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Diquat and endothall: Their fates in the environment

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Residue Reviews

Part of the book series: Reviews of Environmental Contamination and Toxicology ((RECT,volume 62))

Abstract

In recent years, the increasing use of herbicides in the U.S. has been accentuated by the aquatic weed problem caused by eutrophication. Certain herbicides developed mainly for agriculture are being used successfully to control aquatic weed nuisances. Among the herbicides gaining wide acceptance for the control of terrestrial and aquatic vegetation are diquat and endothall.

This work was supported by the College of Agricultural and Life Sciences and the Water Resources Center, University of Wisconsin-Madison, Hatch Project No. 1915 and Office of Water Resources and Technology Grant No. 14-01-001-1567.

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References

  • Akhavein, A. A., and D. L. Linscott: The dipyridylium herbicides, paraquat and diquat. Residue Reviews 23, 97 (1968).

    PubMed  CAS  Google Scholar 

  • Alabaster, J. S.: Survival of fish in 164 herbicides, insecticides, fungicides, wetting agents and miscellaneous substances. Internat. Pest Control, pp. 29–35, Mar./ Apr. (1969).

    Google Scholar 

  • Au, F. H. T.: Preliminary study on microbial effect on endothall. Unpub. rept., Agricultural Chemicals Division, Pennwalt Corp., Tacoma, Wash., Oct. 15 (1962).

    Google Scholar 

  • Bailey, G. W., and J. D. White: Review of adsorption and desorption of organic pesticides by soil colloids, with implications concerning bioactivity. J. Agr. Food Chem. 12, 324 (1964).

    Article  CAS  Google Scholar 

  • Bailey, G. W., and J. D. White: Factors influencing the adsorption, desorption, and movement of pesticides in soil. Residue Reviews 32, 29 (1970).

    PubMed  CAS  Google Scholar 

  • Baldwin, B. C.: Translocation of diquat in plants. Nature 198, 872 (1963).

    Article  Google Scholar 

  • Baldwin, B. C., M. F.Bray, and M. J. Geoghegan: The microbial decomposition of paraquat. Biochem. J. 101, 15P (1966).

    CAS  Google Scholar 

  • Beasley, P. G.: Dipyridylium residues in an aquatic environment. Ph.D. Thesis, Auburn Univ., Auburn, Ala. (1966).

    Google Scholar 

  • Best, J. A., J. B. Weber, and S. B. Weed: Competitive adsorption of diquat2+, paraquat2+, and Ca2+ on organic matter and exchange resins. Soil Sci. 114, 444 (1972).

    Article  CAS  Google Scholar 

  • Black, C. C., and L. Meyers: Some biochemical aspects of the mechanisms of herbicidal activity. Weeds 14, 331 (1966).

    Article  CAS  Google Scholar 

  • Black, W. J. M., A. Calderbank, G. Douglas, and R. H. Mckenna: Residues in herbage and silage and feeding experiments following the use of diquat as desiccant. J. Sci. Food Agr. 17, 506 (1966).

    Article  CAS  Google Scholar 

  • Blackburn, R. D., and L. W. Weldon: Results of 3 years of testing diquat as an aquatic herbicide in Florida. Proc. S. Weed Control Conf. 16, 365 (1963).

    Google Scholar 

  • Blackburn, R. D., and L. W. Weldon: Field of aquatic herbicides; and ecological studies. Florida Agr. Exp. Sta. Rept., pp. 318–319 (1965).

    Google Scholar 

  • Bohmont, B. L.: Toxicity of herbicides to livestock, honey bees, and wildlife. Proc. W. Weed Control Conf. 21, 25 (1967).

    CAS  Google Scholar 

  • Bond, C. E., R. H. Lewis, and J. L. Fryer: Toxicity of various herbicidal materials to fishes. Trans. 1959 Seminar: Biological problems in water pollution, pp. 96–101. The Robert A. Taft Engineering Center, Tech. Rept. W60-3. Public Health Service, U.S. Department of Health, Education, and Welfare, Cincinnati, Ohio (1960).

    Google Scholar 

  • Brian, R. C.: The bipyridylium quaternary salts: The effect of atmospheric and soil humidity on the uptake and movement of diquat and paraquat in plants. Weed Res. 6, 292 (1966).

    Article  CAS  Google Scholar 

  • Brian, R. C.: The uptake and absorption of diquat and paraquat by tomato, sugar beet, and cocksfoot. Ann. Applied Biol. 59, 91 (1967).

    Article  CAS  Google Scholar 

  • Brian, R. C., and J. Ward: The influence of environment on potato haulm kill by diquat and its residues in tubers. Weed Res. 7, 117 (1967).

