Abstract
Herein we report on high-resolution electron energy loss spectroscopy (HREELS) measurements on surface plasmon dispersion in systems exhibiting quantum well states (QWS), i.e., Na/Cu(111), Ag/Cu(111), and Ag/Ni(111). Our results demonstrate that the dominant coefficient of surface plasmon dispersion for thin and layer-by-layer Ag films presenting QWS is quadratic even at small q∥, in contrast with previous measurements on Ag semi-infinite media and Ag thin films deposited on Si(111). We suggest that this behavior is due to screening effects enhanced by the presence of QWS shifting the position of the centroid of the induced charge less inside the geometrical surface compared to Ag surfaces and Ag/Si(111). For ultrathin Ag films, i.e., two layers, the dispersion was found to be not positive, as theoretically predicted. Annealing of the Ag film caused an enhancement of the free-electron character of the QWS, thus inducing a negative linear term of the dispersion curve of the surface plasmon. Moreover, we report the first experimental evidence of chemical interface damping in thin films for K/Ag/Ni(111). As regards Na/Cu(111), we found a different dispersion curve compared to thick Na films, thus confirming the enhanced screening by Na QWS.Results reported here should shed light on the influence of QWS on dynamical screening phenomena in thin films.
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References
Valla T, Kralj M, Siber A, Milun M, Pervan P, Johnson PD, Woodruff DP (2000) Oscillatory electron-phonon coupling in ultra-thin silver films on V(100). Journal of Physics: Condensed Matter, 12 (28), L477–L482
Politano A, Formoso V, Chiarello G (2009) Chemical Reactions at Clean and Alkali-Doped Mismatched Metal/Metal Interfaces. Journal of Physical Chemistry C, 113 (1), 316–320
Wei CM, Chou MY (2002) Theory of quantum size effects in thin Pb(111) films. Physical Review B, 66 (23), 233408
Politano A, Agostino RG, Colavita E, Formoso V, Chiarello G (2007) High resolution electron energy loss measurements of Na/Cu(111) and H2O/Na/Cu(111): Dependence of water reactivity as a function of Na coverage. The Journal of Chemical Physics, 126 (24), 244712
Luh DA, Miller T, Paggel JJ, Chiang TC (2002) Large electron-phonon coupling at an interface. Physical Review Letters, 88 (25), 256802
Pfennigstorf O, Petkova A, Guenter HL, Henzler M (2002) Conduction mechanism in ultrathin metallic films. Physical Review B, 65 (4), 045412
Orr BG, Jaeger HM, Goldman AM (1984) Transition-Temperature Oscillations in Thin Superconducting Films. Physical Review Letters, 53 (21), 2046
Chiang T-C (2004) PHYSICS: Superconductivity in Thin Films. Science, 306 (5703), 1900–1901
Politano A, Agostino RG, Colavita E, Formoso V, Chiarello G (2008) Purely quadratic dispersion of surface plasmon in Ag/Ni(111): the influence of electron confinement. Physica Status Solidi-Rapid Research Letters, 2 (2), 86–88
Yu YH, Tang Z, Jiang Y, Wu KH, Wang EG (2006) Thickness dependence of the surface plasmon dispersion in ultrathin aluminum films on silicon. Surface Science, 600 (22), 4966–4971
Pitarke JM, Nazarov VU, Silkin VM, Chulkov EV, Zaremba E, Echenique PM (2004) Theory of acoustic surface plasmons. Physical Review B, 70 (20), 205403
Bastidas CL, Liebsch A, Mochan RL (2001) Influence of d electrons on the dispersion relation of Ag surface plasmons for different single-crystal faces. Physical Review B, 63 (16), 165407
Liebsch A (1998) Prediction of a Ag multipole surface plasmon. Physical Review B, 57 (7), 3803–3806
Kim JS, Chen LM, Kesmodel LL, GarciaGonzalez P, Liebsch A (1997) Surface plasmon dispersion of Cl/Ag(111). Physical Review B, 56 (8), R4402–R4405
