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Ionic Collisions as the Basis for New Types of Mass Spectra

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Collision Spectroscopy

Abstract

Recently developed techniques for ion structure determination employ ion-molecule reactions in which the ion of interest undergoes a change in charge. These charge permutation reactions can be classified into two categories: (a) charge stripping, in which electrons are removed (stripped) from the high-energy ion, or (b) charge exchange, in which electrons are transferred between the ion and a neutral collision gas. In this chapter we will be concerned with the following four specific charge permutation reactions of polyatomic organic ions.

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References

  1. J. H. Beynon, R. M. Caprioli, W. E. Baitinger, and J. W. Amy, Int. J. Mass Spectrom. Ion Phys. 3, 313 (1969).

    Article  CAS  Google Scholar 

  2. J. H. Beynon, R. G. Cooks, and T. Keough, Int. J. Mass Spectrom. Ion Phys. 14, 437 (1974).

    Google Scholar 

  3. (a) R. Conrad, Phys. J. 31, 888 (1930); (b) J. J. Thomson, Phil. Mag. 24, 668 (1912); (c) S. Meyerson and R. W. Vander Haar, J. Chem. Phys. 37, 2458 (1962).

    CAS  Google Scholar 

  4. T. Ast, J. H. Beynon, and R. G. Cooks, Org. Mass Spectro. 6, 749 (1972).

    Article  CAS  Google Scholar 

  5. T. Ast and J. H. Beynon, Org. Mass Spectro. 7, 503 (1973).

    Article  CAS  Google Scholar 

  6. D. L. Smith and L. Kevan, J. Am. Chem. Soc. 93, 2113 (1971).

    Article  Google Scholar 

  7. D. L. Smith and L. Kevan, in Recent Developments in Mass Spectrometry (K. Ogata and T. Hayakawa, eds.), Univ. of Tokyo Press, 1970, p. 883.

    Google Scholar 

  8. F. L. Mohler, V. H. Dibeler, and R. M. Reese, J. Chem. Phys. 22, 394 (1954).

    Article  CAS  Google Scholar 

  9. J. H. Beynon, G. R. Lester, and A. E. Williams, J. Phys. Chem. 63, 1861 (1959).

    Article  CAS  Google Scholar 

  10. T. Ast, J. H. Beynon, and R. G. Cooks, Org. Mass Spectrom. 6, 741 (1972).

    Article  CAS  Google Scholar 

  11. F. W. McLafferty, in Mass Spectrometry of Organic Ions (F. W. McLafferty, ed.), Academic Press, New York, 1963, p. 318.

    Google Scholar 

  12. T. Keough, J. H. Beynon, and R. G. Cooks, J. Am. Chem. Soc. 95, 1695 (1973).

    Article  CAS  Google Scholar 

  13. V. H. Dibeler, R, M. Reese, and J. L. Franklin, J. Am. Chem. Soc. 83, 1813 (1961).

    Article  CAS  Google Scholar 

  14. C. E. Brion and L. A. R. Olsen, Int. J. Mass Spectrom. Ion Phys. 9, 413 (1972).

    Article  CAS  Google Scholar 

  15. T. Keough, Ph.D. Thesis, Purdue University, 1972, p. 127.

    Google Scholar 

  16. E. G. Bloom, F. L. Mohler, J. H. Lengel, and C. E. Wise, J. Res. Natl. Bur. Std. 40, 437 (1948).

    CAS  Google Scholar 

  17. T. Ast, Ph.D. Thesis, Purdue University, 1972, p. 89

    Google Scholar 

  18. R. G. Cooks, J. H. Beynon, R. M. Caprioli, and G. R. Lester, Metastable Ions, Elsevier, Amsterdam, 1973, p. 139.

    Google Scholar 

  19. D. L. Kemp, J. H. Beynon, and R. G. Cooks, Org. Mass Spectrom. 11, 857 (1976).

    Article  CAS  Google Scholar 

  20. J. F. Litton, unpublished results.

    Google Scholar 

  21. J. H. Bowie and J. Blumenthal, J. Am. Chem. Soc. 97, 2959 (1975).

    Article  CAS  Google Scholar 

  22. J. Marriott and J. D. Craggs, Applied Mass Spectrometry, Institute of Petroleum, London, 1954.

    Google Scholar 

  23. M. Von Ardenne, K. Steinfelder, and R. Tummler, Angew. Chem. 73, 136 (1961).

    Article  CAS  Google Scholar 

  24. C. F. Giese and W. B. Maier, III, J. Chem. Phys. 39, 739 (1963).

    Article  CAS  Google Scholar 

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© 1978 Plenum Press, New York

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Kemp, D.L., Cooks, R.G. (1978). Ionic Collisions as the Basis for New Types of Mass Spectra. In: Cooks, R.G. (eds) Collision Spectroscopy. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3955-7_6

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  • DOI: https://doi.org/10.1007/978-1-4613-3955-7_6

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-3957-1

  • Online ISBN: 978-1-4613-3955-7

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