    Article  CAS  Google Scholar 

  • Burkhalter, A. P.: Guidelines for aquatic weed control. Rept. Florida Dept. of Natural Resources, Tallahassee, Fla., pp. 1–66 (1972).

    Google Scholar 

  • Burkhalter, A. P., L. M. Curtis, R. L. Lazor, M. L. Beach, and J. C. Clark: Aquatic weed identification and control manual. Bureau of Plant Research and Control, Florida Dept. Natural Resources, Tallahassee, Fla. (undated).

    Google Scholar 

  • Burns, R. G., and L. J. Audus: Distribution and breakdown of paraquat in soil. Weed Res. 10, 49 (1970).

    Article  CAS  Google Scholar 

  • Butler, P. A.: Effects of herbicides on estuarine fauna. Proc. S. Weed Control Conf. 18, 576 (1965).

    CAS  Google Scholar 

  • Calderbank, A.: The bipyridylium herbicides. Adv. Pest Control Res. 8, 127 (1968).

    PubMed  CAS  Google Scholar 

  • Calderbank, A., and S. H. Yuen: An improved method for determining residues of diquat. Analyst 91, 625 (1966).

    Article  CAS  Google Scholar 

  • C. B. Morgan, and S. H. Yuen: Determination of diquat residues in potato tubers. Analyst 86, 569 (1961).

    Article  Google Scholar 

  • Carlson, R. E.: Qualitative detection of endothall in water by thin layer chromatography. Unpub. rept. Agr. Chem. Div., Pennwalt Corp., Tacoma, Wash. (undated).

    Google Scholar 

  • Carlson, R. E.: Analysis of endothall in water by gas-liquid chromatography. Unpub. rept. Agr.

    Google Scholar 

  • Carlson, R. E.: Chem. Div., Pennwalt Corp., Tacoma, Wash., April 27 (1964).

    Google Scholar 

  • Carlson, R. E.: Bioassay of endothall. Unpub. rept. Agr. Chem. Div., Pennwalt Corp., Tacoma, Wash., Feb. (1966).

    Google Scholar 

  • Carlson, R. E.: Analytical method for residues of endothall in water. Unpub. rept. Agr. Chem. Div., Pennwalt Corp., Tacoma, Wash., July 8 (1970).

    Google Scholar 

  • Carlson, R. E.: Analytical method for residues of endothall in various crops and other materials. Unpub. rept. Agchem-Decco Div., Pennwalt Corp., Tacoma, Wash., Sept. 29 (1971).

    Google Scholar 

  • Chevron Chemical Company: Analysis of diquat residues. Ortho Division, Research and Development Department, Richmond, Calif., July (1967).

    Google Scholar 

  • Coats, G. E., H. H. Funderburk, JR., J. M. Lawrence, and D. E. Davis: Persistence of diquat and paraquat in pools and ponds. Proc. S. Weed Control Conf. 17, 304 (1964).

    Google Scholar 

  • Coats, G. E., H. H. Funderburk, JR., J. M. Lawrence, and D. E. Davis: Factors affecting persistence and inactivation of diquat and paraquat. Weed Research 6, 58 (1966).

    Article  CAS  Google Scholar 

  • Comes, R. D., D. W. Bohmont, and H. P. Alley: Movement and persistence of endothall (3,6-endoxohexahydrophthalic acid) as influenced by soil texture, temperature, and moisture levels. J. Amer. Soc. Sugar Beet Technol. 11, 287 (1961).

    Article  Google Scholar 

  • Cope, O. B.: Toxicity of endothall salts to rainbow trout. Letter rept. to E. J. Bowles, Agr. Chem. Div., Pennwalt Chemicals Corp., Fresno, Calif., July 23 (1965).

    Google Scholar 

  • Cope, O. B.: Contamination of the freshwater ecosystem by pesticides. J. Applied Ecol. 3 (Suppl.), 33 (1966).

    Article  Google Scholar 

  • Crawford, L. M., and W. D. Black: Herbicide toxicity to domestic animals. Proc. 23rd Ann. Meet. S. Weed Sci. Soc., pp. 362–365 (1970).

    Google Scholar 

  • Crosby, D. G., and R. K. Tucker: Toxicity of aquatic herbicides to Daphnia magna. Science 54, 289 (1966).

    Article  Google Scholar 

  • Currier, H. B.: Protoplasmic response to endothall. Abstr. Joint Meet. Amer. Soc. Plant Physiol., Bot. Soc. Amer., Santa Barbara, Calif., June 16 (1953).

