Abstract
At the present time we have at our disposal a large variety of experimental techniques for the characterization of solute species in solutions and the studies of their properties. Among these nuclear magnetic resonance of metallic nuclei is becoming an increasingly important probe of their behavior in solutions and, in particular, of very weak interactions of the respective ions with solvents, counterions, or complexing agents. This presentation will attempt to describe briefly some of the recent applications of alkali metal, magnesium-25, and silver-109 nmr measurements to the study of ions in solutions.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
C. W. Burges, R. Koschmieder, W. Sahm and A. Schwenk, Z. Naturforsch., 28a, 1753 (1973).
J. E. Wertz and D. Jardetzky, Chem. Phys., 25, 357 (1956).
D. Jardetzky and J. E. Wertz, J. Amer. Chem. Soc., 82, 318 (1960).
R. E. Richards and B. A. Yorke, Molecular Phys., 6, 289 (1963).
C. Deverell and R. E. Richards, Ibid., 10, 551 (1966).
E. G. Bloor and R. G. Kidd, Can. J. Chem., 46, 3425 (1968).
R. H. Erlich, E. Roach and A. I. Popov, J. Amer. Chem. Soc., 92, 4989 (1970).
R. H. Erlich and A. I. Popov, ibid., 93, 5620 (1971).
V. Gutmann, “Coordination Chemistry in Nonaqueous Solvents,” Springer-Verlag, Vienna, 1968.
M. S. Greenberg, D. M. Wied and A. I. Popov, Spectrochim. Acta, 29A, 1927 (1973).
G. E. Maciel, J. K. Hancock, L. F. Lafferty, P. A. Mueller and K. Musker, Inorg. Chem., 5, 554 (1966).
J. W. Akitt and A. J. Downs, Chem. Comm., 1966, 222.
Y. M. Cahen, R. P. Handy, E. T. Roach and A. I. Popov, J. Phys. Chem., 79, 80 (1975).
C. J. Jameson and H. S. Gutowsky, J. Chem. Phys., 40, 1714 (1964).
W. J. DeWitte, R. C. Schoening and A. I. Popov, Inorg. Nucl. Chem. Lett., 12, 251 (1976).
W. J. DeWitte, L. Liu, E. Mei, J. L. Dye and A. I. Popov, J. Solution Chem., In Press.
J. S. Shih and A. I. Popov, Inorg. Nucl. Chem. Lett., In Press.
L. Simeral and G. E. Maciel, J. Phys. Chem., 80, 552 (1976).
C. J. Pedersen, J. Amer. Chem. Soc, 89, 2495, 7017 (1967).
B. Dietrich, J. M. Lehn and J. P. Sauvage, Tetrahed. Letters, 1969, 2885.
J. M. Ceraso and J. L. Dye, J. Amer. Chem. Soc, 95, 4432 (1973).
J. P. Kintzinger and J.-M. Lehn, ibid., 96, 3313 (1974).
Y. M. Cahen, J. L. Dye and A. I. Popov, J. Phys. Chem., 79, 1289 (1975).
Y. M. Cahen, J. L. Dye and A. I. Popov, ibid., 79, 1292 (1975).
E. Mei, J. L. Dye and A. I. Popov, J. Amer. Chem. Soc., 98, 1619 (1976).
A. M. Grotens, J. Smid and E. de Boer, Chem. Comm., 1971, 759.
J. M. Lehn, Structure and Bonding, 16, 1 (1973).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1978 Plenum Press, New York
About this paper
Cite this paper
Popov, A.I. (1978). Alkali Metal, Magnesium-25, and Silver-109 NMR Studies of Complex Compounds in Nonaqueous Solvents. In: Mamantov, G. (eds) Characterization of Solutes in Nonaqueous Solvents. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3982-3_3
Download citation
DOI: https://doi.org/10.1007/978-1-4613-3982-3_3
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4613-3984-7
Online ISBN: 978-1-4613-3982-3
eBook Packages: Springer Book Archive