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The Intermediate-Field Method

  • E. König
  • S. Kremer
Chapter

Abstract

The Hamiltonian of the system is again determined by Eq. (4.1), the case of intermediate-field coupling being characterized by
$$ \sum\limits_{{i > j}} {\tfrac{{{{e}^{2}}}}{{{{r}_{i}}_{j}}}} > \sum\limits_{i} {{{V}_{{LF}}}} ({{r}_{{i,}}}{{\theta }_{{i,}}}{{\varphi }_{i}}) > \sum\limits_{i} {\xi ({{r}_{i}})({{s}_{i}}.{{l}_{i}})}$$
(5.1)
(5.1)Equation (5.1) specifies the requirement that the ligand field interaction should be larger than the effect of spin-orbit coupling but smaller than the Coulomb interaction.

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Copyright information

© Plenum Press, New York 1979

Authors and Affiliations

  • E. König
    • 1
  • S. Kremer
    • 1
  1. 1.University of Erlangen-NürnbergErlangenWest Germany

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