Skip to main content
SpringerLink
Log in
Book cover

Mechanisms of Inorganic and Organometallic Reactions pp 321–341Cite as

Reactivity of Coordinated Hydrocarbons

  • Chapter

  • 132 Accesses

Abstract

As in previous volumes, this chapter reviews kinetic and mechanistic studies on the stoichiometric reactions of coordinated hydrocarbons with nucleophiles and electrophiles, together with some related processes. There has been a marked increase of interest in the stereochemistry of these reactions, in particular with chiral complexes, because of their potential in asymmetric synthesis.

This is a preview of subscription content, log in via an institution.

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. W. A. Kiel, G.-Y. Lin, A. G. Constable, F. B. McCormick, C. E. Strouse, O. Eisenstein, and J. A. Gladysz, J. Am. Chem. Soc., 104, 4865 (1982).

    Article  Google Scholar 

  2. W. A. Kiel, G.-Y. Lin, G. S. Bodner, and J. A. Gladysz, J. Am. Chem. Soc., 105, 4958 (1983).

    Article  Google Scholar 

  3. M. Brookhart, D. Timmers, J. R. Tucker, G. D. Williams, G. R. Husk, H. Brunner, and B. Hammer, J. Am. Chem. Soc., 105, 6721 (1983).

    Article  Google Scholar 

  4. L. R. Beanan, Z. A. Rahman, and J. B. Keister, Organometallics, 2, 1062 (1983).

    Article  Google Scholar 

  5. N. M. Kostic and R. F. Fenske, Organometallics, 1, 974 (1982).

    Article  Google Scholar 

  6. G. N. Mott and A. J. Carty, Inorg. Chem., 22, 2726 (1983).

    Article  Google Scholar 

  7. J. E. Jensen, L. L. Campbell, S. Nakanishi, and T. C. Flood, J. Organomet. Chem., 244, 61 (1983).

    Article  Google Scholar 

  8. O. Eisenstein and R. Hoffmann, J. Am. Chem. Soc., 103,4308 (1981), and references therein.

    Article  Google Scholar 

  9. L. Maresca and G. Natile, J. Chem. Soc., Chem. Commun., 40 (1983), and references therein.

    Google Scholar 

  10. L. Maresca, G. Natile, A.-M. Manotti-Lanfredi, and A. Tiripicchio, J. Am. Chem. Soc., 104, 7661 (1982).

    Article  Google Scholar 

  11. D. L. Reger, K. A. Belmore, E. Mintz, N. G. Charles, E. A. H. Griffith, and E. L. Amma, Organometallics, 2, 101 (1983).

    Article  Google Scholar 

  12. J.-E. Bäckvall, R. E. Nordberg, K. Zetterberg, and B. Akermark, Organometallics, 2, 1625 (1983).

    Article  Google Scholar 

  13. J. E. Bäckvall and R. E. Nordberg, J. Am. Chem. Soc., 103, 4959 (1981), and references therein.

    Article  Google Scholar 

  14. J. W. Faller and K.-H. Chao, J. Am. Chem. Soc., 105, 3893 (1983).

    Article  Google Scholar 

  15. D. A. Brown, J. P. Chester, and N. J. Fitzpatrick, Inorg. Chem.., 21, 2723 (1982).

    Article  Google Scholar 

  16. S. A. Stanton, S. W. Felman, C. S. Parkhurst, and S. A. Godleski, J. Am. Chem. Soc., 105, 1964 (1983).

    Article  Google Scholar 

  17. J. C. Calabrese, S. D. Ittel, H. S. Choi, S. G. Davis, and D. A. Sweigart, Organometallics, 2, 226 (1983).

    Article  Google Scholar 

  18. S. G. Davies, J. Hibberd, and S. J. Simpson, J. Organomet. Chem., 246, C16 (1983).

    Article  Google Scholar 

  19. J. G. Atton and L. A. P. Kane-Maguire, J. Chem. Soc., Dalton Trans., 1491 (1982).

    Google Scholar 

  20. J. J. Guy, B. E. Reichert, and G. M. Sheldrick, Acta Crystallogr., Sect. B, 32, 2504 (1976).

    Article  Google Scholar 

  21. D. A. Brown, S. K. Chawla, W. K. Glass, and F. M. Hussein, Inorg. Chem., 21, 2726 (1982).

    Article  Google Scholar 

  22. D. J. Evans and L. A. P. Kane-Maguire, Inorg. Chem. Acta, 62, 109 (1982).

    Article  Google Scholar 

  23. G. R. John, L. A. P. Kane-Maguire, T. I. Odiaka, and C. Eaborn, J. Chem. Soc., Dalton Trans., 1721 (1983).

    Google Scholar 

  24. J. G. Atton and L. A. P. Kane-Maguire, J. Organomet. Chem., 246, C23 (1983).

    Article  Google Scholar 

  25. E. G. Bryan, A. L. Burrows, B. F. G. Johnson, J. Lewis, and G. M. Schiavon, J. Organomet. Chem., 129, C19 (1977).

    Article  Google Scholar 

  26. A. L. Burrows, Ph.D. thesis, University of Cambridge (1978).

    Google Scholar 

  27. L. A. P. Kane-Maguire, T. I. Odiaka, S. Turgoose, and P. A. Williams, J. Chem. Soc., Dalton Trans., 2489 (1981), and references therein.

