Ageing Studies of Nuclear Waste Forms

  • Rodney C. Ewing


One of the unique and scientifically most difficult aspects of nuclear waste management is the extrapolation of short-term laboratory data (hours to years) to the long time periods (103 to 105 years) required by the performance objectives set in regulations. It will be necessary to establish the extent to which such extrapolations are useful or valid.


Borosilicate Glass Nuclear Waste Natural Analogue Waste Form Alteration Product 
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Selected References

  1. Although this author has attempted to provide full references in the text to previous work, space limitations prevent a complete listing of the citations. Instead, I have listed important, critical references in which the more detailed citations may be found.Google Scholar
  2. Abdelouas, A., Crovisier, J.L., Lutze, W., Fritz, B., Mosser, A. and Müller, R. (1994) Formation of Hydrotalcite-Like Compounds During R7T7 Nuclear Waste Glass and Basaltic Glass Alteration. Clays and Clay Minerals 41,526–533.CrossRefGoogle Scholar
  3. Abrajano, T.A. Bates, J.K. and Mazer, J.J. (1989) Aqueous Corrosion of Natural and Nuclear Waste glasses. II. Mechanisms of Vapor Phase Hydration of Nuclear Waste glasses. Journal of Non-Crystalline Solids 108,269–288.CrossRefGoogle Scholar
  4. Barkatt, Aa., Boulos, M.S., Barkatt, Al., Sousanpour, W., Boroomand, MA., Macedo, P.B., and O’Keefe, J.A. (1984) The Chemical Durability of Tektites - A Laboratory Study and Correlation with Long-Term Corrosion Behavior, Geochimica et Cosmochimica Acta 48, 361–371.CrossRefGoogle Scholar
  5. Bates, J.K., Bradley, C.R., Buck, E.C., Cunnane, J.C., Ebert, W.L., Feng, X., Mazer, J.J., Wronkiewicz, D.J., Sproull, J., Bourcier, W.L., McGrail, B.P., and Altenhofen, M.K., Eds. (1994) High-Level Waste Borosilicate Glass: A Compendium of Corrosion Characteristics. Report DOE-EM-0177 (3 volumes). Washington, D.C.: U.S. Department of Energy, Office of Waste Management.Google Scholar
  6. Bunker, B.C. (1987) Waste glass leaching: Chemistry and kinetics. MRS Proceedings of “Scientific Basis for Nuclear Waste Management X ”, vol. 84,493–507.Google Scholar
  7. Byers, CD., Jercinovic, M.J. and Ewing, R.C. (1986) A Study of Natural Glass Analogues as Applied to Aleration of Nuclear Waste Glass. Argonne National Laboratory, Report ANL086-46/NUREG/CR4842,150 pages.Google Scholar
  8. Crovisier, J.L., Advocat, T., Petit, J.C., and Fritz, B. (1989) Alteration of Basaltic Glass in Iceland as a Natural Analogue for Nuclear Waste Glasses: Geochemical Modeling with DISSOL. Proceedings of “Scientific Basis for Nuclear Waste Management XII” vol. 127, 57–64.Google Scholar
  9. Ewing, R.C. (1979) Natural Glasses: Analogues for Radioactive Waste Forms. MRS Proceedings of “Scientific Basis for Nuclear Waste Management I”, vol. I, 57–68.CrossRefGoogle Scholar
  10. Ewing, R.C. and Haaker, R.F. (1979) Natural glasses: Analogues for Radioactive Waste Forms (Battelle PNL Report 2776/UC-70), 71 pp.CrossRefGoogle Scholar
  11. Ewing, R.C. and Jercinovic, M.J. (1987) Natural Analogues: Their Application to the Prediction of the Long-Term Behavior of Nuclear Waste Glasses. MRS Proceedings of “Scientific Basis for Nuclear Waste Management X”, vol. 84,67–83.Google Scholar
  12. Ewing, R.C. (1992) The role of natural analogues in performance assessment: Applications and limitations. Proceedings of the Third International Conference on High Level Radioactive Waste Management, James S. Tulenko, Ed., (American Nuclear Society) 1429–1436.Google Scholar
  13. Ewing, R.C. (1993) The long-term performance of nuclear waste forms: The use of natural materials - Three case studies. MRS Proceedings of “Scientific Basis for Nuclear Waste Management XVI”, vol. 294, 559 - 568.Google Scholar
  14. Ewing, R.C. (1995) Long-term predictions using natural analogues. Proceedings of the “Workshop on the Role of Natural Analogs in Geologic Disposal of High-Level Nuclear Waste” sponsored by the Office of Nuclear Regulatory Research of the U.S. Nuclear Regulatory Commission, NUREG/CP-0147,29-35.Google Scholar
  15. Grambow, B., Jercinovic, M.J., Ewing, R.C. and Byers, C.D. (1986) Weathered Basalt Glass: A Natural Analogue for the Effects of Reaction Progress on Nuclear Waste Glass Alteration. MRS Proceedings of “Scientific Basis for Nuclear Waste Management IX”, vol. 50,263–272.Google Scholar
  16. Jercinovic, M.J. and Ewing, R.C. (1988) Basaltic Glass from Iceland and the Deep Sea: Natural analogues to Borosilicate Nuclear Waste-Form Glass. JSS Project Tech. Rept. SKB Technical Report 88-01,221 pages.Google Scholar
  17. Jercinovic, M.J. and Ewing, R.C. (1992) Corrosion of Geological and Archaeological Glasses. In Corrosion of Glass. Ceramics and Ceramic Superconductors, edited by D.E. Clark and B.K. Zoitos (Noyes Publications, Park Ridge, New Jersey) pp. 330–371.Google Scholar
  18. Lutze, W., Malow, G., Ewing, R.C., Jercinovic, M.J. and Keil, K. (1985) Alteration of Basalt Glass: Implication for Modeling Long-Term Stability of Nuclear Waste Glasses, Nature 314,252–255.CrossRefGoogle Scholar
  19. Malow, G., Lutze, W. and Ewing, R.C (1984) Alteration Effects and Leach Rates of Basaltic Glasses: Implications for the Long-Term Stability of Nuclear Waste Form Borosilicate Glasses. Journal of Non-Crystalline Solids 67,305–321.CrossRefGoogle Scholar
  20. Mazer, J.J., Bates, J.K., Bradley, C.R. and Stevenson, CM. (1992) Water Diffusion in Tektites: An Example of the Use of Natural Analogues in Evaluating the Long-Term Reaction of Glass with Water. Journal of Nuclear Materials 190, 277–284.CrossRefGoogle Scholar
  21. National Research Council (1996) Glass as a Waste Form and Vitrification Technology (chair, R.C. Ewing), Washington, D.C., National Academy Press, 23 pp.Google Scholar
  22. Werme, L., Bjömer, I.K., Bart, G., Zwicky, H.U., Grambow, B., Lutze, W., Ewing, R.C and Magrabi, C (1990) Chemical corrosion of highly radioactive borosilicate nuclear waste glass under simulated repository conditions. Journal of Materials Research, 5 (5), 1130–1146.CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2001

Authors and Affiliations

  • Rodney C. Ewing
    • 1
  1. 1.Department of Nuclear Engineering and Radiological SciencesThe University of MichiganAnn ArborUSA

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