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Group Theoretical Examination of the Far Infrared Spectra of Tm2 (SO4)3 • 8 H2O and TmCl3 • 6 H2O

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The Rare Earths in Modern Science and Technology

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Abstract

In 1972 the far infrared spectra of hydrated tripositive thulium sulfate and chloride were presented without analysis (1,2). The work was done to observe the spectra directly and support the validity of vibrational assignments made on the basis of vibronic spectra of these crystals observed in the visible region.

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References

  1. B.W. Berringer, J.B. Gruber, and E.A. Karlow, Far Infrared Spectra of Hydrated and Anhydrous Tripositive Thulium Sulfate, J. Inorg. Nucl. Chem., 34: 2084 (1972)

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  2. B. W. Berringer, J.B. Gruber, D.N. Olsen, and J. Stöhr, Far Infrared Spectra of Hydrated and Anhydrous Thulium Chloride, J. Inorg. Nucl. Chem., 34: 373 (1972)

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  3. W.G. Fately, Neil T. McDevitt, and Freeman F. Bently, Infrared and Raman Selection Rules for Lattice Vibration: The Correlation Method, Appl. Spectrosc., 25: 155 (1971)

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  4. William G. Fately, Infinite Number of Sites for Bravais Space Cell, Appl, Sectrosc, 27: 395 (1973)

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  5. Joachim Stöhr, Ernst Seidel and John B. Gruber, Spectroscopic Evidence for Higher Symmetry Effects in Monoclinic Tm2 (SO 4) 3 •8H 2 O, J. Chem. Phys., 61:4820 (1974) and references therein.

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  6. J. B. Gruber, USAEC Progress Report, RLO-2012-3, p. 109 (1969)

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Author information

Authors and Affiliations

  1. Community College of Allegheny County, Boyce Campus, Monroeville, Pa., 15146, USA

    Burton W. Berringer

Authors
  1. Burton W. Berringer
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Editor information

Editors and Affiliations

  1. North Dakota State University, Fargo, North Dakota, USA

    Gregory J. McCarthy

  2. Pennsylvania State University, University Park, Pennsylvania, USA

    Gregory J. McCarthy

  3. National Bureau of Standards, Washington, D.C., USA

    James J. Rhyne

  4. University of Texas at San Antonio, San Antonio, Texas, USA

    Herbert B. Silber

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© 1980 Plenum Press, New York

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Berringer, B.W. (1980). Group Theoretical Examination of the Far Infrared Spectra of Tm2 (SO4)3 • 8 H2O and TmCl3 • 6 H2O. In: McCarthy, G.J., Rhyne, J.J., Silber, H.B. (eds) The Rare Earths in Modern Science and Technology. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-3054-7_86

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  • DOI: https://doi.org/10.1007/978-1-4613-3054-7_86

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-3056-1

  • Online ISBN: 978-1-4613-3054-7

  • eBook Packages: Springer Book Archive

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