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Solution Photochemistry and Kinetics of Palladium(II) Complexes

  • John C. Cooper
  • David L. Venezky
  • Timothy Lorenz

Abstract

Recent work with palladium(II) complexes as homogenous catalysts for oxidation of olefins (1), conversion of carbon dioxide and hydrogen to formic acid (2,3), and studies of carbonate-palladium(II) complexes (4–7) , and involvement of such complexes in some catalytic systems (8), led us to investigate the equilibria leading to creation of a catalytic site in aqueous solution. Such studies provide insight into the nature of homogeneous catalysis and related photochemical investigations of palladium complexes (9–11) suggest possible new catalytic reactions and enhancement of known reactions.

Keywords

Palladium Complex Homogeneous Catalysis Apparent Quantum Yield Chloro Complex High Chloride Concentration 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Press, New York 1979

Authors and Affiliations

  • John C. Cooper
    • 1
  • David L. Venezky
    • 1
  • Timothy Lorenz
    • 1
  1. 1.Inorganic and Electrochemistry Branch, Chemistry DivisionU.S. Naval Research LaboratoryUSA

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