Politano A, Formoso V, Chiarello G (2009) Dispersion and damping of surface plasmon in Ag thin films grown on Cu(111) and Ni(111). Superlattices and Microstructures, 46 (1–2), 137–140
Politano A, Formoso V, Chiarello G (2009) Damping of the surface plasmon in clean and K-modified Ag thin films. Journal of Electron Spectroscopy and related Phenomena, 173 (1), 12–17
Politano A, Formoso V, Chiarello G (2008) Dispersion and Damping of Gold Surface Plasmon. Plasmonics, 3 (4), 165–170
Yu YH, Jiang Y, Tang Z, Guo QL, Jia JF, Xue QK, Wu KH, Wang EG (2005) Thickness dependence of surface plasmon damping and dispersion in ultrathin Ag films. Physical Review B, 72 (20), 205405
Savio L, Vattuone L, Rocca M (2003) Surface plasmon dispersion on sputtered and nanostructured Ag(001). Physical Review B, 67 (4), 045406
Rocca M, Moresco F (1996) HREELS and ELS-LEED studies of surface plasmons on Ag and Pd single crystals. Progress in Surface Science, 53 (2–4), 331–340
Moresco F, Rocca M, Zielasek V, Hildebrandt T, Henzler M (1997) ELS-LEED study of the surface plasmon dispersion on Ag surfaces. Surface Science, 388 (1–3), 1–4
Savio L, Vattuone L, Rocca M (2000) Effect of surface interband transitions on surface plasmon dispersion: O/Ag(001). Physical Review B, 61 (11), 7324–7327
Chiarello G, Formoso V, Santaniello A, Colavita E, Papagno L (2000) Surface-plasmon dispersion and multipole surface plasmons in Al(111). Physical Review B, 62 (19), 12676–12679
Moresco F, Rocca M, Hildebrandt T, Zielasek V, Henzler M (1998) Influence of surface interband transitions on surface plasmon dispersion: K/Ag(110). Europhysics Letters, 43 (4), 433–438
Kevan SD (1983) Evidence for a New Broadening Mechanism in Angle-Resolved Photoemission from Cu(111). Physical Review Letters, 50 (7), 526
Tang SJ, Jeng HT, Ismail, Sprunger PT, Plummer EW (2009) Surface electronic band structure and temperature dependence of the surface state at Ā on Mg (10 1– 0) surface. Physical Review B, 80 (8), 085419
Sklyadneva IY, Heid R, Silkin VM, Melzer A, Bohnen KP, Echenique PM, Fauster T, Chulkov EV (2009) Unusually weak electron-phonon coupling in the Shockley surface state on Pd(111). Physical Review B, 80 (4), 045429
Scheybal A, Müller K, Bertschinger R, Wahl M, Bendounan A, Aebi P, Jung TA (2009) Modification of the Cu(110) Shockley surface state by an adsorbed pentacene monolayer. Physical Review B, 79 (11), 115406
Nishimura Y, Kakeya M, Higashiguchi M, Kimura A, Taniguchi M, Narita H, Cui Y, Nakatake M, Shimada K, Namatame H (2009) Surface electronic structures of ferromagnetic Ni(111) studied by STM and angle-resolved photoemission. Physical Review B, 79 (24), 245402
Mulazzi M, Rossi G, Braun J, Minár J, Ebert H, Panaccione G, Vobornik I, Fujii J (2009) Understanding intensities of angle-resolved photoemission with circularly polarized radiation from a Cu(111) surface state. Physical Review B, 79 (16), 165421
Kowalczyk PJ (2009) Investigation of STM tip influence on the recorded position of the Shockley surface state on Au(1 1 1). Surface Science, 603 (5), 747–751
Braun KF, Hla SW (2009) Inelastic quasiparticle lifetimes of the Shockley surface state band on Ni(111). Applied Physics A: Materials Science and Processing, 98 (3), 583–588
Scheybal A, Müller K, Bertschinger R, Wahl M, Bendounan A, Aebi P, Jung TA (2009) Modification of the Cu(110) Shockley surface state by an adsorbed pentacene monolayer. Physical Review B, 79 (11), 115406
Nishimura Y, Kakeya M, Higashiguchi M, Kimura A, Taniguchi M, Narita H, Cui Y, Nakatake M, Shimada K, Namatame H (2009) Surface electronic structures of ferromagnetic Ni(111) studied by STM and angle-resolved photoemission. Physical Review B, 79 (24), 245402
