Abstract
The reaction of vitamin B12s, generated by the reduction of aquocobalamin, with l-chloro-2,2-bis (p-chlorophenyl)ethane results in the formation of 2,2-bis(p-chlorophenyl)ethyl cobalamin (B12-DDMS). In the vitamin B12-DDMS adduct, the hydrocarbon moiety is σ-bonded to the cobalt atom in the sixth coordination position.
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References
J. H. Fendler and E. J. Fendler, “Catalysis in Micellar and Macromolecular Systems”, Academic Press, 1975.
E. J. Fendler and J. H. Fendler, Adv. Phys. Org. Chem., 8, 271 (1970).
C. A. Bunton, Prog. Solid State Chem, 8, 239 (1973).
E. H. Cordes and C. Gitler, Prog. Bioorg. Chem., 2, 1 (1973).
E. H. Cordes, Ed., “Reaction Kinetics in Micelles”, Plenum Press, New York, 1973.
W. P. Jencks, Adv. Enzymol., 43, 219 (1975)
T. C. Bruice, “Enzymes”, 3rd edition, 2, 217 (1970).
H. Morawetz, Adv. Catal. Rel. Subj., 20, 341 (1969).
I. V. Berezin, K. Martinek and A. K. Yatsimirskii, Chem., Rev., 42, 787 (1973).
E. H. Cordes and R. B. Dunlap, Acc. Chem. Res., 2, 329 (1969).
J. M. Pratt, “Inorganic Chemistry of Vitamin B, ”, Academic Press, New York, 1972.
R. H. Prince and D. A. Stotter, J. Inorg. Nucl. Chem., 35, 321 (1973).
J. H. Fendler, F. Nome and H. C. Van Woert, J. Am. Chem. Soc., 96, 6745 (1974).
F. Nome and J. H. Fendler, J. Chem. Soc., Dalton Trans., 1212 (1976).
F. Nome and J. H. Fendler, J. Chem. Soc., 99, 1557 (1977).
G. C. Robinson, F. Nome, and J. H. Fendler, J. Am. Chem. Soc., 99, 4969 (1977).
L. S. Beckmann and D. G. Brown, Biochim. Biophys. Acta, 428, 720 (1976).
K. Martinek, A. P. Osipou, A. K. Yatsimirskii and I. V. Berezin, Tetrahedron, 709 (1975).
C. A. Bunton and L. S. Romsted, in “Solution Behavior of Surfactants - Theoretical and Applied Aspects”, K. L. Mittal and E. J. Fendler, Eds., Plenum Press, New York, this volume.
F. Nome and D. Zanette, Can. J. Chem., in press.
F. Nome, E. Schwingel and L. G. Ionescu, J. Org. Chem., 45, 705 (1980).
R. Barnett, H. P. C. Hogenkamp, and R. H. Abeles, J. Biol. Chem., 241, 1483 (1966).
U. Tonellato, in “Solution Chemistry of Surfactants”, K. L. Mittal, Editor, Vol. 2, pp. 541-, Plenum Press, New York, 1979.
C. A. Bunton and L. G. Ionescu, J. Am. Chem. Soc., 95, 1212 (1973).
F. H. Quina and H. Chaimovich, J. Phys. Chem., 83, 1844 (1979).
D. Zanette and F. Nome, J. Org. Chem., 44, 2308 (1979). 1157
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Nome, F., Neves, A., Ionescu, L.G. (1982). Specific Role of Functional Micelles in the Catalysis of an Elimination Reaction. In: Mittal, K.L., Fendler, E.J. (eds) Solution Behavior of Surfactants. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3494-1_27
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DOI: https://doi.org/10.1007/978-1-4613-3494-1_27
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