Abstract
Important advances in experimental and theoretical methods for the study of surface phenomena have been made in the last decade. A modern treatment of the adsorption of gases on solids can now include as a significant theme considerations of the quantum mechanical behavior of electrons and atoms at surfaces. The primary objective here is to discuss adsorption processes and the nature of adsorbed layers in terms of the phenomenological models and concepts that arise from comparative interpretation of experimental information as well as in terms of the emerging connection between these concepts and established principles of quantum chemistry and physics. In the latter regard, recent developments in the theory of adsorption and in semiempirical calculations are also discussed to examine what insight may be achieved in the interpretation of experimental data and what directions may be suggested for future experimental work. The secondary objective is to provide a guide of a critical nature to significant recently published work illustrative of important methods and concepts. Although a major effort is made to achieve sufficient breadth to present an accurate perspective, the subject by its nature requires a good deal of selectivity to achieve focus and coherency. We do not attempt to make a complete review or to present a detailed account of the historical development of the field. The intention is to achieve a cogent and representative introduction to the present state of the subject.
This chapter is dedicated to Lester H. Germer for his inspiring commitment to the study of the microscopic behavior of solid surfaces.
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© 1976 Bell Telephone Laboratories, Incorporated
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Rhodin, T.N., Adams, D.L. (1976). Adsorption of Gases on Solids. In: Hannay, N.B. (eds) Treatise on Solid State Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-4313-4_5
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DOI: https://doi.org/10.1007/978-1-4613-4313-4_5
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