a statistics-sensistive background treatment for the quantitative analysis of PIXE spectra in geoscience applications. Nucl. Inst. Meth., Phys. Res., B34, 396–402.

    Google Scholar 

  • Ryan, C.G., Cousens, D.R., Heinrich, C.A. et al. (1991) Quantitative PIXE microanalysis of fluid inclusions based on a layered yield model. Nucl. Instr. Meth. Phys. Res., B54, 292–7.

    Article  Google Scholar 

  • Shepherd, T.J., Rankin, A.H. and Alderton, D.M.H. (1985) A Practical Guide to Fluid Inclusion Studies. Blackie, London.

    Google Scholar 

  • Sterk, A.A. (1965) X-ray generation by proton bombardment. Adv. X-ray Anal., 8, 189–97.

    Google Scholar 

  • Volkov, V.N., Vykhodets, V.B., Golubkov, I.K. et al. (1983) Accurate light ion beam monitoring by backscattering. Nucl. Instr. Methods, B205, 73–7.

    Google Scholar 

  • Watt, F. and Grime, G.W. (1987) Principles and Applications of High Energy Microbeams, Adam Hilger, Bristol, 399 pp.

    Google Scholar 

  • Watt, F., Grime, G.W., Blower, G.D. et al. (1982) The Oxford 1 μm proton microprobe Nucl. Instr. Meth. Phy. Res., B197, 65–77.

    Article  Google Scholar 

  • Wogelius, R.A., Fraser, D.G., and Feltham, D.J. (1992) Trace element zoning in dolomite: proton microprobe data and thermodynamic constraints on fluid compositions. Geochim. Cosmochim. Acta, 56, 319–34.

    Article  Google Scholar 

  • Ziegler, J.F., Biersack, J.P. and Littmark, U. (1985) The Stopping and Range of Ions in Solids, Vol. 1, Pergamon Press, New York.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1995 The Mineralogical Society

About this chapter

Cite this chapter

Fraser, D.G. (1995). The nuclear microprobe — PIXE, PIGE, RBS, NRA and ERDA. In: Potts, P.J., Bowles, J.F.W., Reed, S.J.B., Cave, M.R. (eds) Microprobe Techniques in the Earth Sciences. The Mineralogical Society Series, vol 6. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-2053-5_4

Download citation

  • DOI: https://doi.org/10.1007/978-1-4615-2053-5_4

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-0-412-55100-0

  • Online ISBN: 978-1-4615-2053-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics