Abstract
Electrochemical methods of pretreating copper surfaces for adhesive bonding were studied. The objective of the electrochemical pretreatment was to control the oxide layer under the copper-coupling agent complex film, since this layer was found to be the locus of failure of copper/epoxy bonds aged in boiling water. Both cathodic and anodic pretreatments resulted in improved durability of the joint after exposure. Experiments were also performed to understand the mechanism of weakening of copper/epoxy bonds in boiling water.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
J. M. Park and J. P. Bell, in “Adhesion Aspects of Polymeric Coatings”, K. L. Mittal, Editor, pp. 245–224, Plenum Press, New York, April 1983.
I. C. Ogle and G. W. Poling, Canad. Metall. Quart., 14(1), 37 (1975).
F. Mansfeld, T. Smith and E. P. Parry, Corrosion Sci., 27, 289 (1971).
D. Chadwick and T. Hashemi, Corrosion Sci., 18, 39 (1979).
C. J. Lin and J. P. Bell, J. Polym. Sci., 16, 1721 (1972).
J. M. Park, Master’s Thesis, University of Connecticut, 1980.
W. T. McCarvill and J. P. Bell, J. Adhesion, 6, 185 (1974).
N. D. Greene, G. A. Moebus and N. H. Baldwin, Corrosion, 29(6), 234 (1973).
R. Q. Brewster and W. E. McEwen, “Organic Chemistry”, 3rd Ed., p. 238, Prentice-Hall, Englewood, NJ, 1961.
J. Kruger, J. Electrochem. Soc., 108(6), 503 (1961).
T. N. Rhodin, J. Am. Chem. Soc., 73, 3143 (1951).
M. Osawa and W. Suetaka, Corrosion Sci., 19, 709 (1979).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1984 Plenum Press, New York
About this chapter
Cite this chapter
Park, J.M., Bell, J.P. (1984). Epoxy Adhesion to Copper, Part II: Electrochemical Pretreatment. In: Mittal, K.L. (eds) Adhesive Joints. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2749-3_31
Download citation
DOI: https://doi.org/10.1007/978-1-4613-2749-3_31
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4612-9702-4
Online ISBN: 978-1-4613-2749-3
eBook Packages: Springer Book Archive