    Google Scholar 

  • Damanakis, M., D. S. H. Drennan, J. D. Fryer, and K. Holly: The adsorption and mobility of paraquat on different soils and soil constituents. Weed Res. 10, 264 (1970).

    Article  CAS  Google Scholar 

  • Daniel, J. W., and J. C. Gage: Absorption and excretion of diquat and paraquat in rats. Brit. J. Ind. Med. 23, 133 (1966).

    CAS  Google Scholar 

  • Daniel, T. C.: Evaluation of diquat and endothall for the control of water milfoil (Myriophyllum exalhescens) and the effect of weedkill on the nitrogen and phosphorus status of a waterbody. Ph.D. Thesis, Univ. Wis., Madison, Wis. (1972).

    Google Scholar 

  • Davies, P. J. T.: Uptake, movement, and physiological activities of l,l’-ethylene-2,2’-dipyridylium dichloride in submersed aquatic plants. M. S. Thesis, Univ. Calif., Davis, Calif. (1964).

    Google Scholar 

  • Davies, P. J. T., and D. E. Seaman: Uptake and translocation of diquat in Elodea. Weed Sci. 16, 293 (1968).

    CAS  Google Scholar 

  • Davis, H. C., and H. Hindu: Effects of pesticides on embryonic development of clams and oysters and on survival and growth of larvae. U.S. Fish and Wildlife Service Fishery Bull. 67, 393 (1969).

    CAS  Google Scholar 

  • Dixon, J. B., D. E.Moore, N. P. Agnihotri, and D. E. Lewis, JR.: Exchange of diquat2+ in soil clays, vermiculite and smectite. Soil Sci. Soc. Amer. Proc. 34, 805 (1970).

    CAS  Google Scholar 

  • Engelhardt, J., and W. P. Mckinley: Bipyridylium herbicides. Polarography of 1,1 ‘-ethylene-2,2’-bipyridylium dibromide. J. Agr. Food Chem. 14, 377 (1966).

    Article  CAS  Google Scholar 

  • Faust, S. D., and N. E. Hunter: Chemical methods for the detection of aquatic herbicides. J. Amer. Water Works Assoc. 57, 1028 (1965).

    CAS  Google Scholar 

  • Fish, G. R.: Some effects of the destruction of aquatic weeds in Lake Rotoiti, New Zealand. Weed Res. 6, 350 (1966).

    Article  Google Scholar 

  • Frank, P. A., and R. D. Comes: Herbicidal residues in pond water and hydrosoil. Weeds 15, 210 (1967).

    Article  CAS  Google Scholar 

  • Freed, V. H., and I. Gauditz: The absorption and metabolism of radioendothall by fish and aquatic plants. Proc. NE Weed Control Conf. 15, 560 (1961).

    Google Scholar 

  • Freed, V. H., and R. E. Hughes: Spectrofluorometric determination of 1:l’-ethylene-2:2’- bipyridylium dibromide (FB 12). Weeds 7, 364 (1959).

    Article  Google Scholar 

  • Freed, V. H., M. L. Montgomery, and S. C. Fang: The absorption and translocation of 14C labelled endothall in red beets and spinach. Unpub. rept. Agr. Chem. Div., Pennwalt Corp., Tacoma, Wash, (undated).

    Google Scholar 

  • Fry, J. C., M. P. Brooker, and P. L. Thomas: Changes in the microbial populations of a reservoir treated with the herbicide paraquat. Water Res. 7, 395 (1973).

    Article  CAS  Google Scholar 

  • Funderburk, H. H., JR.: Diquat and paraquat. In P. C. Kearney and D. D. Kaufman (eds.): Degradation of herbicides, pp. 283–298. New York: Marcel Dekker (1969).

    Google Scholar 

  • Funderburk, H. H., and G. A. Bozarth: Review of the metabolism and decomposition of diquat and paraquat. J. Agr. Food Chem. 15, 563 (1967).

    Article  CAS  Google Scholar 

  • Funderburk, H. H., and J. M. Lawrence: A sensitive method for determination of low concentrations of diquat and paraquat. Nature 199, 1011 (1963).

    Article  CAS  Google Scholar 

  • Funderburk, H. H., and J. M. Lawrence: Mode of action and metabolism of diquat and paraquat. Weeds 12, 259 (1964).

    Article  CAS  Google Scholar 

  • Funderburk, H. H., N. S. Negi, and J. M. Lawrence: Photochemical decomposition of diquat and paraquat. Weeds 14, 240 (1966).

    Article  CAS  Google Scholar 

  • Gajan, R. J.: Recent developments in the detection and determination of pesticides and their residues by oscillographic polarography. Residue Reviews 6, 75 (1964).

