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Protons in Solution

  • John O’M. Bockris
  • Ronald A. Fredlein

Abstract

H9O4+ is often given as a reasonable configuration for the proton in solution. Using the Born equation and the equations for ion-dipole and ion-quadrupole interactions, show that the proton affinity of water must be about 180 kcal mole−1. The absolute individual heat of hydration of protons in water is −263 kcal mole−1.

Keywords

Proton Transfer Proton Affinity Lithium Chloride Chloroacetic Acid Standard Free Energy Change 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1973

Authors and Affiliations

  • John O’M. Bockris
    • 1
  • Ronald A. Fredlein
    • 2
  1. 1.The Flinders UniversityAdelaideAustralia
  2. 2.The University of NewcastleAustralia

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