Mulazzi M, Rossi G, Braun J, Minár J, Ebert H, Panaccione G, Vobornik I, Fujii J (2009) Understanding intensities of angle-resolved photoemission with circularly polarized radiation from a Cu(111) surface state. Physical Review B - Condensed Matter and Materials Physics, 79 (16), 165421
Kowalczyk PJ (2009) Investigation of STM tip influence on the recorded position of the Shockley surface state on Au(111). Surface Science, 603 (5), 747–751
Nuber A, Higashiguchi M, Forster F, Blaha P, Shimada K, Reinert F (2008) Influence of reconstruction on the surface state of Au(110). Physical Review B, 78 (19), 195412
Kowalczyk PJ, Puchalski M, Kozłowski W, Dabrowski P, Klusek Z, Olejniczak W (2008) Investigation of the Shockley surface state on clean and air-exposed Au (1 1 1). Applied Surface Science, 254 (15), 4572–4576
Vergniory MG, Pitarke JM, Echenique PM (2007) Self-energy and lifetime of Shockley and image states on Cu(100) and Cu(111): Beyond the GW approximation of many-body theory. Physical Review B, 76 (24), 245416
Higashiguchi M, Shimada K, Arita M, Miura Y, Tobita N, Cui X, Aiura Y, Namatame H, Taniguchi M (2007) High-resolution angle-resolved photoemission study of Ni(1 1 1) surface state. Surface Science, 601 (18), 4005–4009
Schiller F, Laubschat C (2006) Surface states at close-packed surfaces of simple metals. Physical Review B, 74 (8), 085109
Caravati S, Butti G, Brivio GP, Trioni MI, Pagliara S, Ferrini G, Galimberti G, Pedersoli E, Giannetti C, Parmigiani F (2006) Cu(111) and Cu(001) surface electronic states. Comparison between theory and experiment. Surface Science, 600 (18), 3901–3905
Zhang X, Liu J, Li B, Wang K, Ming F, Wang J, Xiao X (2010) Effect of substrate doping concentration on quantum well states of Pb island grown on Si(1 1 1). Surface Science, 604 (2), 175–180
Trontl VM, Pervan P, Milun M (2009) Growth and electronic properties of ultra-thin Ag films on Ni(111). Surface Science, 603 (1), 125–130
Sawa K, Aoki Y, Hirayama H (2009) Thickness dependence of Shockley-type surface states of Ag(111) ultrathin films on Si (111) 7×7 substrates. Physical Review B, 80 (3), 035428
Rybkin AG, Shikin AM, Adamchuk VK (2009) Spectra of quantum states in thin metal films and their modification: Al/ W(110) system. Bulletin of the Russian Academy of Sciences: Physics, 73 (5), 683–685
Pervan P, Milun M (2009) Photoemission from 2D metallic quantum wells. Surface Science, 603 (10–12), 1378–1388
Okuda T, Takeichi Y, He K, Harasawa A, Kakizaki A, Matsuda I (2009) Substrate dependence of anisotropic electronic structure in Ag(111) quantum film studied by angle-resolved photoelectron spectroscopy. Physical Review B, 80 (11), 113409
Lin X, Nilius N, Freund HJ, Walter M, Frondelius P, Honkala K, Häkkinen H (2009) Quantum well states in two-dimensional gold clusters on MgO thin films. Physical Review Letters, 102 (20), 206801
Choi J, Wu J, El Gabaly F, Schmid AK, Hwang C, Qiu ZQ (2009) Quantum well states in Au/Ru(0001) and their effect on the magnetic properties of a Co overlayer. New Journal of Physics, 11, 043016
Wang LL, Ma XC, Ji SH, Fu YS, Shen QT, Jia JF, Kelly KF, Xue QK (2008) Epitaxial growth and quantum well states study of Sn thin films on Sn induced Si(111)- (23×23) R30° surface. Physical Review B, 77 (20), 205410
Tang SJ, Chang WK, Chiu YM, Chen HY, Cheng CM, Tsuei KD, Miller T, Chiang TC (2008) Enhancement of subband effective mass in Ag/Ge(111) thin film quantum wells. Physical Review B, 78 (24), 245407
Pletikosić I, Trontl VM, Milun M, Okević D, Brako R, Pervan P (2008) D-band quantum well states in Ag(111) monolayer films; Substrate-induced shifts. Journal of Physics: Condensed Matter, 20 (35), 355004
