Vanadyl(IV) EPR Spin Probes Inorganic and Biochemical Aspects

  • N. Dennis Chasteen

Abstract

Many proteins have metal ions as an integral part of their structure or require them as cofactors in enzyme catalysis. In many cases, these metal ions serve as useful spectrochemical probes of molecular structure, electron transfer, and enzyme kinetics (Vallee and Williams, 1968; Vallee and Wacker, 1970; Ochiai, 1977; Hughes, 1972; Eichhorn and Marzilli, 1979). Often the native metal (frequently zinc) can be removed and another metal ion substituted which has different and sometimes more desirable spectroscopic properties. By judicious choice of substitute metal ion to match particular technique, e.g., nuclear magnetic resonance (NMR), Mössbauer, optical absorption, or electron paramagnetic resonance (EPR) spectroscopy, much can be learned about the metal binding site and its role in the function of the protein.

Keywords

Hydrolysis Lignin Titration Perchlorate Uridine 

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Copyright information

© Plenum Press, New York 1981

Authors and Affiliations

  • N. Dennis Chasteen
    • 1
  1. 1.Department of ChemistryUniversity of New HampshireDurhamUSA

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