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Influence of the Solvent on the Orientation of Ambidentate Solvent and Ligand Molecules in the Coordination Sphere of Metal Ions

  • Floyd FarhaJr.
  • Wayne C. Boring
  • Merton R. Olds
  • Reynold T. Iwamoto
Conference paper

Abstract

Studies on the nature and behavior of inorganic species in nonaqueous media, over the years, have dealt primarily with monofunctional solvents such as acetonitrile, acetone, dimethyl sulfoxide, dimethylformamide, and ethanol. In this paper, we describe some of our work on the nature and behavior of inorganic species in difunctional solvents where there is the possibility of monocoordination by either or both functional groups. More specifically, our studies focus on the influence of the solvent on the orientation of difunctional or ambidentate solvent molecules in the coordination sphere of metal ions.

Keywords

Propylene Carbonate Proton Magnetic Resonance Data Proton Magnetic Resonance Study Downfield Shift Nitrile Group 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

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    F. Farha, Jr. and R. T. Iwamoto, J. Electroanal. Chem., 8, 55 (1964).CrossRefGoogle Scholar
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    W. C. Boring and R. T. Iwamoto, Inorg. Chim. Acta, 7, 264 (1973).CrossRefGoogle Scholar
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    J. F. Coetzee and D. K. McGuire, J. Phys. Chem., 67, 1810 (1963).CrossRefGoogle Scholar
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    V. Gutman, “Coordination Chemistry in Nonaqueous Solutions,” Springer-Verlag, New York, New York, 1968, p. 19.Google Scholar
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    M. R. Olds and R. T. Iwamoto, Anal. Chem., 47, 2394 (1975).CrossRefGoogle Scholar

Copyright information

© Plenum Press, New York 1978

Authors and Affiliations

  • Floyd FarhaJr.
    • 1
  • Wayne C. Boring
    • 1
  • Merton R. Olds
    • 1
  • Reynold T. Iwamoto
    • 1
  1. 1.Department of ChemistryUniversity of KansasLawrenceUSA

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