Miyata N, Horikoshi K, Hirahara T, Hasegawa S, Wei CM, Matsuda I (2008) Electronic transport properties of quantum-well states in ultrathin Pb (111) films. Physical Review B, 78 (24), 245405
He K, Hirahara T, Okuda T, Hasegawa S, Kakizaki A, Matsuda I (2008) Spin polarization of quantum well states in Ag films induced by the Rashba effect at the surface. Physical Review Letters, 101 (10), 107604
Algdal J, Balasubramanian T, Breitholtz M, Chis V, Hellsing B, Lindgren SÅ, Walldén L (2008) Sodium and potassium monolayers on Be(0001) investigated by photoemission and electronic structure calculations. Physical Review B, 78 (8), 085102
Mathias S, Wessendorf M, Passlack S, Aeschlimann M, Bauer M (2006) Morphological modifications of Ag/Cu(111) probed by photoemission spectroscopy of quantum well states and the Shockley surface state. Applied Physics A: Materials Science and Processing, 82 (3), 439–445
Luh D-A, Cheng C-M, Tsai C-T, Tsuei K-D, Tang J-M (2008) Transition from Disorder to Order in Thin Metallic Films Studied with Angle-Resolved Photoelectron Spectroscopy. Physical Review Letters, 100 (2), 027603
Politano A, Agostino RG, Formoso V, Chiarello G (2008) Short-range interactions in Na coadsorption with CO and O on Ni(111). Chemphyschem, 9 (8), 1189–1194
Politano A, Agostino RG, Colavita E, Formoso V, Tenuta L, Chiarello G (2008) Nature of the alkali surface bond at low coverages investigated by vibrational measurements. Journal of Physical Chemistry C, 112 (17), 6977–6980
Politano A, Formoso V, Chiarello G (2008) Mechanisms Leading to Alkali Oxidation on Metal Surfaces. Journal of Physical Chemistry C, 112 (46), 17772–17774
Politano A, Formoso V, Chiarello G (2009) Effects of O adsorption on the Na + CO/Ni(111) system. Superlattices and Microstructures, 46 (1–2), 10–13
Chiarello G, Barberi R, Amoddeo A, Caputi LS, Colavita E (1996) XPS and AFM characterization of a vanadium oxide film on TiO2(100) surface. Applied Surface Science, 99 (1), 15–19
Rocca M, Biggio F, Valbusa U (1990) Surface-plasmon spectrum of Ag(001) measured by high-resolution angle-resolved electron-energy-loss spectroscopy. Physical Review B, 42 (5), 2835–2841
Marini A, Del Sole R, Onida G (2002) First-principles calculation of the plasmon resonance and of the reflectance spectrum of silver in the GW approximation. Physical Review B, 66 (11), 1151011
Liebsch A (1997) Electronic Excitations at Metal Surfaces, Plenum, New York
Li YB, Levi AC, Rocca M (1995) Anisotropy of Surface-Plasmons in Metals. Surface Science, 336 (3), 371–376
Rocca M (1995) Low-Energy Eels Investigation of Surface Electronic Excitations on Metals. Surface Science Reports, 22 (1–2), 1–71
Pitarke JM, Silkin VM, Chulkov EV, Echenique PM (2007) Theory of surface plasmons and surface-plasmon polaritons. Reports on Progress in Physics, 70, 1–87
Politano A, Chiarello G (2009) Tuning the lifetime of the surface plasmon upon sputtering. Physica Status Solidi-Rapid Research Letters, 3 (5), 136–138
Politano A, Formoso V, Chiarello G (2009) Annealing effects on the plasmonic excitations of metal/metal interfaces. Applied Surface Science, 255 (11), 6038–6042
Politano A, Formoso V, Chiarello G (2009) Electronic properties of metallic bilayers deposited on Cu(111): A comparative study. Surface Science, 603 (6), 933–937
Politano A, Formoso V, Chiarello G (2009) Interference effects in the excitation of collective electronic modes in nanoscale thin Ag films. Superlattices and Microstructures, 46 (1–2), 166–170