    PubMed  CAS  Google Scholar 

  • Gilderhus, P. A.: Effects of diquat on bluegills and their food organisms. Progressive Fish-Culturist 29, 67 (1967).

    Article  CAS  Google Scholar 

  • Grzenda, A. R., H. P. Nicholson, and W. S. Cox: Persistence of four herbicides in pond water. J. Amer. Water Works Assoc. 58, 326 (1966).

    Google Scholar 

  • Harris, C. I., and G. F. Warren: Adsorption and desorption of herbicides by soil. Weeds 12, 120 (1964).

    Article  Google Scholar 

  • Headford, D. W. R., and G. Douglas: Tuber necrosis following the desiccation of potato foliage with diquat. Weed Res. 7, 131 (1967).

    Article  CAS  Google Scholar 

  • Helling, C. S., P. C. Kearney, and M. Alexander: Behavior of pesticides in soils. Adv. Agron. 23, 147 (1971).

    Article  CAS  Google Scholar 

  • Hilsenhoff, W.: Effect of diquat on aquatic insects and related animals. J. Econ. Entomol. 59, 1520 (1966).

    CAS  Google Scholar 

  • Hiltibran, R. C.: Duration of toxicity of endothall in water. Weeds 10, 17 (1962).

    Article  CAS  Google Scholar 

  • Hiltibran, R. C.: Effects of some herbicides on fertilized fish eggs and fry. Trans. Amer. Fisheries Soc. 96, 414 (1967).

    Article  CAS  Google Scholar 

  • Hiltibran, R. C.: Aquatic weed control in Illinois. Hyacinth Control J. 7, 11 (1968).

    Google Scholar 

  • Hiltibran, R. C., D. L. Underwood, and J. S. Fickle: Fate of diquat in the aquatic environment. Water Resources Center, Research Rept. 52, pp. 1–45. Univ. of 111., Urbana, 111. (1972).

    Google Scholar 

  • Holmberg, D. J.: The effects and persistence of endothall in aquatic environment. M. S. Thesis, Univ. of Wis., Univ. of Wis. (1973).

    Google Scholar 

  • Homer, R. F., G. C. Mees, and T. E. Tolimson: Mode of action of dipyridyl quaternary salts as herbicides. J. Sci. Food Agr. 11, 309 (1960).

    Article  CAS  Google Scholar 

  • Horowitz, M.: Breakdown of endothall in soil. Weed Res. 6, 168 (1966).

    Article  CAS  Google Scholar 

  • Howe, D. J. T., and N. Wright: The toxicity of paraquat and diquat. Proc. New Zealand Weed and Pest Control Conf. 18, 105 (1965).

    CAS  Google Scholar 

  • Hughes, J. S., and J. T. Davis: Comparative toxicity to bluegill sunfish of granular and liquid herbicides. Proc. 16th Ann. Conf. SE Assoc. Game Fish Commissioners, pp. 319–323 (1965).

    Google Scholar 

  • Inglis, A., and E. L. Davis: Effects of water hardness on the toxicity of several organic and inorganic herbicides to fish, pp. 1–22. Tech. Paper 67, Bureau of Sport Fisheries and Wildlife, U.S. Department of Interior, Washington, D.C. (1972).

    Google Scholar 

  • Jensen, H. L.: Studies on soil bacteria (Arthrobacter globiformis) capable of decomposing the herbicide endothall. Acta Agr. Scand. 14, 193 (1964 a).

    Google Scholar 

  • Jensen, H. L.: Biologisk s0nderdeling af ukrudtsmidler i jordbunden III. Endothal. Tidskr. Plavl. 68, 553 (1964 b).

    Google Scholar 

  • Jones, R. O.: Tolerance of the fry of common warm-water fishes to some chemicals employed in fish culture. Proc. 16th Ann. Conf. SE Assoc. Game Fish Commissioners, pp. 436–445 (1965).

    Google Scholar 

  • Kay, K.: Toxicology of pesticides: Recent advances. Environ. Res. 6, 202 (1973).

    Article  PubMed  CAS  Google Scholar 

  • Kearney, P. C., D. D. Kaufman, and M. Alexander: Biochemistry of herbicide decomposition in soils. In A. D. McLaren and G. H. Peterson (eds.): Soil biochemistry, pp. 318–342. New York: Marcel Dekker (1967).

    Google Scholar 

  • Keckemet, O.: Chemical, toxicological, and biological properties of endothall. Hyacinth Control J. 8, 50 (1969).

