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Development of Glass-Based Solid Electrolytes for Lithium-Ion Batteries

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Nanoscale Technology for Advanced Lithium Batteries

Part of the book series: Nanostructure Science and Technology ((NST))

Abstract

The development of glass-based solid electrolytes for lithium-ion batteries is reviewed. Strategies for preparing glass electrolytes with high Li+ ion conductivity are as follows: increase in Li+ ion concentration, change from oxide matrix to a sulfide one, and stabilization at room temperature of high-temperature or metastable phase by crystallization of glass. Glass electrolytes with high Li+ ion concentration were prepared by rapid quenching and mechanochemical techniques. Oxysulfide glasses in a Li2S-SiS2-Li4SiO4 system and sulfide glass ceramics in a Li2S-P2S5 system are suitable as solid electrolytes with a high ion conductivity of 10−3 S cm−1 at room temperature and a wide electrochemical window of more than 5 V. The sulfide glass-based compounds were applied as solid electrolytes to bulk-type, all-solid-state rechargeable lithium batteries. The solid-state batteries using Li4Ti5O12 active material exhibited a high rate capability with excellent cyclability for 700 cycles at a high temperature of 100 °C.

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Authors and Affiliations

  1. Department of Applied Chemistry, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka, 599-8531, Japan

    Masahiro Tatsumisago & Akitoshi Hayashi

Authors
  1. Masahiro Tatsumisago
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  2. Akitoshi Hayashi
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Correspondence to Masahiro Tatsumisago .

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Editors and Affiliations

  1. Science and Engineering, Waseda University, Tokyo, Japan

    Tetsuya Osaka

  2. Society-Academia Collaboration for Innovation, Kyoto University, Kyoto, Japan

    Zempachi Ogumi

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Tatsumisago, M., Hayashi, A. (2014). Development of Glass-Based Solid Electrolytes for Lithium-Ion Batteries. In: Osaka, T., Ogumi, Z. (eds) Nanoscale Technology for Advanced Lithium Batteries. Nanostructure Science and Technology. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-8675-6_7

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