Politano A, Formoso V, Colavita E, Chiarello G (2009) Probing collective electronic excitations in as-deposited and modified Ag thin films grown on Cu(111). Physical Review B, 79 (4), 045426
Fujikawa Y, Sakurai T, Tromp RM (2008) Surface Plasmon Microscopy Using an Energy-Filtered Low Energy Electron Microscope. Physical Review Letters, 100 (12), 126803
Moresco F, Rocca M, Hildebrandt T, Henzler M (1999) Plasmon confinement in ultrathin continuous Ag films. Physical Review Letters, 83 (11), 2238–2241
Chelaru LI, Meyer zu Heringdorf FJ (2007) In situ monitoring of surface plasmons in single-crystalline Ag-nanowires. Surface Science, 601 (18), 4541–4545
Lazzari R, Jupille J, Layet JM (2003) Electron-energy-loss channels and plasmon confinement in supported silver particles. Physical Review B, 68 (4), 454281–4542811
Nilius N, Ernst N, Freund HJ (2000) Photon Emission Spectroscopy of Individual Oxide-Supported Silver Clusters in a Scanning Tunneling Microscope. Physical Review Letters, 84 (17), 3994–3997
Varykhalov A, Shikin AM, Gudat W, Moras P, Grazioli C, Carbone C, Rader O (2005) Probing the Ground State Electronic Structure of a Correlated Electron System by Quantum Well States: Ag/Ni(111). Physical Review Letters, 95 (24), 247601
Mróz S, Jankowski Z (1995) Properties of ultrathin silver layers on the Ni(111) face. Surface Science, 322 (1–3), 133–139
Mróz S, Jankowski Z, Nowicki M (2000) Growth and isothermal desorption of ultrathin silver layers on the Ni(111) face at the substrate temperature from 180 to 900 K. Surface Science, 454 (1), 702–706
Mróz S (1995) Directional elastic peak and directional Auger electron spectroscopies - New tools for investigating surface-layer atomic structure. Progress in Surface Science, 48 (1–4), 157–166
Politano A, Chiarello G, Formoso V, Agostino RG, Colavita E (2006) Plasmon of Shockley surface states in Cu(111) : A high-resolution electron energy loss spectroscopy study. Physical Review B, 74 (8), 081401
Borensztein Y, Roy M, Alameh R (1995) Threshold and Linear Dispersion of the Plasma Resonance in Thin Ag Films. EPL (Europhysics Letters), 31 (5–6), 311
Politano A, Formoso V, Chiarello G (2010) Plasmonic Modes Confined in Nanoscale Thin Silver Films Deposited onto Metallic Substrates Journal of Nanoscience and Nanotechnology, 10 (2), 1313–1321
Suto S, Tsuei KD, Plummer EW, Burstein E (1989) Surface-plasmon energy and dispersion on Ag single crystals. Physical Review Letters, 63 (23), 2590–2593
Rocca M, Lazzarino M, Valbusa U (1991) Surface-Plasmon Energy and Dispersion on Ag Single-Crystals - Comment. Physical Review Letters, 67 (22), 3197–3197
Lee G, Sprunger PT, Plummer EW, Suto S (1991) Lee et al. reply. Physical Review Letters, 67 (22), 3198
Feibelman PJ (1982) Surface electromagnetic fields. Progress in Surface Science, 12 (4), 287–407
Feibelman PJ (1973) Sensitivity of surface plasmon dispersion and damping to alkali adsorption. Surface Science, 40 (1), 102–108
Feibelman PJ (1974) Microscopic calculation of surface-plasmon dispersion and damping. Physical Review B, 9 (12), 5077–5098
Feibelman PJ (1993) Perturbation of surface plasmon dispersion by “extra” electrons near a surface. Surface Science Letters, 282 (1–2), 129–136
Feibelman PJ (1994) Comment on Surface plasmon dispersion of Ag. Physical Review Letters, 72 (5), 788
Feibelman PJ (1989) Interpretation of the linear coefficient of surface-plasmon dispersion. Physical Review B, 40 (5), 2752–2756
Feibelman PJ (1973) Sensitivity of surface-plasmon dispersion and damping to potential barrier shape. Physical Review Letters, 30 (20), 975–978
Feibelman PJ (1971) Dependence of the normal modes of plasma oscillation at a bimetallic interface on the electron density profile. Physical Review B, 3 (9), 2974–2982
