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Stabilized 2-Norbornyl Cations

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The Nonclassical Ion Problem

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Abstract

The position that the importance of neighboring group participation should diminish as an incipient cationic center is stabilized by substitution1 appears to be generally accepted.2 Consequently, we undertook to synthesize representative 2-norbornyl systems containing a stabilizing p-anisyl group at the 2-position in order to establish its effect on the exo :endo rate and product ratios.

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Authors and Affiliations

  1. Purdue University, West Lafayatte, Indiana, USA

    Herbert C. Brown

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  1. Herbert C. Brown
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© 1977 Plenum Press, New York

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Brown, H.C. (1977). Stabilized 2-Norbornyl Cations. In: The Nonclassical Ion Problem. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-4118-5_7

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  • DOI: https://doi.org/10.1007/978-1-4613-4118-5_7

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-4120-8

  • Online ISBN: 978-1-4613-4118-5

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