Abstract
Jatropha curcas L. has been widely regarded as a promising plant to supplement the existing biofuel production from first generation biocrops. However, several of its distinctive oil properties such as high moisture and free fatty acid (FFA) content lower its cost competitiveness and compatibility with established biofuels production process. Consequently, in situ biodiesel production, which combines both oil extraction and transesterification in a single processing unit, is applied for Jatropha to address these shortcomings. There are four main routes of in situ process being explored i.e. alkaline catalytic, acidic catalytic, enzymatic catalytic and supercritical non-catalytic reaction. Most of the experimental studies showed that in situ biodiesel production process for Jatropha was superior in terms of process severity, extraction rate and final biodiesel yield. However, more detailed studies pertaining to the kinetics and mechanism should be conducted in the future to increase its sustainability and commercialization prospects.
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References
Abel K, de Schmertzing H, Peterson JI (1963) Classification of microorganism by analysis of chemical composition 1. Feasibility of utilizing gas chromatography. J Bacteriol 85:1039–1044
Achten WMJ, Verchot L, Franken YJ, Mathijs E, Singh VP, Aerts R et al (2008) Jatropha biodiesel production and use. Biomass Bioenergy 32:1063–1084
Aregheore EM, Makkar HPS, Becker K (1998) Assessment of lectin activity in a toxic and a non-toxic variety of Jatropha curcas using latex agglutination and haemagglutination methods and inactivation of lectin by heat treatments. J Sci Food Agric 77:349–352
Carrapiso AI, Timón ML, Petrón MJ, Tejeda JF, GarcÃa C (2000) In situ transesterification of fatty acids from Iberian pig subcutaneous adipose tissue. Meat Sci 56:159–164
Currie J (2007) Food, feed and fuels: an outlook on the agriculture, livestock and biofuel markets. The Goldman Sachs Group. Available from: http://www.gceholdings.com/pdf/GoldmanReportFoodFeedFuel.pdf
Ginting MSA, Azizan MT, Yusup S (2012) Alkaline in situ ethanolysis of Jatropha curcas. Fuel 93:82–85. doi:10.1016/j.fuel.2011.08.062
Gu H, Jiang Y, Zhou L, Gao J (2011) Reactive extraction and in situ self-catalyzed methanolysis of germinated oilseed for biodiesel production. Energy Environ Sci 4:1337–1344
Haas JH, Scott KM (2007) Moisture removal substantially improves the efficiency of in situ biodiesel production from soybeans. J Am Oil Chem Soc 84:197–204
Haas MJ, Scott KM, Marmer WN, Foglia TA (2004) In situ alkaline transesterification: an effective method for the production of fatty acid esters from vegetable oils. J Am Oil Chem Soc 81:83–89
Haas MJ, Scott KM, Foglia TA, Marmer WN (2007) The general applicability of in situ transesterification for the production of fatty acid esters from a variety of feedstocks. J Am Oil Chem Soc 84:963–970
Hailegiorgis SM, Mahadzir S, Subbarao D (2011) Enhanced in situ ethanolysis of Jatropha curcas L. in the presence of cetyltrimethylammonium bromide as a phase transfer catalyst. Renew Energy 36:2502–2507
Harrington KJ, D’Arcy-Evans C (1985) Transesterification in situ of sunflower seed oil. Ind Eng Chem Prod Res Dev 24:314–318
Karaj S, Muller J (2011) Optimizing mechanical oil extraction from Jatropha curcas L. seeds with respect to press capacity, oil recovery and energy efficiency. Ind Crops Prod 34:1010–1016
Kaul S, Porwal J, Garg MO (2010) Parametric study of Jatropha seeds for biodiesel production by reactive extraction. J Am Oil Chem Soc 87:903–908
Kildiran G, Ozgul-Yucel S, Turkay S (1996) In situ alcoholysis of soybean oil. J Am Oil Chem Soc 73:225–232
Kumar MS, Ramesh A, Nagalingam B (2003) An experimental comparison of methods to use methanol and Jatropha oil in a compression ignition engine. Biomass Bioenergy 25:309–318