Feibelman PJ, Tsuei KD (1990) Negative surface-plasmon dispersion coefficient: A physically illustrative, exact formula. Physical Review B, 41 (12), 8519–8521
Rocca M, Lazzarino M, Valbusa U (1992) Surface-Plasmon on Ag(110) - Observation of Linear and Positive Dispersion and Strong Azimuthal Anisotropy. Physical Review Letters, 69 (14), 2122–2125
Silkin VM, Quijada M, Muino RD, Chulkov EV, Echenique PM (2007) Dynamic screening and electron-electron scattering in low-dimensional metallic systems. Surface Science, 601 (18), 4546–4552
Silkin VM, Quijada M, Vergniory MG, Alducin M, Borisov AG, Muino RD, Juaristi JI, Sanchez-Portal D, Chulkov EV, Echenique PM (2007) Dynamic screening and electron dynamics in low-dimensional metal systems. Nuclear Instruments & Methods in Physics Research Section B-Beam Interactions with Materials and Atoms, 258 (1), 72–78
Chiang TC (2000) Photoemission studies of quantum well states in thin films. Surface Science Reports, 39 (7–8), 181–235
Tsuei KD, Plummer EW, Liebsch A, Pehlke E, Kempa K, Bakshi P (1991) The Normal-Modes at the Surface of Simple Metals. Surface Science, 247 (2–3), 302–326
Rocca M, Lazzarino M, Valbusa U (1992) Plasmon Damping and Surface Interband-Transitions on Ag(001) and (011). Surface Science, 270, 560–562
Rocca M, Li YB, Demongeot FB, Valbusa U (1995) Surface-Plasmon Dispersion and Damping on Ag(111). Physical Review B, 52 (20), 14947–14953
Rocca M, Moresco F, Valbusa U (1992) Temperature-Dependence of Surface-Plasmons on Ag(001). Physical Review B, 45 (3), 1399–1402
Rocca M, Valbusa U (1990) Angular-Dependence of Dipole Scattering Cross-Section - Surface-Plasmon Losses on Ag(100). Physical Review Letters, 64 (20), 2398–2401
Rocca M, Valbusa U (1993) Electronic Excitations on Silver Single-Crystal Surfaces. Surface Science, 287, 770–775
Quijada M, Muino RD, Echenique PM (2005) The lifetime of electronic excitations in metal clusters. Nanotechnology, 16 (5), S176–S180
Quijada M, Borisov AG, Nagy I, Muino RD, Echenique PM (2007) Time-dependent density-functional calculation of the stopping power for protons and antiprotons in metals. Physical Review A, 75 (4), 042902
Politano A, Agostino RG, Colavita E, Formoso V, Chiarello G (2009) Collective Excitations in Nanoscale Thin Alkali Films: Na/Cu(111). Journal of Nanoscience and Nanotechnology, 9 (6), 3932–3937
Zielasek V, Ronitz N, Henzler M, Pfnur H (2006) Crossover between monopole and multipole plasmon of Cs monolayers on Si(111) individually resolved in energy and momentum. Physical Review Letters, 96 (19), 196801
Tsuei KD, Plummer EW, Feibelman PJ (1989) Surface-plasmon dispersion in simple metals. Physical Review Letters, 63 (20), 2256–2259
Tu KN, Mayer JV, Feldman LC (1992) Electronic Thin Films Science. Macmillan, New York
Bendounan A, Fagot Revurat Y, Kierren B, Bertran F, Yurov VY, Malterre D (2002) Surface state in epitaxial Ag ultrathin films on Cu(1 1 1). Surface Science, 496 (1–2), L43–L49
De Crescenzi M, Piancastelli MN (1996) Electron Scattering and Related Spectroscopies, World Scientific, Singapore
Moresco F, Rocca M, Hildebrandt T, Zielasek V, Henzler M (1999) K adsorption on Ag(110), effect on surface structure and surface electronic excitations. Surface Science, 424 (1), 62–73
Persson BNJ (1993) Polarizability of small spherical metal particles: influence of the matrix environment. Surface Science, 281 (1–2), 153–162
Hövel H, Fritz S, Hilger A, Kreibig U, Vollmer M (1993) Width of cluster plasmon resonances: Bulk dielectric functions and chemical interface damping. Physical Review B, 48 (24), 18178–18188
