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Auxiliary Relations

  • Pascal Richet

Abstract

Before passing to some more practical aspects of thermodynamics, we will complete the catalog of the most useful mathematical expressions. To derive Maxwell’s and other important relations, extensive use will be made of the fact that differentials of state functions are exact differentials. With partial molar properties, an additional class of properties will also be defined, and the variations of the internal energy and entropy with pressure will be related to the temperature, pressure and volume changes through the thermodynamic equations of state.

Keywords

Gibbs Free Energy Partial Derivative Internal Energy Thermal Expansion Coefficient Isothermal Compressibility 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 2001

Authors and Affiliations

  • Pascal Richet
    • 1
  1. 1.Institut de Physique du GlobeParisFrance

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