    Google Scholar 

  • Khan, S. U.: Interaction of bipyridylium herbicides with organo-clay complex. J. Soil Sci. 24, 244 (1973 a).

    Google Scholar 

  • Khan, S. U.: Interaction of humic substances with bipyridylium herbicides. Can. J. Soil Sci. 53, 199 (1973 b).

    Google Scholar 

  • Khan, S. U.: Determination of diquat and paraquat residues in soil by gas chromatography. J. Agr. Food Chem. 22, 863 (1974 a).

    Google Scholar 

  • Khan, S. U.: Humic substances reactions involving bipyridylium herbicides in soil and aquatic environments. Residue Reviews 52, 1 (1974 b).

    Google Scholar 

  • Khan, S. U.: Adsorption of bipyridylium herbicides by humic acid. J. Environ. Qual. 3, 202 (1974 c).

    Google Scholar 

  • Kirsten, W. J.: The determination of diquat residues in potato tubers. Analyst 91, 732 (1966).

    Article  CAS  Google Scholar 

  • Knight, B. A. G., and T. E. Tolimson: The interaction of paraquat (1:l’-dimethyl 4:4’-dipyridylium dichloride) with mineral soils. J. Soil Sci. 18, 233 (1967).

    Article  CAS  Google Scholar 

  • Landskov, A. O., and R. E. Carlson: Analytical method for residues in water. Unpub. rept., Agr. Chem. Div., Pennwalt Corp., Tacoma, Wash., Sept. 23 (1968).

    Google Scholar 

  • Lawrence, J. M., H. H. Funderburk, JR., R. D. Blackburn and P. G. Beasley: The status of diquat and paraquat as aquatic herbicides. Proc. 16th Ann. Conf. SE Assoc. Game Fish Commissioners, pp. 247–257 (1965).

    Google Scholar 

  • Lindaberry, H. L.: Considerations regarding the use of aquathol in potable watersheds. Proc. NE Weed Control Conf. 15, 451 (1961).

    Google Scholar 

  • Litchfield, M. H., J. W. Daniel, and S. Longshaw: The tissue distribution of the bipyridylium herbicides diquat and paraquat in rats and mice. Toxicology 1, 155 (1973).

    Article  PubMed  CAS  Google Scholar 

  • Little, E. C. S.: The control of water weeds. Weed Res. 8, 79 (1968).

    Article  CAS  Google Scholar 

  • Maestri, M.: Structural and functional effects of endothall on plants. Ph.D. Thesis, Univ. of Calif., Davis, Calif. (1967).

    Google Scholar 

  • Maestri, M., and H. B. Currier: Interactions of maleic hydrazide and endothall. Weeds 6, 315 (1958).

    Article  CAS  Google Scholar 

  • Maestri, M., and H. B. Currier: Toxic effects of endothall. Plant Physiol., Proc. Ann. Meetings, Univ. Maryland, p. V II (1966).

    Google Scholar 

  • Mann, J. D., L. S. Jordan, and B. E. Day: A survey of herbicides for their effect upon protein synthesis. Plant Physiol. 40, 151 (1965).

    Article  Google Scholar 

  • Mann, J. D., and M. Pu: Inhibition of lipid synthesis by certain herbicides. Weed Sci. 16, 197 (1968).

    CAS  Google Scholar 

  • May, B. E., R. S. Hestand, and J. M. Van Dyke: Comparative effects of diquat plus copper sulfate on aquatic organisms. Weed Sci. 21, 249 (1973).

    CAS  Google Scholar 

  • Mees, G. C.: Experiments on the herbicidal action of l-l’-ethylene-2,2’-dipyridylium dibromide. Ann. Applied Biol. 48, 601 (1960).

    Article  CAS  Google Scholar 

  • Michaelis, L., and E. S. Hill: The viologen indicators. J. Gen. Physiol. 16, 859 (1933).

    Article  PubMed  CAS  Google Scholar 

  • Montgomery, M. L., and V. H. Freed: The absorption and metabolism of endothall when used as a post-emergence treatment for beets. Unpub. rept., Agr. Chem. Div., Pennwalt Corp., Tacoma, Wash., Feb. 13 (1961).

    Google Scholar 

  • Montgomery, M. L., and V. H. Freed: Progress report on the study of the degradation products of endothall in soil. Unpub. rept., Agr. Chem. Div., Pennwalt Corp., Tacoma, Wash., Sept. 23 (1963).

    Google Scholar 

  • Montgomery, M. L., and V. H. Freed: Metabolism of endothall. Unpub. rept., Agr. Chem. Div., Pennwalt Corp., Tacoma, Wash., Nov. 12 (1964).

