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Photoelectrochemical Water Splitting


Solar photoelectrochemical (PEC) hydrogen production is one of the promising technologies that could potentially provide a clean, cost-effective, and domestically produced energy carrier by taking advantage of the *120,000 TW of radiation that continually strikes the earth’s surface. To date, no cost-effective materials system satisfies all of the technical requirements listed above for practical hydrogen production. Despite the challenges, there are promising pathways for achieving the important goal of efficient, cost-effective PEC hydrogen production. For continued progress in overcoming the most important remaining scientific and engineering barriers, widely accepted standards in the characterization and reporting of PEC materials and devices are needed.

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  1. J.P. Holdren, Energy and sustainability. Science 315, 737 (2007)

    Article  CAS  Google Scholar 

  2. N.S. Lewis, D.G. Nocera, Powering the planet: chemical challenges in solar energy utilization. Proc. Natl. Acad. Sci. U. S. A. 104, 20142 (2007)

    CAS  Google Scholar 

  3. L.E. Doman, K.A. Smith, L.D. Mayne, E.M. Yucel, J.L. Barden, A.M. Fawzi, P.D. Martin, V.V. Zaretskaya, M.L. Mellish, D.R. Kearney, B.T. Murphy, K.R. Vincent, P.M. Lindstrom, M.T. Leff, International Energy Outlook 2010 (2010)

    Google Scholar 

  4. J. Stringer, L. Horton, Basic Research Needs to Assure a Secure Energy Future (2003)

    Google Scholar 

  5. A. Fujishima, K. Honda, Electrochemical photolysis of water at a semiconductor electrode. Nature 238, 37–38 (1972)

    Article  CAS  Google Scholar 

  6. O. Khaselev, J.A. Turner, A monolithic photovoltaic-photoelectrochemical device for hydrogen production via water splitting. Science 280, 425–427 (1998)

    Article  CAS  Google Scholar 

  7. M.D. Archer, A.J. Nozik, Nanostructured and Photoelectrochemical Systems for Solar Photon Conversion, vol. 3 (Imperial College Press, London, 2008)

    Google Scholar 

  8. R. Memming, Semiconductor Electrochemistry (Wiley-Vch, Weinheim, 2001)

    Google Scholar 

  9. L. Vayssieres, On Solar Hydrogen and Nanotechnology (Wiley, Chichester, 2009)

    Google Scholar 

  10. T. Bak, J. Nowotny, M. Rekas, C.C. Sorrell, Photo-electrochemical hydrogen generation from water using solar energy. Materials-related aspects. Int. J. Hydrog. Energy 27, 991–1022 (2002)

    Article  CAS  Google Scholar 

  11. A. Kudo, Y. Miseki, Heterogeneous photocatalyst materials for water splitting. Chem. Soc. Rev. 38, 253–278 (2009)

    Article  CAS  Google Scholar 

  12. M. Gratzel, Photoelectrochemical cells. Nature 414, 338–344 (2001)

    Article  CAS  Google Scholar 

  13. A. Polman, H.A. Atwater, Photonic design principles for ultrahigh-efficiency photovoltaics. Nat. Mater. 11, 174–177 (2011)

    Article  Google Scholar 

  14. W. Shockley, H.J. Queisser, Detailed balance limit of efficiency of p–n junction solar cells. J. Appl. Phys. 32, 510–519 (1961)

    Article  CAS  Google Scholar 

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Correspondence to Eric Miller .

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Chen, Z. et al. (2013). Introduction. In: Photoelectrochemical Water Splitting. SpringerBriefs in Energy. Springer, New York, NY.

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  • Print ISBN: 978-1-4614-8297-0

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