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Source Zone Remediation: The State of the Practice

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Part of the book series: SERDP ESTCP Environmental Remediation Technology ((SERDP/ESTCP,volume 7))

Abstract

Chlorinated solvents are widespread groundwater contaminants whose physical and chemical properties make them difficult to locate and treat within the subsurface. In particular, remediating chlorinated solvent source zones has proven technically challenging, costly and contentious. Nevertheless, there has been a concerted effort over the past 20-25 years to remediate these source zones, involving development of several in situ technologies. This chapter summarizes the knowledge gained from these efforts, and serves as an introduction to the entire volume. The chapter first summarizes the evolution of the conceptual model of DNAPL source zones, and then describes the current model of a 5-stage life cycle, with a long final stage of back diffusion and desorption. The chapter then summarizes the development of the important remediation technologies, followed by an overview of the current state of the practice. The chapter includes brief summaries of the remaining chapters, and concludes with a summary of the current needs, both for research and for the highly-qualified personnel required to manage groundwater restoration in the future.

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References

  • Ankeny MD, Forbes JR. 2000. Constant Hydraulic Head Moat and Method for Controlling Regional Ground Water Flow. U.S. Patent No. 6,139,221A. http://www.google.com/pat ents/US6139221?dq=%22ankeny+moat%22. Accessed January 20, 2014.

  • Brewster ML, Annan AP, Greenhouse JP, Kueper BH, Olhoeft GR, Redman JD, Sander KA. 1995. Observed migration of a controlled DNAPL release by geophysical methods. Ground Water 33:977–987.

    Article  CAS  Google Scholar 

  • Falta RW, Rao PSC, Basu N. 2005. Assessing the impacts of partial mass depletion in DNAPL source zones: I. Analytical modeling of source strength functions and plume response. J Contam Hydrol 78:259–280.

    Article  CAS  Google Scholar 

  • Gerhard JI, Pang T, Kueper BH. 2007. Time scales of DNAPL migration in sandy aquifers examined via numerical simulation. Ground Water 45:147–157.

    Article  CAS  Google Scholar 

  • Kavanaugh MC, Rao PSC, Abriola L, Cherry J, Newell C, Sale T, Destouni G, Falta R, Shoemaker S, Siegrist R, Major D, Mercer J, Teusch G, Udell K. 2003. The DNAPL Remediation Challenge: Is There a Case For Source Depletion? EPA/600/R-03/143. USEPA National Risk Management Research Laboratory, Cincinnati, OH, USA. 129 p.

    Google Scholar 

  • Kueper BH. 1996. Unpublished. Queen’s University, Kingston, ON, Canada.

    Google Scholar 

  • Kueper BH, Gerhard JI. 1995. Variability of point source infiltration rates for two-phase flow in heterogeneous porous media. Water Resour Res 31:2971–2980.

    Article  Google Scholar 

  • Kueper BH, Redman JD, Starr RC, Reitsma S, Mah M. 1993. A field experiment to study the behavior of tetrachloroethylene below the water table: Spatial distribution of residual and pooled DNAPL. Ground Water 31:756–766.

    Article  CAS  Google Scholar 

  • McCarty PL. 2010. Groundwater contamination by chlorinated solvents: History, remediation technologies and strategies. In Stroo HF, Ward CH, eds, In Situ Remediation of Chlorinated Solvent Plumes. Springer, New York, NY, USA, pp 1–28.

    Chapter  Google Scholar 

  • NAVFAC (Naval Facilities Engineering Command), Geosyntec. 2011. DNAPL Technology Evaluation Screening Tool (DNAPL TEST). http://projects.geosyntec.com/DNAPL/dnapltest.aspx. Accessed January 20, 2014.

  • NRC (National Research Council). 2005. Contaminants in the Subsurface: Source Zone Assessment and Remediation. National Academies Press, Washington, DC, USA. 333 p.

    Google Scholar 

  • NRC. 2013. Alternatives for Managing the Nation’s Complex Contaminated Groundwater Sites. Committee on Future Options for Management in the Nation's Subsurface Remediation Effort; Water Science and Technology Board (WSTB); Division on Earth and Life Studies (DELS); National Research Council of the Academies. The National Academies Press, Washington, DC, USA. 422 p.

  • Pankow JF, Cherry JA, eds. 1996. Dense Chlorinated Solvent and Other DNAPLs in Groundwater. Waterloo Press, Portland, OR, USA. 522 p.

    Google Scholar 

  • Poulsen M, Kueper BH. 1992. A field experiment to study the behavior of tetrachloroethylene in unsaturated porous media. Environ Sci Technol 26:889–895.

    Article  CAS  Google Scholar 

  • Schwille F. 1981. Groundwater pollution in porous media by fluids immiscible with water. Sci Total Environ 21:173–185.

    Article  CAS  Google Scholar 

  • Schwille F. 1988. Dense Chlorinated Solvents in Porous and Fractured Media: Model Experiments. Translated from the German by J.F. Pankow. Lewis Publishers, Boca Raton, FL, USA. 146 p.

    Google Scholar 

  • Streeter VL, Wylie EB. 1981. Fluid Mechanics, First SI Metric Edition. McGraw-Hill Ryerson, Whitby, ON, Canada. 562 p.

    Google Scholar 

  • Stroo HF, Lesson A, Marqusee JA, Johnson PC, Ward CH, Kavanaugh MC, Sale TC, Newell CJ, Pennell KD, Lebrón CA, Unger M. 2012. Chlorinated ethene source remediation: Lessons learned. Environ Sci Technol 46:6438–6447.

    Article  CAS  Google Scholar 

  • Travis CC, Doty CB. 1990. Can contaminated aquifers at Superfund sites be remediated? Environ Sci Technol 24:1464–1466.

    Article  Google Scholar 

  • Triplett Kingston JL, Dahlen PR, Johnson PC. 2010. State-of-the-practice review of in situ thermal technologies. Ground Water Monit Remediat 30:64–72

    Article  Google Scholar 

  • USEPA (U.S. Environmental Protection Agency). 2004. Cleaning Up the Nation’s Waste Sites: Markets and Technology Trends. EPA 542-R-04-015. USEPA Office of Solid Waste and Emergency Response. http://www.clu-in.org/download/market/2004market.pdf. Accessed January 20, 2014.

  • USEPA. 2009. Assessment and Delineation of DNAPL Source Zones at Hazardous Waste Sites. EPA/600/R-09/119. USEPA National Risk Management Research Laboratory, Cincinnati, OH, USA. 20 p.

    Google Scholar 

  • USEPA. 2013. Basic Information about Regulated Drinking Water Contaminants and Indicators. http://water.epa.gov/drink/contaminants/basicinformation. Accessed January 20, 2014.

  • WCGR (Waterloo Centre for Groundwater Research). 1992. Lecture 2 (B. Kueper), Immiscible Liquid Behaviour (Porous Media). Professional Short Course, Site Characterization and Remediation of Dense, Immiscible Phase Liquid Contaminants (DNAPLs) in Porous and Fractured Media. November 2–5, Chicago, IL, USA.

    Google Scholar 

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Kueper, B.H., Stroo, H.F., Vogel, C.M., Ward, C.H. (2014). Source Zone Remediation: The State of the Practice. In: Kueper, B., Stroo, H., Vogel, C., Ward, C. (eds) Chlorinated Solvent Source Zone Remediation. SERDP ESTCP Environmental Remediation Technology, vol 7. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-6922-3_1

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