    Google Scholar 

  • Montgomery, M. L., V. H. Freed, and F. Teeny: The uptake of C14 from endothall-C14 by beets and spinach. Unpub. rept., Agr. Chem. Div., Pennwalt Corp., Tacoma, Wash, (undated).

    Google Scholar 

  • Morton, H. L., J. O. Moffett, and R. H. Macdonald: Toxicity of herbicides to newly emerged honey bees. Environ. Entomol. 1, 102 (1972).

    CAS  Google Scholar 

  • Müller, V. B., and M. Worseck: Eine Methode zur semiquantitativen dün006Eschichtchromatografischen Bestimmung von Diquat (Handelsname: Reglone) und Paraquat (Handelsname: Gramoxone). Monats, für Veterinärmedizin 14, 560 (1970).

    Google Scholar 

  • Namdeo, K. N.: Biodegradation of paraquat dichloride. Indian J. Exp. Biol. 10, 133 (1972),

    Google Scholar 

  • Newman, J. F., and J. M. Way: Some ecological observations on the use of paraquat and diquat as aquatic herbicides. Proc. 8th Brit. Weed Control Conf. 2, 582 (1966).

    CAS  Google Scholar 

  • Parker, C.: Influence of water hardness on the phytotoxicity of paraquat. Nature 212, 1465 (1966).

    Article  CAS  Google Scholar 

  • Portmann, J. E., and K. W. Wilson: The toxicity of 140 substances to the brown shrimp and other marine animals. Ministry of Agriculture, Fisheries and Food Fisheries Laboratory, Burnham-on-Crouch, Essex, Eng., Shellfish Information Leaflet No. 22, pp. 1–12 (1971).

    Google Scholar 

  • Sanders, H. O.: Toxicity of pesticides to the crustacean Qammarus lacustris, pp. 1–18. Tech. Paper 25, Bureau of Sport Fisheries and Wildlife, U.S. Department of Interior, Washington, D.C. (1969).

    Google Scholar 

  • Sanders, H. O.: Toxicities of some herbicides to six species of freshwater crustaceans. J. Water Pollution Control Fed. 42, 1544 (1970 a).

    Google Scholar 

  • Sanders, H. O.: Pesticide toxicities to tadpoles of the western chorus frog Pseudacris triseriata and Fowler’s toad Bufo woodhousii fowleri. Copeia 1970, 246 (1970b).

    Article  Google Scholar 

  • Scott, D. C., and J. B. Weber: Herbicide phytotoxicity as influenced by adsorption. Soil Sci. 104, 151 (1967).

    Article  CAS  Google Scholar 

  • Serns, S. L.: The effects of a dipotassium endothall treatment on the ecology of a small pond. Research Rept., Water Resources Section, Wis. Dept. Nat. Resources, Madison, Wis., pp. 1–40 (1974).

    Google Scholar 

  • Serns, S. L.: Private communication (1975).

    Google Scholar 

  • Sharp, C. W., and E. M. Lores, JR.: Chromatographic parameters of the bisquaternary herbicides, paraquat and diquat. J. Agr. Food Chem. 22, 458 (1974).

    Article  CAS  Google Scholar 

  • Sikka, H. C.: Fate of herbicides in the aquatic environment. Ann. Rept., Life Sci. Div., Syracuse Univ. Res. Corp., Syracuse, N.Y. (1971).

    Google Scholar 

  • Sikka, H. C., and C. P. Rice: Persistence of endothall in aquatic environment as determined by gas-liquid chromatography. J. Agr. Food Chem. 21, 842 (1973).

    Article  CAS  Google Scholar 

  • Sikka, H. C., and J. Saxena: Metabolism of endothall by aquatic microorganisms. J. Agr. Food Chem. 21, 402 (1973).

    Article  CAS  Google Scholar 

  • Simsiman, G. V., and G. Chesters: Persistence of diquat in the aquatic environment. Water Res. Accepted for publication (1975a).

    Google Scholar 

  • Simsiman, G. V., and G. Chesters: Persistence of endothall in the aquatic environment. Water, Air, and Soil Pollution. Accepted for publication (1975 b).

    Google Scholar 

  • Simsiman, G. V., G. Chesters, and T. C. Daniel: Chemical control of aquatic weeds and its effect on the nutrient and redox status of water and sediment. Proc. 15th Conf. Great Lakes Research 1972, 166 (1972).

    Google Scholar 

  • Slade, P.: Photochemical degradation of paraquat. Nature 207, 515 (1965).

    Article  CAS  Google Scholar 

  • Slade, P.: The fate of paraquat applied to plants. Weed Res. 6, 158 (1966).

