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New Approaches in Spin Labeling and Spin Trapping. Part One: ESR Studies of Local Chemical Environment

  • Valery V. Khramtsov

Abstract

Spin labeling and spin trapping techniques are based on detection of ESR spectra of spin labels/probes or spin adducts which in many cases are nitroxyl radicals (NR). Spin traps have high reactivity towards free radical chemistry while spin labels are designed to prevent involvement of their paramagnetic fragment in chemical reactions. As a matter of fact the chemical reactions of nitroxides are often considered as a factor that compromises the stability of the paramagnetic fragment of NR and therefore limits their applications in spin labeling.

Keywords

Nitric Oxide Spin Label Dynamic Nuclear Polarisation Nitroxyl Radical Nitronyl Nitroxides 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 2001

Authors and Affiliations

  • Valery V. Khramtsov
    • 1
  1. 1.Institute of Chemical Kinetics and CombustionNovosibirskRussia

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