Bendounan A, Forster F, Ziroff J, Schmitt F, Reinert F (2005) Influence of the reconstruction in Ag/Cu (111) on the surface electronic structure: Quantitative analysis of the induced band gap. Physical Review B, 72 (7), 075407
Schiller F, Cordón J, Vyalikh D, Rubio A, Ortega JE (2005) Fermi Gap Stabilization of an Incommensurate Two-Dimensional Superstructure. Physical Review Letters, 94 (1), 016103
Zacharias P, Kliewer KL (1976) Dispersion relation for the 3.8 eV volume plasmon of silver. Solid State Communications, 18 (1), 23–26
He JH, Carosella CA, Hubler GK, Qadri SB, Sprague JA (2006) Bombardment-Induced Tunable Superlattices in the Growth of Au-Ni Films. Physical Review Letters, 96 (5), 056105
Yuan Z, Gao S (2008) Landau damping and lifetime oscillation of surface plasmons in metallic thin films studied in a jellium slab model. Surface Science, 602 (2), 460–464
Chiarello G, Cupolillo A, Caputi LS, Papagno L, Colavita E (1997) Collective and single-particle excitations in thin layers of K on Ni(111). Surface Science, 377 (1–3), 365–370
Politano A, Chiarello G (2010) Sputtering-induced modification of the electronic properties of Ag/Cu(111). Journal of Physics D: Applied Physics 43 (8), 085302
Stephanov MA (2009) Non-Gaussian Fluctuations near the QCD Critical Point. Physical Review Letters, 102 (3), 032301
Politano A, Agostino RG, Colavita E, Formoso V, Chiarello G (2007) Electronic properties of self-assembled quantum dots of sodium on Cu(111) and their interaction with water. Surface Science, 601 (13), 2656–2659
Tsuei K-D, Plummer EW, Feibelman PJ (1989) Surface-plasmon dispersion in simple metals. Physical Review Letters, 63 (20), 2256–2259
Silkin VM, Chulkov EV (2006) Energy and lifetime of surface plasmon from first-principles calculations. Vacuum, 81 (2), 186–191
Bagchi A, Duke CB, Feibelman PJ, Porteus JO (1971) Measurement of surface-plasmon dispersion in aluminum by inelastic low-energy electron diffraction. Physical Review Letters, 27 (15), 998–1001
Sprunger PT, Watson GM, Plummer EW (1992) The normal modes at the surface of Li and Mg. Surface Science, 269–270, 551–555
Liebsch A, Schaich WL (1995) Influence of a Polarizable Medium on the Nonlocal Optical-Response of a Metal-Surface. Physical Review B, 52 (19), 14219–14234
Perri S, Lepreti F, Carbone V, Vulpiani A (2007) Position and velocity space diffusion of test particles in stochastic electromagnetic fields. Europhysics Letters, 78 (4), 40003
Chulkov EV, Silkin VM, Echenique PM (2000) Inverse lifetime of surface states on metals. Surface Science, 454, 458–461
Steeb F, Mathias S, Fischer A, Wiesenmayer M, Aeschlimann M, Bauer M (2009) The nature of a nonlinear excitation pathway from the Shockley surface state as probed by chirped pulse two photon photoemission. New Journal of Physics, 11, 013016
Bonzel HP, Bradshaw AM, Ertl G (1989) Alkali Adsorption on Metals and Semiconductors, Elsevier, Amsterdam
Palik ED (1985) Handbook of Optical Constants of Solids. Academic Press, New York
Nazarov VU (1999) Multipole surface plasmon excitation enhancement in metals. Physical Review B, 59 (15), 9866–9869
Tsuei KD, Plummer EW, Liebsch A, Kempa K, Bakshi P (1990) Multipole Plasmon Modes at a Metal-Surface. Physical Review Letters, 64 (1), 44–47
Eremeev SV, Rusina GG, Borisova SD, Chulkov EV (2008) Electron-phonon interaction in the quantum well state of the 1 ML Na/Cu(111) system. Physics of the Solid State, 50 (2), 323–329
Fuyuki M, Watanabe K, Ino D, Petek H, Matsumoto Y (2007) Electron-phonon coupling at an atomically defined interface: Na quantum well on Cu(111). Phys Rev B, 76 (11), 115427
Hoffmann G, Berndt R, Johansson P (2003) STM-induced fluorescence from Na monolayers on Cu(111). Physics of Low-Dimensional Structures, 3-4, 209–219
