Abstract
Using the ro-vibrational wave functions from a recent ab initio quantum dynamical calculation in combination with an empirical dipole function deduced from the collision induced far infrared spectrum of gaseous nitrogen, we have calculated the intensities of far infrared transitions in (N2)2 dimers. Employing, moreover, the multipole moment and polarizability derivatives from ab initio calculations on N2 monomers, we have estimated intensities of near infrared transitions. It is demonstrated that the dimer infrared spectra depend sensitively, not only on the intermolecular potential, but also on the different contributions to the N2-N2 interaction induced dipole function.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Allnatt, A. R., 1983, private communication
Amos, R. D., 1980, Mol. Phys., 39: 1
Avoird, A. van der, Wormer, P. E. S., Mulder. F., and Berns, R. M., 1980, Topics in Current Chem., 93: 1
Berns, R. M., and Avoird, A. van der, 1980, J. Chem. Phys., 72: 6107
Birnbaum, G., Frommhold, L., Nencini, L., and Sutter, H., 1983, Chem. Phys. Lett., 100: 292
Blaney, B. L., and Ewing, G. E., 1976, Ann. Rev. Phys. Chem., 27: 553
Bosomworth, D. R., and Gush, H. P., 1965, Can. J. Phys., 43: 751
Brink, and Satchler, G. R., 1968, “Angular Momentum”, 2nd ed., Clarendon, Oxford
Brocks, G., Avoird, A. van der, Sutcliffe, B. T., and Tennyson, J., 1983, Mol. Phys., 50: 1025
Brocks, G., and Avoird, A. van der, 1984, to be published
Bunker, P.R., 1979, “Molecular Symmetry and Spectroscopy”, Academic, New York
Buontempo, U., Cunsolo, S., Jacucci, G., and Weiss, J. J. (1975) J. Chem. Phys., 63: 2570
Curtiss, C.F., 1953, J. Chem. Phys., 21: 1199
Dagg, I. R., Reesor, G. E., and Urbaniak, J. L., 1974, Can. J. Phys., 52: 821, 52: 1764
Danby, G., and Flower, D. R., 1983, J. Phys. B, 16: 3411
Dunker, A. M., and Gordon, R. G., 1978, J. Chem. Phys., 68: 700
Egelstaff, P. A., Gray, C. G., and Gubbins, K. E., 1975, in: “Physical Chem. Ser. 2, Vol. 2, Molecular structure and properties, MTP Internat. Rev. Sci.,” Buttersworths, London
Frommhold, L., Hong, K. H., and Profitt, M. H., 1976, Mol. Phys. 35: 691
Godfried, H. P., and Silvera, I. F., 1982, Phys. Rev. Lett., 48: 1337
Hemert, M. C. van, and Berns, R. M., 1982, J. Chem. Phys., 76: 354
Herzberg, G., 1950, “Molecular spectra and mglecular structure, I. Spectra of diatomic molecules”, 2nd ed., Van Nostrand, New York
Langhoff, S. R., Bauschlicher, C. W., and Chong, D. P., 1983, J. Chem. Phys., 78: 5287
Launey, J. M., 1977, J. Phys. B, 10: 3665
LeRoy, R. J., and Kranendonk, J. van, 1974, J. Chem. Phys., 61: 4750
LeRoy, R. J., and Carley, J. S., 1980, Advan. Chem. Phys., 42: 353
Long, C. A., Henderson, G., and Ewing, G. E., 1973, Chem. Phys., 2: 485
Luty, T., Avoird, A. van der, and Berns, R. M., 1980, J. Chem. Phys., 73: 5305
McKellar, A. R. W., and Welsh, H. L., 1971, J. Chem. Phys., 55: 595
McKellar, A.R.W., 1982, Faraday Disc. Chem. Soc., 73: 89
Mulder, F., Dijk, G. van, and Avoird, A. van der, 1980, Mol. Phys., 39: 407
Nyeland, C., Poulsen, L. L., and Billing, G. D., Feb. 1984, J. Phys. Chem.
Poll, J. D., and Hunt, J. L., 1981, Can. J. Phys., 59: 1448
Prengel, A. T., and Gornall, W. S., 1976, Phys. Rev., A13: 253
Schäfer, J., and Meyer, W., 1984, this volume
Sheng, D. T., and Ewing, G. E., 1971, J. Chem. Phys., 55: 5424
Steele, W. A., 1963, J. Chem. Phys., 39: 3197
Svendsen, E. N., and Oddershede, J., 1979, J. Chem. Phys., 71: 3000
Tennyson, J., and Avoird, A. van der, 1982, J. Chem. Phys., 77: 5664
Tennyson, J., and Sutcliffe, B. T., 1982, J. Chem. Phys., 77: 4061
Tennyson, J., and Sutcliffe, B. T., 1983, J. Chem. Phys., 79: 43
Verberne, J., and Reuss, J., 1981, Chem Phys., 50: 137
Waaijer, M., Jacobs, M., and Reuss, J., 1981, Chem. Phys., 63: 257
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1985 Plenum Press, New York
About this chapter
Cite this chapter
Brocks, G., van der Avoird, A. (1985). Contribution of Bound Dimers, (N2)2, To the Interaction Induced Infrared Spectrum of Nitrogen. In: Birnbaum, G. (eds) Phenomena Induced by Intermolecular Interactions. NATO ASI series, vol 127. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2511-6_39
Download citation
DOI: https://doi.org/10.1007/978-1-4613-2511-6_39
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4612-9518-1
Online ISBN: 978-1-4613-2511-6
eBook Packages: Springer Book Archive