Carbon Nanotube Assemblies for Transparent Conducting Electrodes

  • Ilia N. Ivanov
  • Matthew P. Garrett
  • Rosario A. Gerhardt
Chapter
Part of the Nanostructure Science and Technology book series (NST)

Abstract

The goal of this chapter is to introduce readers to the fundamental and practical aspects of nanotube assemblies made into transparent conducting networks and discuss some practical aspects of their characterization. Transparent conducting coatings (TCC) are an essential part of electro-optical devices, from photovoltaics and light emitting devices to electromagnetic shielding and electrochromic widows. The market for organic materials (including nanomaterials and polymers) based TCCs is expected to show a growth rate of 56.9% to reach nearly $20.3 billion in 2015, while the market for traditional inorganic transparent electronics will experience growth with rates of 6.7% to nearly $103 billion in 2015. Emerging flexible electronic applications have brought additional requirements of flexibility and low cost for TCC. However, the price of indium (the major component in indium tin oxide TCC) continues to increase. On the other hand, the price of nanomaterials has continued to decrease due to development of high volume, quality production processes. Additional benefits come from the low cost, nonvacuum deposition of nanomaterials based TCC, compared to traditional coatings requiring energy intensive vacuum deposition. Among the materials actively researched as alternative TCC are nanoparticles, nanowires, and nanotubes with high aspect ratio as well as their composites. The figure of merit (FOM) can be used to compare TCCs made from dissimilar materials and with different transmittance and conductivity values. In the first part of this manuscript, we will discuss the seven FOM parameters that have been proposed, including one specifically intended for flexible applications. The approach for how to measure TCE electrical properties, including frequency dependence, will also be discussed. We will relate the macroscale electrical characteristics of TCCs to the nanoscale parameters of conducting networks. The fundamental aspects of nanomaterial assemblies in conducting networks will also be addressed. We will review recent literature on TCCs composed of carbon nanotubes of different types in terms of the FOM.

Notes

Acknowledgments

This work was conducted at the Center for Nanophase Materials Sciences, which is sponsored at Oak Ridge National Laboratory by the Office of Basic Energy Sciences, U.S. Department of Energy. We acknowledge financial support by the Solar Energy Technologies Program of the Office of Energy Efficiency and Renewable Energy, U.S. Department of Energy.

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Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  • Ilia N. Ivanov
    • 1
  • Matthew P. Garrett
    • 1
    • 2
  • Rosario A. Gerhardt
    • 3
  1. 1.Center for Nanophase Materials SciencesOak Ridge National LaboratoryOak RidgeUSA
  2. 2.Department of PhysicsUniversity of TennesseeKnoxvilleUSA
  3. 3.Georgia Institute of TechnologyAtlantaUSA

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