Politano A, Agostino RG, Colavita E, Formoso V, Chiarello G (2008) Electronic properties of (3/2×3/2)-Na/Cu(111).J Electron Spectrosc Relat Phenom, 162 (1), 25–29
Langer T, Förster DF, Busse C, Michely T, Pfnür H, Tegenkamp C (2011) Sheet plasmons in modulated graphene on Ir(111). New J Phys, 13 (5), 053006
Langer T, Baringhaus J, Pfnür H, Schumacher HW, Tegenkamp C (2010) Plasmon damping below the Landau regime: the role of defects in epitaxial graphene. New J Phys, 12, 033017
Liu Y, Willis RF (2009) The evolution of sheet-plasmon behavior in silver monolayers on Si(111)-(Ö3×Ö3)-Ag surface. Surf Sci, 603 (13), 2115-2119
Pfnür H, Langer T, Baringhaus J, Tegenkamp C (2011) Multiple plasmon excitations in adsorbed two-dimensional systems. J Phys: Condens Matter, 23 (11), 112204
Tegenkamp C, Pfnür H, Langer T, Baringhaus J, Schumacher HW (2011) Plasmon electron–hole resonance in epitaxial graphene. J Phys: Condens Matter, 23 (1), 012001
Politano A, Marino AR, Formoso V, Farías D, Miranda R, Chiarello G (2011) Evidence for acoustic-like plasmons on epitaxial graphene on Pt(111). Phys Rev B, 84 (3), 033401
Borca B, Barja S, Garnica M, Minniti M, Politano A, Rodriguez-García JM, Hinarejos JJ, Farías D, Vázquez de Parga AL, Miranda R (2010) Electronic and geometric corrugation of periodically rippled, self-nanostructured graphene epitaxially grown on Ru(0001). New J Phys, 12 (9), 093018
Politano A, Agostino RG, Colavita E, Formoso V, Tenuta L, Chiarello G (2008) Nature of the alkali surface bond at low coverages investigated by vibrational measurements.J Phys Chem C, 112 (17), 6977-6980
Politano A, Formoso V, Chiarello G (2008) Temperature effects on alkali-promoted CO dissociation on Ni(111). Surf Sci, 602 (12), 2096–2100
Politano A, Formoso V, Chiarello G (2008) Alkali adsorption on Ni(111) and their coadsorption with CO and O. Appl Surf Sci, 254 (21), 6854–6859
Politano A, Formoso V, Chiarello G (2008) Mechanisms Leading to Alkali Oxidation on Metal Surfaces. J Phys Chem C, 112 (46), 17772–17774
Robba D, Ori DM, Sangalli P, Chiarello G, Depero LE, Parmigiani F (1997) A photoelectron spectroscopy study of sub-monolayer V/TiO2(001) interfaces annealed from 300 up to 623 K. Surf Sci, 380 (2–3), 311–323
Caputi LS, Chiarello G, Papagno L (1985) Carbonaceous layers on Ni (110) and (100) studied by AES and EELS. Surf Sci, 162 (1–3), 259–263
De Crescenzi M, Colavita E, Papagno L, Chiarello G, Scarmozzino R, Caputi LS, Rosei R (1983) Electronic properties of Fe80B20 alloys: ordering and disordering effects. J Phys F Met Phys, 13 (4), 895–907
Chiarello G, Robba D, De Michele G, Parmigiani F (1993) An X-ray Photoelectron-Spectroscopy Study of the Vanadia Titania Catalysts. Appl Surf Sci, 64 (2), 91–96
Ciambelli P, Bagnasco G, Lisi L, Turco M, Chiarello G, Musci M, Notaro M, Robba D, Ghetti P (1992) Vanadium-Oxide Catalysts Supported on Laser-Synthesized Titania Powders - Characterization and Catalytic Activity in the Selective Reduction of Nitric-Oxide. Appl Catal B Environ, 1 (2), 61–77
Acknowledgments
We want to thank Dr. Stefan Mathias and Prof. Michael Bauer for having allowed to use their photoemission data, and, moreover, dr. Vincenzo Formoso for many helpful discussions.
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Politano, A., Chiarello, G. (2012). Influence of Electron Quantum Confinement on the Electronic Response of Metal/Metal Interfaces. In: Geddes, C. (eds) Reviews in Plasmonics 2010. Reviews in Plasmonics, vol 2010. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-0884-0_3
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