Abstract
Using wave-packet simulations on ab-initio potential curves we investigate the vi-brational dynamics of Nal and Csl in their first excited electronic states when aggregated with a single molecule of acetonitrile (CH3CN). The probe signal is obtained by femtosecond ionization of the diatomic chromophore. The addition of acetonitrile is found to change greatly the ionization signal of the free molecule suggesting strong modification of the reaction dynamics.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
W. R. Lambert, P. M. Felker and A. H. Zewail, J. Chem. Phys. 75, 5958 (1981)..[2] J. Manz and L. Wöste, in Femtosecond Chemistry, Vols 1 and 2, VCH, Weinheim, (1996).
A. H. Zewail, in Femtochemistry - Ultrafast Dynamics of the Chemical Bond, Vols 1 and 2, World Scientific, Singapore, (1994).
M. Chergui, in Femtochemistry, World Scientific, Singapore, (1995).
R. J. Gordon and S. A. Rice, Annu. Rev. Phys. Chem. 48, 601 (1997).
S. A. Rice, Nature 403, 496 (2000).
E. Charron and B. Sheehy, in An introduction to molecules and clusters in intense laser fields, Cambridge University Press (2000).
M. Shapiro, J. W. Hepburn and P. Brumer, Chem. Phys. Lett. 149, 451 (1988).
D. J. Tannor, R. Kosloff and S. A. Rice, J. Chem. Phys. 85, 5805 (1986).
S. Shi, A. Woody and H. Rabitz, J. Chem. Phys. 88, 6870 (1988).
R. S. Judson and H. Rabitz, Phys. Rev. Lett. 68, 1500 (1992).
A. Assion et al, Science 282, 919 (1998).
G. Grégoire, M. Mons, I. Dimicoli, C. Dedonder-Lardeux, C. Jouvet, S. Martrenchard and D. Solgadi, Eur. Phys. J. D 11, 227 (2000).
G. Gregoire, PhD. Thesis, Universit’ e Paris XI, (1999).
T. S. Rose, M. J. Rosker and A. H. Zewail, J. Chem. Phys. 88, 6672 (1988).
M. J. Rosker, T. S. Rose and A. H. Zewail, Chem. Phys. Lett. 146, 175 (1988).
A. Mohkatari, P. Cong, J. L. Herek and A. H. Zewail, Nature 348, 225 (1990).
P. Cong, A. Mokhtari and A. H. Zewail, Chem. Phys. Lett. 172, 109 (1990).
P. Cong, G. Roberts, J. L. Herek, A. Mohkatari and A. H. Zewail, J. Chem. Phys. 100, 7832 (1996)..[20] A. Assion, M. Geisler, J. Helbing, V. Seyfried and T. Baumert, Phys. Rev. A 54, R4605 (1996).
C. Jouvet et al, J. Phys. Chem. A 101, 2555 (1997).
V. Engel, H. Metiu, R. Almeida, R. A. Marcus and A. H. Zewail, Chem. Phys. Lett. 152, 1 (1988).
V. Engel and H. Metiu, Chem. Phys. Lett. 155, 77 (1989).
H. Metiu and V. Engel, J. Chem. Phys. 93, 5693 (1990).
E. Charron and A. Suzor-Weiner, J. Chem. Phys. 108, 3922 (1998).
G. Grégoire, V. Brenner and P. Millie, J. Phys. Chem. A 104, 5204 (2000).
D. Stibbe, E. Charron and A. Suzor-Weiner, J. Chem. Phys. 116, 10753 (2002).
M. Braun, C. Meier and V. Engel, J. Chem. Phys. 103, 7907 (1995).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2002 Springer Science+Business Media New York
About this chapter
Cite this chapter
Charron, E., Stibbe, D.T., Suzor-Weiner, A. (2002). Femtosecond ionization of CH3CN-NaI and CH3CN-Csl. In: Mohan, M. (eds) Current Developments in Atomic, Molecular, and Chemical Physics with Applications. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-0115-2_6
Download citation
DOI: https://doi.org/10.1007/978-1-4615-0115-2_6
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4613-4930-3
Online ISBN: 978-1-4615-0115-2
eBook Packages: Springer Book Archive