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The Mass Spectra of Permethylated Disaccharides

  • E. C. de Jong
  • W. Heerma
  • B. C. G. Dujardin
  • J. Haverkamp
  • J. F. G. Vliegenthart

Abstract

Disaccharides have been investigated most of the time as their trimethylsilyl ethers, mainly because of their case of preparation (1–3). However permethylderivatives of oligosaccharides have considerable adavantages, as has been pointed out by Das and Thayumanavan (4) and by Moor and Waight (5) in their systematic investigation of permethylated oligosaccharides. In the latter investigation Moor et al. described the differences between the spectra of only those disaccharides with a 1 – 1, 1 – 2, 1 – 4 or a 1 – 6 glycosidic bond.

Keywords

Mass Spectrum Base Peak Glycosidic Linkage Bond Type Trimethylsilyl Ether 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1).
    N.K. Kochetkov, O.S. Chizhov and N.V. Molodtsov, Tetrahedron, 1968, 24, 5587.CrossRefGoogle Scholar
  2. 2).
    J. Vink, J.J. de Ridder, J.P. Kamerling and J.F.G. Vliegenthart, Tetrahedron, 1971, 27, 4275.CrossRefGoogle Scholar
  3. 3).
    J.P. Kamerling, J.F.G. Vliegenthart, J. Vink and J.J. de Ridder, Tetrahedron, 1972, 28, 4375.CrossRefGoogle Scholar
  4. 4).
    K.G. Das and B. Thayumanavan, Org. Mass. Spectrom., 1972, 6, 1063.CrossRefGoogle Scholar
  5. 5).
    J. Moor and E.S. Waight, Biomed. Mass Spectrom., 1975, 2, 36.CrossRefGoogle Scholar
  6. 6).
    J. Vink, “Mass spectra of monosaccharides, pattern recognition as an identification method”, Thesis, Utrecht, The Netherlands, 1974.Google Scholar
  7. 7).
    J.P. Kamerling, “Structure determination of oligosaccharides”, Thesis, Utrecht, The Netherlands, 1972.Google Scholar
  8. 8).
    P. Nägeli, “Beitrag zur computerunterstützten Interpretation von Massenspektren organischer Verbindungen mit Hilfe von Pattern Recognition und Spektrenvergleich”, Thesis, ETH Zürich, Switzerland, 1975.Google Scholar

Copyright information

© Plenum Press, New York 1978

Authors and Affiliations

  • E. C. de Jong
    • 1
  • W. Heerma
    • 1
  • B. C. G. Dujardin
    • 1
  • J. Haverkamp
    • 2
  • J. F. G. Vliegenthart
    • 1
  1. 1.Laboratory of Analytical ChemistryUtrechtThe Netherlands
  2. 2.Laboratory of Organic ChemistryUtrechtThe Netherlands

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