Abstract
In the present work the sol-gel process in the silica base systems, starting with different alkoxides, was approached by gas chromatography coupled with mass spectrometry (CG-MS). The influence of the type of alkoxide, type of solvent and the water amount on the molecular species formed in the early stages of the hydrolysis-polycondenstion process were analyzed, as well as the influence of the molecular species present in the solution at the moment of gelation on the structure of the obtained gels.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Assink R.A., Kay B.D. Sol-gel kinetics.I.Functional group kinetics. J.Non-Cryst. Solids, 1988; 99:359 1997; 210:187–203
Sivade A., Bourret D., Sempere R., Bouaziz J. H1 NMR studies of tetramethylortosilicate (TMOS) alcoholysis by isopropyl alcohol. J. Non-Cryst. Solids. 1992; 147&148: 167
Babonneau F., Bonhomme C., Toutou C., Gavériaux S.. 17O NMR Investigation of Chemical Homogeneity in Hybrid Systems. J.Sol-Gel Sci.and Technol. 1997; 8:553
Wheeler G.E., Ph.D. Thesis, New York University, 1987
Wheeler G.E., Ultrastructure Processing of Advanced Ceramics,eds. J.D. Mackenzie and D.R. Ulrich (Wiley, New York), 1988, p.819.
Bãdescu V., Radu M., Zaharescu M., Vasilescu A., Hydrolysis-Condensation of tetraethoxysilan in Nonparental Solvents studied by GC-MS. J. Sol-Gel Sci. and Technol. 1994; 2:43
Zaharescu M., Vasilescu A., Bãdescu V., Radu M. Influence of the catalysts on the hydrolysis-polycondensation of tetraethoxysilan studied by GC-MS. Rev.Roum.Chim. 1997; 42:633
Zaharescu M., Jitianu A., badescu V., Radu M. Comparative study of the sol-gel transition mechanism of different substitute Si-alkoxides. Ceramics: Getting into the 2000’. Proceedings of the World Ceramic Congress, part of the 9th CIMTEC-World Ceramic Congress and Forum on New materials, Florence, Italy June 14–19, 1998, Part C: 151–158, Edited vy P. Vincenzini, techna, faenta 1999 (Series: Advances in Science and Technology)
Zaharescu M., Jitianu A., Braileanu A., Badescu V., Pokol G., Madarasz J., Novak Cs. J. Therm. Anal. Cal. 1999; 56:191–198
Bãdescu V., Radu M. GC-MS studies of the molecular species identified in hydrolysis-transesterification-condensation reactions of tetraethoxysilane in nonparental solvent. “Euroanalysys IX” - European Conference on Analytical Chemistry, Bologna (Italy), September 1–7, 1996.
Vasilescu, Adrian. Oxide materials in bi-component systems obtained from gels (in roumanian), Ph.D. Thesis, Institute of Physical Chemistry Bucharest, Romania, 1999.
Yoshino H., Kamiya K., Nasu H. IR study on the structural evolution of sol-gel derived SiO2 gels in the early stage of conversion to glasses. J.Non-Cryst.Solids 1990; 126:68.
Bertoluzza, A., Fangano, C., Morelli, M.A., Gottardi, V., Guglielmi, M. Raman and infrared spectra on silica gel evolving toward glass. J. Non-Cryst. Solids 1982; 48: 117–122.
Ou D.L., Seddon A.B. Near — and mid — infrared spectroscopy of sol-gel derived ormosils: vinyl and phenyl silicates. J.Non-Cryst.Solids 1997; 210:187–203
Capozzi C.A., Pye L.D., Condrate R.A. Vibrational spectral/structural changes from the hydrolysis/polycondensation of methyl — modified silicates. I. Comparisons for single monomer condensates. Mat. Lett. 1992; 15:130–136
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2003 Springer Science+Business Media New York
About this chapter
Cite this chapter
Zaharescu, M., Bădescu, V., Vasilescu, A., Jitianu, A. (2003). Contribution to the Sol-Gel Chemistry in Silica Based Systems. In: López, T.M., Avnir, D., Aegerter, M. (eds) Emerging Fields in Sol-Gel Science and Technology. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-0449-8_16
Download citation
DOI: https://doi.org/10.1007/978-1-4615-0449-8_16
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4020-7458-5
Online ISBN: 978-1-4615-0449-8
eBook Packages: Springer Book Archive