Li Y, Lian S, Tong D, Song R, Yang W, Fan Y et al (2011) One-step production of biodiesel from Nannochloropsis sp. on solid base Mg–Zr catalyst. Appl Energy 88:3313–3317
Lim S, Lee KT (2011) Effects of solid pre-treatment towards optimizing supercritical methanol extraction and transesterification of Jatropha curcas L. seeds for the production of biodiesel. Sep Purif Technol 81:363–370
Lim S, Hoong SS, Teong LK, Bhatia S (2010) Supercritical fluid reactive extraction of Jatropha curcas L. seeds with methanol: a novel biodiesel production method. Bioresour Technol 101:7169–7172
Min J, Li S, Hao J, Liu N (2010) Supercritical CO2 extraction of Jatropha oil and solubility correlation. J Chem Eng Data 55:3755–3758
Ozgul-Yucel S, Turkay S (1993) In situ esterification of rice bran oil with methanol and ethanol. J Am Oil Chem Soc 70:145–147
Ozgul-Yucel S, Turkay S (2003) Fatty acid monoalkylesters from rice bran oil by in situ esterification. J Am Oil Chem Soc 80:81–84
Pandey KK, Pragya N, Sahoo PK (2011) Life cycle assessment of small-scale high-input Jatropha biodiesel production in India. Appl Energy 88:4831–4839
Pramanik K (2002) Properties and use of Jatropha curcas oil and diesel fuel blends in compression ignition engine. Renew Energy 28:239–248
Qian J, Wang F, Liu S, Yun Z (2008) In situ alkaline transesterification of cottonseed oil for production of biodiesel and nontoxic cottonseed meal. Bioresour Technol 99:9009–9012
Sato S, Hirakawa H, Isobe S, Fukai E, Watanabe A, Kato M et al (2010) Sequence analysis of the genome of an oil-bearing tree, Jatropha curcas L. DNA Res 18:65–76
Shah S, Sharma A, Gupta MN (2004) Extraction of oil from Jatropha curcas L. seed kernels by enzyme assisted three phase partitioning. Ind Crops Prod 20:275–279
Shah S, Sharma A, Gupta MN (2005) Extraction of oil from Jatropha curcas L. seed kernels by combination of ultrasonication and aqueous enzymatic oil extraction. Bioresour Technol 96:121–123
Shuit SH, Lee KT, Kamaruddin AH (2010a) Reactive extraction and in situ esterification of Jatropha curcas L. seeds for the production of biodiesel. Fuel 89:527–530
Shuit SH, Lee KT, Kamaruddin AH, Yusup S (2010b) Reactive Extraction of Jatropha curcas L. seed for Production of Biodiesel: Process Optimization Study. Environ Sci Technol 44:4361–4367
Siler-Marinkovic S, Tomasevic A (1998) Transesterification of sunflower oil in situ. Fuel 77:1389–1391
Su EZ, Xu WQ, Gao KL, Zheng Y, Wei DZ (2007) Lipase-catalyzed in situ reactive extraction of oilseeds with short-chained alkyl acetates for fatty acid esters production. J Mol Catal B: Enzym 48:28–32
The Global Exchange for Social Investment (GEXSI 2008) Global Market Study on Jatropha and our project in Madagascar. JatrophaWorld 2008 Miami
Wyatt VT, Haas MJ (2009) Production of fatty acid methyl esters via the in situ transesterification of soybean oil in carbon dioxide-expanded methanol. J Am Oil Chem Soc 86:1009–1016
Zeng J, Wang X, Zhao B, Sun J, Wang Y (2009) Rapid in situ transesterification of sunflower oil. Ind Chem Eng Res 48:850–856
Acknowledgments
The authors would like to acknowledge Universiti Sains Malaysia for the financial support given (Research University Grant No: 814062) and USM Vice-Chancellors Award of a student scholarship to Steven Lim.
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Lee, K.T., Lim, S. (2012). The In Situ Biodiesel Production and Its Applicability to Jatropha. In: Carels, N., Sujatha, M., Bahadur, B. (eds) Jatropha, Challenges for a New Energy Crop. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-4806-8_28
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DOI: https://doi.org/10.1007/978-1-4614-4806-8_28
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