Abstract
Recently, solutions of micelles and cyclodextrins have been shown to be effective mobile phases in liquid chromatography. The term pseudophase chromatography has been coined to describe those separations where the partitioning of solutes occur primarily to a species solubilized in the mobile phase rather than to the bulk mobile phase. Since the partitioning to the pseudophase utilizes both electrostatic and hydrophobic interactions, effective separations can be performed. In addition, many water insoluble-hydrophobic substances can now be chromatographed for the first time with inexpensive, nontoxic aqueous solutions. Recent applications of pseudophase chromatography as well as some theoretical aspects are discussed.
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© 1982 Plenum Press, New York
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Armstrong, D.W. (1982). Use of Micellar and Cyclodextrin Solutions in Liquid Chromatographic Separations. In: Mittal, K.L., Fendler, E.J. (eds) Solution Behavior of Surfactants. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3494-1_36
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DOI: https://doi.org/10.1007/978-1-4613-3494-1_36
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4613-3496-5
Online ISBN: 978-1-4613-3494-1
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