    Article  CAS  Google Scholar 

  • Slade, P., and A. E. Smith: Photochemical degradation of diquat. Nature 213, 919 (1967).

    Article  CAS  Google Scholar 

  • Slodki, M. E., and L. J. Wickerham: Extracellular polysaccharides and classification of the genus Lipomyces. J. Gen. Microbiol. 42, 381 (1966).

    PubMed  CAS  Google Scholar 

  • Smith, A. E.: Residues in potato tubers following haulm desiccation with 14C-diquat. Bull. Environ. Contam. Toxicol. 2, 169 (1967).

    Article  CAS  Google Scholar 

  • Smith, A. E., and J. Grove: Photochemical degradation of diquat in dilute aqueous solution and on silica gel. J. Agr. Food Chem. 17, 609 (1969).

    Article  CAS  Google Scholar 

  • Smith, J. M., and G. R. Sagar: A reexamination of the influence of light and dark-ness on the long-distance transport of diquat in Lycopersicon esculentum Mill. Weed Res. 6, 314 (1966).

    Article  CAS  Google Scholar 

  • Soderquist, C. J., and D. G. Crosby: The gas chromatographic determination of paraquat in water. Bull. Environ. Contam. Toxicol. 8, 363 (1972).

    Article  PubMed  CAS  Google Scholar 

  • Soo, A., I. Tinsley, and S. C. Fang: Metabolism of 14C-endothall in rats. J. Agr. Food Chem. 15, 1019 (1967).

    Article  Google Scholar 

  • Steucke, E. W.: Observations on the use of disodium endothall in fish hatchery ponds. Weed Abstr. 12, 197 (1963).

    Google Scholar 

  • Stevens, M. A., and J. K. Walley: Tissue and milk residues arising from the ingestion of single doses of diquat and paraquat by cattle. J. Sci. Food Agr. 17, 472 (1966).

    Article  CAS  Google Scholar 

  • Surber, E. W., and Q. H. Pickering: Acute toxicity of endothall, diquat, hyamine, dalapon, and silvex to fish. Prog. Fish-Culturist 24, 164 (1962).

    Article  CAS  Google Scholar 

  • Sutton, D. L., R. D. Blackburn, and W. R. Barlowe: Response of aquatic plants to combinations of endothall and copper. Weed Sci. 19, 643 (1971).

    CAS  Google Scholar 

  • Swabey, Y. H., and C. F. Schenk: Algicides and aquatic herbicides. Proc. 3rd Ann. Meeting Aq. Weed Control Soc., pp. 1–20 (1963).

    Google Scholar 

  • Thomas, T. M.: Uptake and fate of endothall in submersed aquatic plants. M. S. Thesis, Univ. of Calif., Davis, Calif. (1966).

    Google Scholar 

  • Thrower, S. L., N. D. Hallam, and L. B. Thrower: Movement of diquat (1,1’- ethylene-2,2’-bipyridylium) dibromide in leguminous plants. Ann. Applied Biol. 55, 253 (1965).

    Article  CAS  Google Scholar 

  • Tischler, N., J. C. Bates, and G. P. Quimba: A new group of defoliant herbicidal chemicals. Proc. NE Weed Control Conf. 4, 51 (1950).

    Google Scholar 

  • Tu, C. M.: Interaction between dipyridylium herbicides and microbes in soil. Ph.D. Thesis, Ore. State Univ., Corvallis, Ore. (1966).

    Google Scholar 

  • Tucker, B. V., A. Omid, and W. D. Thomas: Paraquat soil bonding and plant response. Weed Sci. 17, 448 (1969).

    CAS  Google Scholar 

  • Tucker, B. V., D. E. Pack, and J. N. Ospenson: Adsorption of bipyridylium herbicides in soil. J. Agr. Food Chem. 15, 1005 (1967).

    Article  CAS  Google Scholar 

  • Walker, C. R.: Endothall derivatives as aquatic herbicides in fishery habitats. Weeds 11, 226 (1963).

    Article  Google Scholar 

  • Walsh, G. E.: Effects of herbicides on photosynthesis and growth of marine unicellular algae. Hyacinth Control J. 10, 45 (1972).

    Google Scholar 

  • Way, J. M., J. F. Newman, N. W. Moore, and F. W. Knaggs: Some ecological effects of the use of paraquat for the control of weeds in small lakes. J. Applied Ecol. 8, 509 (1971).

    Article  Google Scholar 

  • Weber, J. B.: Interaction of organic pesticides with particulate matter in aquatic and soil systems. Adv. Chem. Series 111, 52 (1972).