    Google Scholar 

  28. D. J. Evans and L. A. P. Kane-Maguire, J. Organomet. Chem., 236, C15 (1982), and references therein.

    Article  Google Scholar 

  29. J. A. S. Howell and M. J. Thomas, J. Chem. Soc., Dalton Trans., 1401 (1983).

    Google Scholar 

  30. B. M. R. Bandara, A. J, Birch, L. F. Kelly, and T. Chak Khor, Tetrahedron Letter., 24 2491 (1983).

    Article  Google Scholar 

  31. J. A. S. Howell and M. J. Thomas, J. Organomet. Chem., 247, C21 (1983).

    Article  Google Scholar 

  32. Y. K. Chung, H. S. Choi, D. A. Sweigart, and N. G. Connelly, J. Am. Chem. Soc., 104, 4245 (1982).

    Article  Google Scholar 

  33. Y. K. Chung, E. D. Honig, W. T. Robinson, D. A. Sweigart, N. G. Connelly, and S. D. Ittel, Organometallics, 2, 1479 (1983).

    Article  Google Scholar 

  34. G. Schiavon and C. Paradisi, J. Organomet. Chem., 243, 351 (1983).

    Article  Google Scholar 

  35. C. Paradisi and G. Schiavon, J. Organomet. Chem., 246, 197 (1983).

    Article  Google Scholar 

  36. Y. K. Chung, E. D. Honig, and D. A. Sweigart, J. Organomet. Chem., 256, 277 (1983).

    Article  Google Scholar 

  37. L. A. P. Kane-Maguire and D. A. Sweigart, Inorg. Chem., 18, 700 (1979).

    Article  Google Scholar 

  38. G. Faraone, F. Cusmano, and R. Pietropaolo, J. Organomet. Chem., 26, 147 (1971).

    Article  Google Scholar 

  39. M. Brookhart, A. R. Pinhas, and A. Lukacs, Organometallics, 1, 1730 (1982).

    Article  Google Scholar 

  40. Y. K. Chung, P. G. Williard, and D. A. Sweigart, Organometallics, 1, 1053 (1982).

    Article  Google Scholar 

  41. M. F. Semmelhack, J. L. Garcia, D. Cortes, R. Farina, R. Hong, and B. K. Carpenter, Organometallics, 2, 467 (1983).

    Article  Google Scholar 

  42. T. A. Albright and B. K. Carpenter, Inorg. Chem., 19, 3092 (1980).

    Article  Google Scholar 

  43. W. R. Jackson, I. D. Rae, M. G. Wong, M. F. Semmelhack, and J. N. Garcia, J. Chem. Soc., Chem. Commun., 1359 (1982).

    Google Scholar 

  44. E. P. Kündig, V. Desobry, and D. P. Simmons, J. Am. Chem. Soc., 105, 6962 (1983).

    Article  Google Scholar 

  45. L. N. Nekrasov, L. P. Yur’eva, and S. M. Peregudova, J. Organomet. Chem., 238, 185 (1982).

    Article  Google Scholar 

  46. C. A. Bunton, M. J. Mhala, J. R. Moffatt, and W. E. Watts, J. Organomet. Chem., 253, C33 (1983).

    Article  Google Scholar 

  47. D. W. Clack, M. Monshi, and L. A. P. Kane-Maguire, J. Organomet. Chem., 120, C25 (1976).

    Article  Google Scholar 

  48. C. A. Bunton, K. Lal, and W. E. Watts, J. Organomet. Chem., 247, C14 (1983).

    Article  Google Scholar 

  49. G. R. John, L. A. P. Kane-Maguire, and D. A. Sweigart, J. Organomet. Chem., 120, C47 (1976).

    Article  Google Scholar 

  50. O. Koch, F. Edelmann, and U. Behrens, Chem. Ber., 115, 1313 (1982).

    Article  Google Scholar 

  51. U. Belluco, R. A. Michelin, P. Uguagliati, and B. Crociani, J. Organomet. Chem., 250, 565 (1983).

    Article  Google Scholar 

  52. G. S. Lewandos, J. W. Maki, and J. P. Ginnebaugh, Organometallics, 1, 1700 (1982).

    Article  Google Scholar 

  53. Wong and J. A. Gladysz, J. Am. Chem. Soc., 104, 4948 (1982).

    Article  Google Scholar 

  54. W. G. Hatton and J. A. Gladysz, J. Am. Chem. Soc., 105, 6157 (1983).

    Article  Google Scholar 

  55. J. H. Merrifield, G.-Y. Lin, W. A. Kiel, and J. A. Gladysz, J. Am. Chem. Soc. 105, 5811 (1983).

    Article  Google Scholar 

  56. M. F. Semmelhack and C. Ullenius, J. Organomet. Chem., 235, C10 (1982).

    Article  Google Scholar 

  57. H. Fischer, E. O. Fischer, and R. Cai, Chem. Ber., 115, 2707 (1982).

    Article  Google Scholar 

  58. H. Fischer, E. O. Fischer, R. Cai, and D. Himmelreich, Chem. Ber., 116, 1009 (1983).

    Article  Google Scholar 

  59. H. Fischer, J. Mühlemeier, R. Märkl, and K. H. Dötz, Chem. Ber., 115, 1355 (1982).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Imperial Chemical Industries P.L.C., Billingham, Cleveland, UK

    M. V. Twigg

Authors
  1. M. V. Twigg
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Imperial Chemical Industries P.L.C., Billingham, Cleveland, UK

    M. V. Twigg

Rights and permissions

Reprints and permissions

Copyright information

© 1985 Plenum Press, New York

About this chapter

Cite this chapter

Twigg, M.V. (1985). Reactivity of Coordinated Hydrocarbons. In: Twigg, M.V. (eds) Mechanisms of Inorganic and Organometallic Reactions. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2479-9_12

Download citation

  • DOI: https://doi.org/10.1007/978-1-4613-2479-9_12

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-9503-7

  • Online ISBN: 978-1-4613-2479-9

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation