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Aspects of Organoiron Mössbauer Spectroscopy

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Chemical Mössbauer Spectroscopy

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Abstract

In this the silver anniversary year of the discovery of the Mössbauer effect its role in the characterization of the organo- metallic chemistry of iron will be considered. Within the frame-work of this discussion we begin by examining the range of parameters normally encountered in low valent iron Mössbauer spectroscopy and the structure of the experiment for this application. Mössbauer spectroscopy studies the interaction of nuclear spin transitions with the electronic and magnetic environment. This provides information regarding electronic configuration or oxidation state, stereochemistry and the bonding capabilities of ligands. Some of these arguments have impacted historically on the field of organoiron chemistry. More detailed expositions of the theory and practice of Mossbauer spectroscopy may be found published elsewhere1–13 and also accompany this review. Previous reviews of this subject have also appeared.1,2,10

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  1. Research Center, Olin Corporation, 275 South Winchester Avenue, New Haven, Connecticut, 06511, USA

    Barrie A. Sosinsky

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  1. Rutgers University, New Brunswick, New Jersey, USA

    R. H. Herber

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© 1984 Plenum Press, New York

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Sosinsky, B.A. (1984). Aspects of Organoiron Mössbauer Spectroscopy. In: Herber, R.H. (eds) Chemical Mössbauer Spectroscopy. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-2431-7_1

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  • DOI: https://doi.org/10.1007/978-1-4613-2431-7_1

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