    Google Scholar 

  • Weber, J. B., and H. D. Coble: Microbial decomposition of diquat adsorbed on montmorillonite and kaolinite clays. J. Agr. Food Chem. 16, 475 (1968).

    Article  CAS  Google Scholar 

  • Weber, J. B., and D. C. Scott: Availability of a cationic herbicide adsorbed on clay minerals to cucumber seedlings. Science 152, 1400 (1966).

    Article  PubMed  CAS  Google Scholar 

  • Weber, J. B. and S. B. Weed: Adsorption and desorption of diquat, paraquat, and prometone by montmorillonitic and kaolinitic clay minerals. Soil Sci. Soc. Amer. Proc. 32, 485 (1968).

    CAS  Google Scholar 

  • Weber, J. B. and S. B. Weed: Effect of soil on the biological activity of pesticides. In W. D. Guenzi (ed.): Pesticides in soil and water, pp. 223–256. Madison, Wis.: Soil Sci. Soc. Amer., Inc. (1974).

    Google Scholar 

  • Weber, J. B., R. C. Meek, and S. B. Weed: The effect of cation exchange capacity on the retention of diquat and paraquat by three-layer type clay minerals: II. Plant availability of paraquat. Soil Sci. Soc. Amer. Proc. 33, 382 (1969 a).

    Google Scholar 

  • Weber, J. B., P. W. Perry, and R. P. Upchurch: The influence of temperature and time on the adsorption of paraquat, diquat, 2,4-D and prometone by clays, charcoal, and an anion-exchange resin. Soil Sci. Soc. Amer. Proc. 29, 678 (1965).

    CAS  Google Scholar 

  • Weber, J. B., S. B. Weed, and J. A. Best: Displacement of diquat from clay and its phytotoxicity. J. Agr. Food Chem. 17, 1075 (1969 b).

    Google Scholar 

  • Weed, S. B., and J. B. Weber: The effect of cation exchange capacity on the retention of diquat and paraquat by three-layer type clay minerals. I. Adsorption and release. Soil Sci. Soc. Amer. Proc. 33, 379 (1969).

    CAS  Google Scholar 

  • Weil, C. S., N. Confra, C. Haun, and J. A. Striegel: Experimental carcinogenicity, acute toxicity of representative epoxides. Amer. Ind. Hyg. Assoc. J. 24, 305 (1963).

    Article  CAS  Google Scholar 

  • Wellborn, T. L., Jr.: The toxicity of nine therapeutic and herbicidal compounds to striped bass. Progressive Fish-Culturist 31, 27 (1969).

    Article  CAS  Google Scholar 

  • Wellborn, T. L., Jr.: Toxicity of some compounds to striped bass fingerlings. Progressive Fish-Culturist 33, 32 (1971).

    Article  CAS  Google Scholar 

  • Wicks, G. A., and E. N. Anderson: Effectiveness of PEBC, DATC and endothall for controlling weeds in sugar beets in western Nebraska. J. Amer. Soc. Sugar Beet Technol. 13, 81 (1964).

    Google Scholar 

  • Wilson, D. C., and C. E. Bond: The effects of the herbicides Diquat® and dichlobenil (Casoron®) on pond invertebrates. Part I. Acute toxicity. Trans. Amer. Fish Soc. 98, 438 (1969).

    Article  CAS  Google Scholar 

  • Wright, K. A., and R. B. Cain: Microbial formation of methylamine from 4-carboxy-1-methylpyridinium chloride, a photolytic product of paraquat. Soil Biol. Biochem. 1, 5 (1969).

    CAS  Google Scholar 

  • Yeo, R. R.: Dissipation of diquat and paraquat, and effects on aquatic weeds and fish. Weeds 15, 42 (1967).

    Article  CAS  Google Scholar 

  • Yeo, R. R.: Dissipation of endothall and effects on aquatic weeds and fish. Weed Sci. 18, 282 (1970).

    CAS  Google Scholar 

  • Yuen, S. H., J. E. Bagness, and D. Myles: Spectrophotometric determination of diquat and paraquat in aqueous herbicide formulations. Analyst 92, 375 (1967).

    Article  PubMed  CAS  Google Scholar 

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Simsiman, G.V., Daniel, T.C., Chesters, G. (1976). Diquat and endothall: Their fates in the environment. In: Gunther, F.A., Hylin, J.W., Westlake, W.E. (eds) Residue Reviews. Reviews of Environmental Contamination and Toxicology, vol 62. Springer, New York, NY. https://doi.org/10.1007/978-1-4613-9404-4_11

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